FEM model of the ohmic resistance of IP-SOFCs

In the present work, the ohmic resistance of an integrated planar-SOFC (IP-SOFC) has been evaluated by developing a model whose equations have been solved numerically through an FEM method. The model allows to estimate the distribution of voltage and current density in the cell. A comparison between simulated and experimental data of area specific resistance is reported, which shows satisfactory agreement. The mathematical model has also been used to carry out some parametric studies for optimisation purposes. Indeed, a reduction in cell pitch length and an increase in electrode thickness are predicted to lead to a reduction in ohmic losses in IP-SOFCs.     

溶胶-凝胶法制备纳米氧化锡及其性能表征

以SnCl4·5H2O为原料,采用溶胶-凝胶法制备了纳米SnO2粒子,研究了焙烧温度、碱的种类及反应物浓度对纳米SnO2粒子大小和分散状态的影响。采用XRD、TEM、ED等技术对SnO2纳米粒子的性能进行了表征。实验结果表明:用氨水和尿素作为沉淀剂,控制反应结束时pH值为7,在600℃焙烧,制备得到粒子尺寸约为15nm、分散性良好的纳米SnO2粒子。     

不锈钢冶炼过程中相关热力学问题的解析(Ⅰ)--原料预处理时的热力学问题

针对“电弧炉 多功能转炉 VOD”三步法不锈钢冶炼工艺，以脱磷为主线，从冶金热力学的角度对流程中涉及的几个重要工艺环节的可行性(包括电弧炉去硅保铬、铁水包同时脱磷脱硫等问题)进行了理论分析和计算。在此基础上，提出了强化冶炼和脱磷的工艺措施，从而为不锈钢冶炼全流程控制磷及优化脱磷工艺提供了理论依据。     

喷雾干燥法制备石榴状嵌套结构MoS2

将硫代钼酸盐溶液用喷雾干燥法获得前驱体,通过分解前驱体制备了嵌套结构MoS2.前驱体在650℃下分解5小时获得的MoS2颗粒,具有石榴状球形结构,且内部嵌套有较小的多面体.本文结合已有报道讨论了它的形成和生长机制.     

在备件招标采购中运用"定质比价法"初探

针对公司在备件采购中存在的质量、价格等问题，探讨了如何使用“定质比价法”这一新的招标采购方法来提高备件质量、降低成本。     

Numerical experiments of preconditioned Krylov subspace methods solving the dense non-symmetric systems arising from BEM

Discretization of boundary integral equations leads, in general, to fully populated non-symmetric linear systems of equations. An inherent drawback of boundary element method (BEM) is that, the non-symmetric dense linear systems must be solved. For large-scale problems, the direct methods require expensive computational cost and therefore the iterative methods are perhaps more preferable. This paper studies the comparative performances of preconditioned Krylov subspace solvers as bi-conjugate gradient (Bi-CG), generalized minimal residual (GMRES), conjugate gradient squared (CGS), quasi-minimal residual (QMR) and bi-conjugate gradient stabilized (Bi-CGStab) for the solution of dense non-symmetric systems. Several general preconditioners are also considered and assessed. The results of numerical experiments suggest that the preconditioned Krylov subspace methods are effective approaches solving the large-scale dense non-symmetric linear systems arising from BEM.     

Nodally exact Ritz discretizations of 1D diffusion–absorption and Helmholtz equations by variational FIC and modified equation methods

This article presents the first application of the Finite Calculus (FIC) in a Ritz-FEM variational framework. FIC provides a steplength parametrization of mesh dimensions, which is used to modify the shape functions. This approach is applied to the FEM discretization of the steady-state, one-dimensional, diffusion–absorption and Helmholtz equations. Parametrized linear shape functions are directly inserted into a FIC functional. The resulting Ritz-FIC equations are symmetric and carry a element-level free parameter coming from the function modification process. Both constant- and variable-coefficient cases are studied. It is shown that the parameter can be used to produce nodally exact solutions for the constant coefficient case. The optimal value is found by matching the finite-order modified differential equation (FOMoDE) of the Ritz-FIC equations with the original field equation. The inclusion of the Ritz-FIC models in the context of templates is examined. This inclusion shows that there is an infinite number of nodally exact models for the constant coefficient case. The ingredients of these methods (FIC, Ritz, MoDE and templates) can be extended to multiple dimensions     

小议变动成本法的合理性

企业对盈亏临界点的计算通常是以变动成本法为基础，但也有以制造成本法为计算基础的，对于这两种成本方法计算的几种盈亏临界点的情况，本文结合案例，通过比较分析认为：盈亏临界点的计算应当以变动成本法为基础更为合理。     

PV module dynamic impedance and its voltage and frequency dependencies

The paper presents a derivation of the dynamic impedance of a PV module. At each bias voltage, the general form of the impedance describes a semicircular locus in the complex impedance plane. Intercepts of each impedance locus yield series, shunt and dynamic resistance of a module. Determinations of the dynamic impedance of a x-Si PV module in the dark with five reverse bias voltages and over a frequency range of 1 Hz to 60 kHz are made. The experimental results validate the derived general form of dynamic impedance.     

Direct synthesis and catalytic performance of ultralarge pore GaSBA-15 mesoporous molecular sieves with high gallium content

Mesoporous GaSBA-15 molecular sieves with different n_Si/n_Ga ratios have been directly synthesized using Pluronic 123 triblock polymer as a structure-directing agent by pH-adjusting method. The mesoporous materials have been characterized using ICP-AES, XRD, N₂ adsorption, ⁷¹Ga-MAS NMR, SEM and TEM. ICP-AES studies show a high amount of gallium incorporation on the silica pore walls. The structural and textural properties of calcined GaSBA-15 are characterized by XRD and N₂ adsorption. ⁷¹Ga MAS NMR results demonstrate that a high amount of tetrahedral-gallium could be substituted for Si in the framework of SBA-15. TEM and FE-SEM images show the uniform pore diameter and rope-like hexagonal mesoporous structure of GaSBA-15. These GaSBA-15 materials have been used as catalysts for vapour-phase t-butylation of 1,2-dihydroxybenzene (DHB) for selective synthesis of 4-t-butylcatechol (4-TBC) under different reaction conditions. GaSBA-15(10) gave the highest 93.2% conversion of DHB and 95.7% selectivity of 4-TBC as compared with other GaSBA-15 catalysts.