液相合成纳米氧化锌及其光催化性能探讨

以硝酸锌和氢氧化钠为原料,分别以水和醇作为溶剂,采用液相直接沉淀法合成纳米氧化锌。在以水为反应溶剂条件下,研究了反应时间、反应温度、反应物浓度和反应物配比对纳米氧化锌中位径和形貌的影响,得到制备较小中位径及合适长径比纳米氧化锌的最优反应条件,即:反应时间为3 h、反应温度为70 ℃、锌离子浓度为0.5 mol/L、锌离子与氢氧根浓度比为1:2。在上述最优反应条件下,研究了不同醇溶剂对纳米氧化锌中位径、形貌及其光催化性能的影响。研究发现,随着溶剂碳链长度的增长,纳米氧化锌中位径呈现上下波动,无明显变化规律,形貌由球状向柱状发展,光催化性能总体不断减弱。     

Liquid Radial Dispersion in Liquid-solid Circulating Fluidized Beds with Viscous Liquid Medium

Liquid dispersion in the radial direction was investigated in the riser of a viscous liquid-solid fluidized bed 0.102 m in diameter and 3.5 m in height. Pressure fluctuations in the riser were also measured and analyzed to examine the behavior of fluidized particles. Effects of liquid velocity (0.15-0.45 m/s), solid circulation rate (2-8 kg/m²s), particle size (1-3 mm), and liquid viscosity (0.96-38 mPas) on pressure fluctuations and the liquid radial dispersion coefficient were determined. The infinite space model was employed to obtain the radial dispersion coefficient from the radial concentration profiles of the tracer. The pressure fluctuations were analyzed by means of autocorrelation coefficient as well as power spectral density function. The dominant frequency obtained from the autocorrelation coefficient or power spectral density function of pressure fluctuations decreases with increasing liquid viscosity or liquid velocity, but it increases with increasing particle size. The liquid radial dispersion coefficient decreases with increasing liquid velocity or viscosity, but it increases as the solid circulation rate or particle size increases. The liquid radial dispersion coefficient is related closely to the resultant behavior of fluidized particles. The radial dispersion coefficient has been well correlated with operating variables in terms of dimensionless groups.     

一种简单便携的存储介质信息检测及备份装置研究

随着信息时代的飞速发展,数据信息在生活中的作用越来越显重要,数据恢复在社会生活中的应用越来越广,这便需要对存储介质的信息进行必要的检测和备份。虽然一些常见的软件可以通过PC端实现检测和备份功能,但也就是针对常见USB设备和一些专业性比较强的硬盘,不方便备份且不易携带,因此能提供一种兼容各种存储介质,并且方便使用、易于携带且不依赖于电脑就能实现检测和备份的设备非常重要。本文阐述了一种简单便携的存储介质信息检测及备份装置的研究设计．．     

采用两种中间介质的工业园区厂际余热集成

发挥园区集群效应，借助中间介质回路将工业园区中各单厂内的余热于厂际间进一步回收利用，能够显著提高园区整体能源效率。其中，中间介质回路的设置与介质的选择将关系到整个余热回收系统的最优设计与节能效果。因此，不同于目前研究仅采用一种中间介质的集成策略，同时选用热水和导热油为介质开展厂际余热集成研究。提出耦合介质与厂内流股换热及介质流股在厂际间分配的换热器网络超结构，以年度总费用最小为目标建立MINLP热集成数学模型，优化获得包含介质回路结构与厂内换热器网络结构等内容的园区余热集成结果。最后，在一个包含3个厂的厂际余热集成案例中，分别研究了单种介质单回路、单种介质双回路及双种介质双回路3种情况，通过对比验证了所提方法的有效性。     

Electroreduction of dioxygen (ORR) in alkaline medium on Ag/C and Pt/C nanostructured catalysts—effect of the presence of methanol

Ag/C catalysts with different loading were prepared using a colloidal route to obtain well dispersed catalysts on carbon, with a particle size close to 15 nm. An amount of 20 wt.% Ag on carbon was found to be the best loading in terms of current density and mass activity. The 20 wt.% Ag/C catalyst was then studied and the kinetics towards ORR was determined and compared with that of a 20 wt.% Pt/C catalyst. The number of exchanged electrons for the ORR was found to be close to four with the rotating disk electrode (RDE) as well as with the rotating ring disc electrode (RRDE) techniques. From the RDE results, the Tafel slopes b, the diffusion limiting current density inside the catalytic film (j_l^film) and the exchange current density (j₀) were evaluated. The Tafel slopes b and diffusion limiting current densities inside the catalytic film (j_l^film) were found to be in the same order for both catalysts, whereas the exchange current density (j₀), which is a suitable estimation of the activity of the catalyst, was at least 10 times higher at the Pt/C catalyst than at the Ag/C catalyst. The behavior of both catalysts in methanol containing electrolyte was investigated and it was found that at a low methanol concentration, the Pt/C catalyst was quasi-tolerant to methanol. But, at a high methanol concentration, the ORR at a Pt/C was affected. However, the Pt/C catalyst showed in each case better activity towards ORR than the Ag/C catalyst, even if the latter one was less affected by the presence of methanol than the former one.     

Analysis of junction temperatures in high-power GaN-based LEDs

We presented the analysis of the incomplete conduction in bonding medium in high power GaN-based light-emitting diode (LED) packages. A numerical study was carried out with parametric model to understand the junction temperature variation due to bonding medium defects. Transient thermal measurement was performed to evaluate LED’s junction temperature. Thermal resistance from chip to lead frame was 20 K/W in our sample LED. It was suggested that only 60% of the surface area of the bonding medium was involved...     

财务工程视角下的中小民企财务困境分析

我国的中小民营企业已经成为支撑和推动我国国民经济增长的重要力量。但我国中小民营企业的财务问题一直困扰着企业的发展。并且传统的研究方法和金融手段已经不能适应日益复杂的金融环境。财务工程的发展为解决中小民营企业财务困境提供了全新的思路与方法。利用财务工程理论,分析我国中小民营企业出现财务困境的原因,并针对其融资难、信息不对称、投资风险和利率汇率风险提出对策。     

弹性介质中框架结构的有限元计算分析(英文)

文章提出了一种考虑剪切变形,由经典弯杆理论发展形成的在弹性介质中框架结构的有限元计算方法.     

Longitudinal surface cracks of thin slabs

Based on the production practice of medium carbon thin slabs in the CSP plant,the reasons and influencing factors for the formation of longitudinal cracks were investigated,and some industrial measures were taken to eliminate the cracks.The results show that the efficient solutions to reduce longitudinal cracks are improving the performance of the mold powder,stabilizing the mold heat flux,and maintaining a proper taper of the mold during casting.Proper pouring temperature and secondary cooling also play...     

考虑中主应力效应Gudehus-Bauer亚塑性模型的改进

针对Gudehus-Bauer亚塑性模型不能考虑中主应力影响,在Gudehus提出的响应包络线理论基础上,提出了在模型的非线性项乘以一个考虑中主应力的因子进行改进.这种改进增加了土体剪切时的强度,改变了土体受压时的变形.新模型对中主应力的变化在中主应力参数影响程度能够有一定反映.同时将改进后的模型与中主应力参数为常量的真三轴实验进行了比较.结果表明改进后的模型可以模拟中主应力对砂土强度和变形特性的影响,能够定量预测由于中主应力影响产生的体积应变.