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91.
92.
采用非预混燃烧模型与组分传输的一步反应模型,模拟了甲烷燃烧及NOx的生成,得出燃烧温度场、NO生成情况。模拟结果表明:采用非预混燃烧模型模拟时结果更接近实测值,模拟更准确;甲烷扩散燃烧时NO产生区域主要集中在高温火焰后侧,在前部低温区基本没有NO生成;燃烧中P-NO生成量比T-NO量小两个数量级,NO产生几乎完全被热力型NO机制支配,在燃烧过程中应特别注意高温区域的影响。 相似文献
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95.
Methane absorption and application of mixed organic aggregate prepared from Span80 and alkaline salt
The water-based materials for mine gas absorption and explosion suppression were prepared, in which the mixed organic aggregate
of Span80 and alkaline salt can be used as methane absorbent. Methane was used as a model of mine gas, and the absorptions
of methane with different complex materials were studied using head space gas chromatography. Then the state of aqueous material
was characterized with laser light scattering instrument and the effects of different complex materials on explosion suppression
were preliminarily studied in explosion chamber which can simulate mine gas explosion. The research results showed that complex
material could absorb methane and there was some correlation between the mean diameter of organic aggregate in aqueous material
and the absorption effect. Additionally, the aqueous material could suppress the methane explosion to some degree. The material
can absorb mine gas in atomization condition, therefore, degrease mine gas concentration and influence the distribution of
mine gas in the space, and then suppress the mine gas explosion to some extent. 相似文献
96.
以二甲基氨基甲叉二膦酸(DMMP)为原料,双氧水为氧化剂合成二甲基氨基甲叉二膦酸氮氧化物(DMMPO)。研究了原料配比、温度、时间及合成时pH值等条件对目标产物阻磷酸钙垢效果的影响,结果表明:n(DMMP)∶n(H2O2)=1∶3、反应温度为75℃、反应时间为2.5 h,并控制pH值为9左右时合成的DMMPO静态阻垢效果最好。通过IR和31P-NMR对产物进行了结构鉴定,同时对产品进行了活性物含量、亚磷酸根和磷酸根含量的测定,直接合成产物中活性组分含量为22.7%,亚磷酸根和磷酸根含量均小于0.1%。 相似文献
97.
The dissociative adsorption of methane was carried out on a Ni(100) surface covered with various amounts of sulfur under the high incident flux conditions of 1 Torr methane. Auger electron spectroscopy was used to measure the rate of carbon buildup and thus to determine the initial methane decomposition rates on the surface. It was shown that the sulfur atoms poison this reaction by a simple site-blocking process. These results are consistent with the activated dissociative adsorption of methane on Ni(100) occurring via a direct adsorption process. 相似文献
98.
A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example. 相似文献
99.
Promotion of hydrogen permeation on metal-dispersed alumina membranes and its application to a membrane reactor for methane steam reforming 总被引:1,自引:0,他引:1
Maorong Chai Masato Machida Koichi Eguchi Hiromichi Arai 《Applied Catalysis A: General》1994,110(2):239-250
A mesoporous membrane for selective separation of hydrogen was prepared usingthe sol-gel method. Some metal salts such as RuCl3, Pd(NH3)4Cl2, RhCl3,, and H 2PtCl6, were added to the boehmite sol and coated on a porous alumina substrate before firing at 500°C. It was foundthat the permeability of hydrogen and the separation factor for a hydrogen-nitrogen gaseous mixture of these metaldispersed membranes exceeded the limitations of the Knudsen diffusion mechanism. Although the gas permeation through a neat alumina membrane is governed by the Knudsen diffusion, the metals dispersed in alumina membranes were effective in promoting hydrogen permeation. These metaldispersed alumina membranes were also used in a membrane reactor for methane steam reforming at low temperature. In the temperature range of 300 to 500°C, the membrane reactor attained a methane conversion twice as high as the equilibrium value of the packed bed catalytic reactor system as a result of the selective removal of hydrogen from the reaction system. 相似文献
100.
V. Sekkar K. Narayanaswamy K. J. Scariah P. R. Nair K. S. Sastri How Ghee Ang 《应用聚合物科学杂志》2006,101(5):2986-2994
Hydroxyl‐terminated polybutadiene (HTPB)‐based allophanate–urethane networks were prepared by reacting HTPB with di‐isocyanates, such as toluene–di‐isocyanate (TDI), isophorone–di‐isocyanate (IPDI), and 4,4′‐di(socyanatocyclohexyl)methane (H12MDI) at stoichiometric ratios (r‐values) ranging from 1.0 to 1.5. The networks were characterized for mechanical and swell properties. The network parameters, such as “X,” which is the fraction of urethane groups involved in the allophanate formation, and effective chain length (Lx) were calculated from experimental crosslink density values determined from swell data, using α‐model equations developed by Marsh. Excellent linear correlations were obtained between mechanical properties and the calculated network parameters. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2986–2994, 2006 相似文献