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71.
Theoretical investigation of solvent effects on the selective hydrogenation of furfural over Pt(111)
Jian Wang Cun-Qin Lv Jian-Hong Liu Rong-Rong Ren Gui-Chang Wang 《International Journal of Hydrogen Energy》2021,46(2):1592-1604
It was well known that solvent effect plays a very important role in the catalytic reaction. There are many theoretical studies on the solvent effect in homogeneous catalysis while there are few theoretical studies on the solvent effect in the heterogeneous catalytic reaction and there has been no work to investigate the solvent effect on furfural transformation in heterogeneous catalysis. In the present work, both the density functional calculations and the microkinetic analysis were performed to study the selective hydrogenation of furfural over Pt(111) in the presence of methanol as well as toluene and compared with that in the gas condition. The present results indicated that the methanol can enhance the adsorption strength of furfural and other oxygen-containing reaction species due to its relatively strong polarity properties and this can be a main reason for solvent-induced high activity and selectivity. Another reason is that reaction paths study showed that the presence of methanol solvent makes the dehydrogenation of furfural less thermochemical due to the fact that furfural is more stabilized than that of dehydrogenation species, and methanol also has an inhibition effect on the dehydrogenation of furfural in the kinetic aspect, and further energetic span theory proves highest activity and selectivity for hydrogenation in methanol solvent of vapor, methanol and toluene. Moreover, microkinetic model simulation demonstrated that the activity and selectivity of hydrogenation in methanol is both higher than that in vapor and toluene. The much higher activity in methanol is due to the stabilized adsorbed reactants in the surface, which leads to a higher surface coverage of furfural. It might be proposed based on the present work that a solvent with relatively strong polarity may be favorable for the high selective hydrogenation of furfural. 相似文献
72.
以从自然腐败的樱桃上分离的链格孢霉(Alternaria sp.)LD3.0086为指示菌,研究苯乳酸对链格孢霉的主要抑制作用靶位。应用分光光度法测定苯乳酸对链格孢霉的最小抑菌浓度,通过卡尔科弗卢尔荧光增白剂染液(calcofluor white,CFW)染色观察苯乳酸对菌丝顶端生长的破坏作用,利用扫描电子显微镜和透射电子显微镜观察链格孢霉的超微结构变化,通过测定苯乳酸作用前后链格孢霉上清液中N-乙酰葡萄糖胺质量浓度变化研究苯乳酸对菌丝细胞壁的破坏作用,应用荧光双染色法观察苯乳酸对链格孢霉菌丝细胞膜的损伤作用。结果表明,12.5 mmol/L的苯乳酸能有效抑制链格孢霉的生长;与对照组(无菌水处理)相比,苯乳酸处理后链格孢霉顶端生长细胞无明显形变,经12.5 mmol/L苯乳酸处理的链格孢霉上清液中N-乙酰葡萄糖胺质量浓度基本不变;苯乳酸处理24 h,链格孢霉菌丝细胞壁表面无明显损伤,细胞内结构发生明显变化;苯乳酸短时间(4 h)处理链格孢霉,菌丝细胞膜仍较为完整,加入苯乳酸较长时间(8 h)后细胞膜发生破裂。综合分析可知,苯乳酸对链格孢霉的主要作用靶位应不是菌丝体的细胞壁和细胞膜,而是在菌丝体内部,通过破坏菌丝内部细胞器结构或引起细胞内的生化反应,从而抑制链格孢霉的生长和繁殖,发挥抑菌活性。 相似文献
73.
Digital technology becomes more powerful, intelligent, pervasive and ubiquitous. Ethical aspects of this development have not yet drawn the appropriate attention of researchers and engineers. This paper presents an instrument that aims at measuring the individual ethical position with regard to the design and development of computer software. The development of the Epos tool was based on two data collections. The data of the first survey (n1 = 147 participants) were used to select items and to determine the factorial structure of the questionnaire. Results show that the Epos instrument reliably assesses peoples’ ethical opinion with respect to five central components: (1) regulation, (2) data privacy, (3) domain specific knowledge, (4) societal responsibility and (5) company responsibility. In the second survey, we determined the stability of the instruments factor structure by assessing a sample of n2?=?196 participants. A confirmatory factor analysis (CFA) supported the initial factor structure. Next steps and further implications are discussed regarding the final version of the questionnaire. 相似文献
74.
现有毒品滥用流行病模型假设吸毒者康复后对毒品拥有永久"免疫"力,而忽视了其再次成为毒品易感者的可能性。针对这一问题,通过考虑社区治疗和隔离治疗两种措施,分析了毒品滥用人群的演化过程,提出了基于暂时"免疫"力的毒品滥用流行病模型,并计算了模型的基本再生数,讨论了模型平衡点的存在性和稳定性。当基本再生数小于1时,模型存在一个局部渐进稳定的无毒平衡点;当基本再生数大于1时,模型存在唯一的地方病平衡点,并利用几何方法证明了地方病平衡点的全局稳定性;当基本再生数等于1时,如果满足一定条件,模型出现后向分支现象。数值模拟验证了上述所有结果。研究结果表明提高隔离治疗率、改善社区治疗效果和降低接触传染率可以有效抑制毒品滥用的流行。 相似文献
75.
