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71.
通过对活性炭载体进行不同条件的超声波处理获得了具有不同表面化学性质的载体,使用比表面积(BET)、酸碱滴定等技术手段对载体的物理化学性质进行了表征。将经过超声波处理的活性炭载体制备成Pt/C催化剂,并将催化剂直接用于催化反应,考察了活性炭载体的不同超声波处理条件对Pt/C催化剂性能的影响。实验发现,活性炭载体经过超声波处理后,表面灰分含量、pH值和中孔孔容有较大的变化;使用经过60min超声波处理后中孔孔容较大的活性炭作为载体制备的Pt/C催化剂,在催化加氢反应性能测试中显示了最高的催化活性。在此基础上,就活性炭载体的超声波处理对Pt/C催化剂活性的影响进行了讨论。 相似文献
72.
Two commercial SCR catalysts, with a nominal W content of about 9 wt.% and a V nominal content of 0.55 and 1.8 wt.%, respectively, were contacted with different amounts of Na and K and with HCl vapours in order to simulate poisoning by species more specifically contained in exhaust gases from MSW combustion. Catalysts were characterised using XRD analysis, SEM/EDX analysis, BET and pore size distribution measurements, NH3 TPD, TG analysis. Poisoning agents do not cause loss of surface area nor pore occlusion. A significant loss of surface acidity was observed upon alkali metals poisoning whereas a decreasing of vanadium content was observed for the more concentrated catalysts upon HCl poisoning. Catalysts deactivation is proportional to the number of acid sites neutralised by alkali metals adsorbing ammonia in the temperature range typical of SCR process. HCl promotes the formation of new acid sites showing a lower activity compared to the original one. 相似文献
73.
采用复合改性剂生产改性淀粉,制得干粉状NH—1粘合剂,并进行了工业化生产,取得了满意的结果。 相似文献
74.
75.
从废钼合金催化剂中提取钼等有价元素方法的研究 总被引:2,自引:2,他引:0
MoCoNi合金料首先氧化焙烧碱浸出,滤饼再加纯碱焙烧水浸出使钼与钴镍分离,最后用萃取法分离钴镍的工艺流程,对废钼合金催化剂进行了综合回收。采用该工艺流程和生产线分别生产出合格的工业级钼酸钠、氧化钴和氧化镍。 相似文献
76.
T. S. Lee S. B. Lee J. M. Kim J. S. Kim S. H. Suh J. H. Song I. H. Park S. U. Kim M. J. Park 《Journal of Electronic Materials》1995,24(9):1057-1059
In order to improve the Zn homogeneity along the axial direction of CdZnTe boule, we have employed a modified Bridgman technique
using a (Cd, Zn) alloy source in communication with the melt, whose temperature has been gradually changed from 800 to 840°C
during growth. Electron probe microanalysis (EPMA) measurements of Zn composition in the boule shows an excellent homogeneity
of Zn along the axis of the CdZnTe boule compared with results in a boule grown by using a fixed source temperature. We have
performed a numerical simulation to obtain the approximate temperatures of additional heating and cooling needed to improve
the radial Zn homogeneity. CdZnTe boule has been grown by seeded vertical Bridgman furnace with two zones of heater and cooler.
Ultraviolet/visible spectroscopic measurements of Zn composition over the length of the boule indicate that the radial distribution
of Zn composition is very homogeneous in the body region of the boule, where the radial variation of Zn composition is ±0.0005. 相似文献
77.
Modified Atmosphere Packaging Affects Ascorbic Acid, Enzyme Activity and Market Quality of Broccoli 总被引:1,自引:0,他引:1
Reduced ascorbic acid (RAA) content, total chlorophyll and green color retention, enzyme activities and texture changes were followed in broccoli spears packaged in polymeric film and nonpackaged during 96 hr storage (10°C). Concentrations within packages monitored by gas chromatography were (CO2,) 8% and (02) 10%. RAA retention, moisture content, total chlorophyll and color retention were greater in packaged broccoli. No differences were found between packaged and nonpackaged broccoli for ascorbate oxidase and peroxidase activities, or texture. 相似文献
78.
改性己二胺制备TG301环氧树脂室温固化剂 总被引:4,自引:0,他引:4
已二胺经与环氧树脂进行羟烷基化及与丙烯腈进行氰乙基化反应达到改善低熔点低毒性.低脆性的综合效果.文中介绍了改性乙二胶固化剂的制备方法,质量指标和有关固化特性等. 相似文献
79.
A. F. Y. Al-Shammary I. T. Caga A. Y. Tata J. M. Winterbottom I. R. Harris 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,55(4):361-367
Alloys of the general formula Zr50NixCO50-x, where 0 ≦x≧ 50, have been prepared and used in the temperature range 300–400°C, in the pressure range 1–9 barg in a microtubular reactor for the reaction of hydrogen with carbon monoxide to give hydrocarbons. The alloys or intermetallic materials were prepared by argon arc melting, powdered by hydrogen decrepitation and characterised by means of optical microscopy (metallography), scanning electron microscopy with surface analysis and magnetic susceptibility measurements. The selectivity towards higher hydrocarbons increased with (i) increase in the total pressure and (ii) decrease in hydrogen content of the feed gases. The kinetics were found to be of the form: where m = 1.0 ± 0.2 and n = 0. The apparent energy of activation (Ea) lay in the range of 80–130 kJ mole?1 and there appeared to be a compensation effect between Ea and the pre-exponential factor A. The turnover numbers for the reaction exhibited an activity maximum for alloys of composition around Zr50Ni40Co20 and Zr50Ni30Co20. Magnetic susceptibility measurements indicated that alloys changed their nature from moderately paramagnetic to strongly paramagnetic or even ferromagnetic after use and this is attributed to the conversion of zirconium to zirconium oxide during reaction with the attendant production of free 3d-transition metals. Derived catalysts prepared by air treatment of the hydrogen-decrepitated intermetallics behaved almost identically to the latter materials and gave similar magnetic susceptibility values to used hydrided materials. 相似文献
80.
PtRh catalysts were prepared by coimpregnation, with chlorine-free precursors of a -alumina. They were sintered at 973 K under a continuous flow of O2 (1% in Ar or air) or of a flow of Ar into which pulses of O2 were injected periodically. Under the latter conditions the sintering was significantly accelerated, particularly for a certain value of the period of O2 pulses. 相似文献