降温集油技术在朝阳沟油田的应用

精确界定油井温度界限值,对回油温度进行自动控制是降低气耗、能耗的有效措施。首先推导了单井温度界限数值模型,然后针对朝阳沟油田的实际情况对油井进行了分类,并选择了有代表性的单(环)井进行了试验。通过现场实测值与利用模型计算的预测值比对,符合率达到了70%以上。在此基础上利用温度界限分析仪进行了进一步的验证试验,结果符合预期。在单(环)井上加装了掺水量自动控制装置,实现了回油温度的自动控制。     

Determination of instantaneous corrosion rates and runoff rates of copper from naturally patinated copper during continuous rain events

Instantaneous corrosion rates of naturally patinated copper of varying age (16 months, 138 and 145 years) have been determined during continuous rain events in the laboratory with electrochemical impedance spectroscopy using a two-electrode cell. The two-electrode cell was found to yield the same information in bulk rainwater as a conventional three-electrode cell.Relatively constant corrosion rates, between 0.2 and 0.6 μm/y, were determined for samples having a two-layer structure with an inner brownish layer of cuprous oxide and an outer greenish layer of basic copper salts (138, 145 years). Samples with cuprous oxide as the dominating phase of the patina (16 months) showed higher and somewhat increasing corrosion rates during a rain event (from 0.6 to 1.2 μm/y). During a continuous rain event, corrosion rates were found to be approximately 10 (brownish patina) and 25 times (greenish patina) lower than corresponding instantaneous runoff rates. The first flush phenomena of the runoff process, with an increased concentration during first flush and a relatively constant concentration during steady state, was indirectly seen as an increase in solution conductivity during the first rain volume followed by relative constant value. The contribution of the concentration in the first flush to the total annual runoff rate was significant for panels having a greenish layer (138, 145 years) whereas it was negligible for panels having a brownish layer (16 months).     

Microwave Demulsification in Removing Naphthenic Acids from Diesel Oil

Emulsification is an undesired phenomenon in the refining of highly acidic oil by alkali-washing electro-refining. In this article, a novel microwave method is applied for demulsification in the removing of naphthenic acid from diesel oil. The internal heating is attributed to molecular rotation and ionic conduction. The decrease of interface zeta-potential and the viscosity of diesel oil are responsible for the demulsification with microwave irradiation. The results exhibited that the demulsification rate is maximized when the optimum microwave irradiation power, exposure time, and irradiation pressure for Anshan and Liaohe diesel oil are deemed to be 375 W, 5/6 min and 0.05 MPa, respectively.     

海洋石油平台水下夹桩器本体结构分析

水下夹桩器是一种广泛应用于海洋石油平台建设的液压夹具。水下夹桩器本体焊接在导管架上，支撑夹桩器液压缸。在水下夹桩器本体设计中，采用有限元法完成了对本体强度和刚度的结构分析；建立了有限元分析模型，用ANSYS软件进行结构分析，得到了分析结果，并将该结果与理论计算结果进行了比较，验证了有限元分析技术的有效性。设计结果满足工程要求，为改进和优化结构提供了理论依据，节省了分析计算时间。     

Effect of powder painting procedures on the filiform corrosion of aluminium profiles

In this work, the filiform corrosion behaviour of powder painted aluminium profiles was studied, and the coating barrier properties together with adhesion to the substrate were analysed. Samples coated with a traditional painting procedure (one powder layer application followed by curing), and other samples coated using a special cycle to obtain wood grain effect were compared using accelerated filiform corrosion tests. Moreover, in order to better understand the degradation mechanisms of painted metal substrates, thermal stresses were applied to accelerate the natural weathering. The effects of the thermal aging were analysed by electrochemical impedance spectroscopy.     

The Einstein relation in nanostructured materials: simplified theory and suggestion for experimental determination

An attempt is made to study the Einstein relation for the diffusivity–mobility ratio (DMR) in quantum wells (QWs) and quantum well wires (QWWs) of tetragonal compounds on the basis of a newly formulated electron energy spectrum taking into account the combined influences of the anisotropies in effective electron mass, the spin–orbit splitting, and the presence of crystal field splitting, respectively. The results for quantum-confined III–V compounds form a special case of our generalized analysis. The DMR has also been studied for QWs and QWWs of II–VI and IV–VI materials. Taking QWs and QWWs of CdGeAs₂, InAs, CdS and PbSe as examples, it was found that the DMR increases with increasing carrier statistics and decreasing film thickness respectively in various oscillatory manners emphasizing the influence of dimensional quantizations and the energy band constants in different cases. An experimental method of determining the DMR in nanostructures with arbitrary dispersion laws has also been suggested and the present simplified analysis is in agreement with the suggested relationship. The well-known results for nanostructures with parabolic energy bands have also been obtained as special cases from this generalized analysis under certain limiting conditions.     

利用高酸值餐饮废油脂制备生物柴油

以高酸值餐饮废油脂为原料,在酯化反应后再经两步酯交换反应制备生物柴油。在酯化反应中添加吸水剂可降低油脂的酸值,经一次酯化反应即可将油脂的酸值降至2m g/g左右,满足酯交换反应的要求。考察了酯化反应中吸水剂的添加方式、种类及其用量对酯化反应的影响,以及酯交换催化剂的种类及用量对脂肪酸甲酯(FAME)收率和产物组成的影响。实验结果表明,以凹凸棒土为吸水剂(用量为餐饮废油脂中游离脂肪酸质量的3%),且在酯化反应30m in时加入,酯化效果较好;以质量比为1∶1的NaOH和KOH混合物为催化剂进行两步酯交换反应时,催化剂的最佳用量依次为1.00%和0.75%(质量分数,基于油脂的质量),FAME收率最高达到96.33%。     

火灾自动报警与PLC自动控制相结合在油库消防系统中的应用

为了加强对油库消防监控,更好地保护油库的消防安全,宁波镇海国家储备油库的消防监控系统尝试了火灾自动报警与PLC自动控制相结合的监控模式,并取得了良好效果,使系统监控的智能化程度大为提高,其报警及灭火控制功能更为先进。文章主要阐述了该系统的特点、结构及功能,并结合实际工程应用介绍了该系统的工作流程,为该技术在其他类似工程的应用提供了有益的借鉴。     

构造性神经网络在测井岩性识别中的应用

测井岩性识别是石油勘探中十分重要的基础工作,准确的岩性识别结果可以为勘探和开发提供可靠的依据。人工神经网络方法可对复杂的高维数据进行非线性映射,在模式识别领域得到越来越广泛的应用。针对传统的BP神经网络算法存在收敛速度慢、隐层数以及隐层节点数难以确定等缺点,研究了一种构造性神经网络学习算法---级联算法（Cascade Correlation Algorithm,简称CC算法）及其在石油工程中的应用。采用该算法对甘肃镇原-泾川地区进行岩性识别研究,通过与BP神经网络的识别结果进行比较,体现出构造性神经网络的优越性。     

超稠油生产重交通道路石油沥青工艺探讨

超稠油的密度大、粘度高、轻油收率低、酸值高，沥青组成分布不合理，生产沥青困难。探索合适的超稠油生产沥青的加工工艺，不但可以解决超稠油加工困难问题，而且增加了生产道路沥青产品的原料资源。试验及生产证明，采用调和、预处理-蒸馏等工艺加工超稠油能够生产出合格的重交通道路石油沥青产品。