摘 要:目的 了解六六六(hexachlorocyclohexanes,HCHs)与滴滴涕(dichloro diphenyl trichloroethanes,DDTs)在杭州湾南岸滩涂沉积物中的污染现状。方法 于2018年4月,采集杭州湾南岸地区4个采样点不同深度(0~80 cm)滩涂沉积物,利用气相色谱-串联质谱法(gas chromatography tandem mass spectrometry, GC-MS/MS)测定了该区域中HCHs与DDTs的含量,对其分布规律进行分析,使用共识沉积物质量基准法对其生态学风险进行了评估。结果 所有样品中均检出,HCHs与DDTs含量分别为4.20~6.24 μg/kg与3.37~4.73 μg/kg,主要以β-HCH、δ-HCH以及DDE为主,其污染主要来源于历史性工业品,整体污染处于较低水平;20.3%的沉积物样品中DDEs含量以及28.1%的样品DDTs总量介于阈值效应浓度(threshold concentration, TECs) 和可能效应浓度(probable effect concentration, PECs)之间。结论 杭州湾南岸沉积物中HCHs与DDTs的污染处于较低水平,具有较小的生态学风险。 相似文献
76.
Efficient hydrogen production for industry and electricity storage via high-temperature electrolysis
《International Journal of Hydrogen Energy》2019,44(35):19089-19101
The paper describes the development status of Sunfire's reversible solid oxide cell (RSOC) technology. Here, Sunfire is a pioneer in the field of high-temperature electrolysers (HTE) for renewable hydrogen production which can be operated as a fuel cell for power generation in a reverse mode. The maturity of the technology is improved stepwise so that first applications in the field of hydrogen production for industry and electricity storage can be tackled. Three application examples where larger scale prototype has been installed will be discussed: 1) A power-to-power electricity storage based on hydrogen, 2) a RSOC unit that is installed in an iron and steel works, and 3) a pressurized SOEC prototype which will be integrated with a methanation unit. Results show the potentials of the technology in connection with fluctuating renewable energy sources. 相似文献
77.
Journal of Computer Science and Technology - DOACROSS loops are significant parts in many important scientific and engineering applications, which are generally exploited pipeline/wave-front... 相似文献
78.
Vaidhegi Kugarajah Moogambigai Sugumar Elamathi Swaminathan Nagaraj Balasubramani Sangeetha Dharmalingam 《International Journal of Hydrogen Energy》2021,46(42):22134-22148
Hydrothermally prepared zinc oxide nanorods are sulphonated (S–ZnO NR) and incorporated into 15% Sulphonated Poly (1,4-Phenylene Ether Ether Sulfone) (SPEES) to improve the hydrophilicity, water uptake and ion transfer capacity. Water uptake and ion transfer capacity increased to 34.6 ± 0.6% and 2.0 ± 0.05 meq g?1 from 29.8 ± 0.3% and 1.4 ± 0.04 meq g?1 by adding 7.5 wt% S–ZnO NR to SPEES. Morphological studies show the prepared S–ZnO NR is well dispersed in the polymer matrix. SPEES +7.5 wt% S–ZnO NR membrane exhibits optimum performance after three-weeks of continual operation in a fabricated microbial fuel cell (MFC) to produce a maximum power density of 142 ± 1.2 mW m?2 with a reduced biofilm compared to plain SPEES (59 ± 0.8 mW m?2), unsulphonated filler incorporated SPEES (SPEES + 7.5 wt% ZnO, 68 ± 1.1 mW m?2) and Nafion (130 ± 1.5 mW m?2) thereby suggesting its suitability as a sustainable and improved cation exchange membrane (CEM) for MFCs. 相似文献
79.
Anna Wawruszak Jarogniew Luszczki Marta Halasa Estera Okon Sebastian Landor Cecilia Sahlgren Adolfo Rivero-Muller Andrzej Stepulak 《International journal of molecular sciences》2021,22(10)
Histone deacetylase inhibitors (HDIs) are promising anti-cancer agents that inhibit proliferation of many types of cancer cells including breast carcinoma (BC) cells. In the present study, we investigated the influence of the Notch1 activity level on the pharmacological interaction between cisplatin (CDDP) and two HDIs, valproic acid (VPA) and suberoylanilide hydroxamic acid (SAHA, vorinostat), in luminal-like BC cells. The type of drug–drug interaction between CDDP and HDIs was determined by isobolographic analysis. MCF7 cells were genetically modified to express differential levels of Notch1 activity. The cytotoxic effect of SAHA or VPA was higher on cells with decreased Notch1 activity and lower for cells with increased Notch1 activity than native BC cells. The isobolographic analysis demonstrated that combinations of CDDP with SAHA or VPA at a fixed ratio of 1:1 exerted additive or additive with tendency toward synergism interactions. Therefore, treatment of CDDP with HDIs could be used to optimize a combined therapy based on CDDP against Notch1-altered luminal BC. In conclusion, the combined therapy of HDIs and CDDP may be a promising therapeutic tool in the treatment of luminal-type BC with altered Notch1 activity. 相似文献