Emission of trace toxic metals during pulverized fuel combustion of Czech coals

A study of the trace elements emission (As, Se, Cd, Co, Cr, Cu, Zn, Hg, Tl, Pb, Ni, Sn, Sb, V, Mn and Fe) from pulverized coal combustion has been made at six heating and power stations situated in the Czech Republic. The amount of chlorine in coal has considerable influence on volatilization of some elements such as Zn, Cu, Pb, Hg and Tl, which is explained by the formation of thermodynamically stable compounds of these elements with chlorine. Generally, the affinities for Cl follows the order Tl > Cu > Zn > Pb > Co > Mn > Sn > Hg. The experimental data indicates enrichment of some of the trace toxic elements in the emissions (Cu, Zn, As, Se, Cd, Sn, Sb, Hg and Pb) and good agreement was obtained by thermodynamic equilibrium calculations with a few exceptions. In the case of Fe, Mn, Co, Cr and Sn calculated values are overestimated in the bottom ash and there are zero predicted amounts of these elements in the fly ash. In comparison, the results from experiments show up to 80% of these elements retained in fly ash. This implies that there exist additional steps leading to the enrichment by Fe, Mn, Co, Cr and Sn of small particles. Such mechanisms could include the ejection during devolatilization of small inorganic particles from the coal of bottom ash particles, or disintegration of the char containing these metals to small particles of fly ash. On the other hand, there are slightly overestimated or similar values of relative enrichment factors for As, V, Cu, Cd, Sb, Tl and Pb in the fly ashes and zero predicted values for bottom ashes. Our experimental results show about 5% or less of these elements are retained in bottom ashes, so they probably remain in the bottom ash inside unburned parts of coal. Copyright © 2003 John Wiley & Sons, Ltd.     

油气集输系统新增产能建设拓扑优化方法研究

在油气集输新增产能建设中,为充分利用已建管网系统的处理能力,达到降低投资,提高经济效益的目的,进行了油气集输新增产能建设布局优化方法的研究。针对新建集输管网为树状结构的情况,建立了油气集输系统新增产能建设拓扑优化的数学模型,讨论了计算复杂性问题。根据模型的特点,将问题分解为拓扑级优化和几何级优化两个子问题,并通过它们之间的迭代进行求解。实例计算表明,所建立的数学模型正确,求解方法可行,能用于工程实际设计。     

利用多普勒信息的波达方向最大似然估计方法

为了充分利用信号的时域特性来改善信号波达方向（ＤＯＡ）的估计性能，本文从最大似然估计出发，推导出了有限快拍，低信噪比情况下多普勒信号波达方向的迭代估计计算法，为进一步减小运算量，本文还推导了一种简化算法，本文提出的两种算法对低信噪比，少快拍数下多普勒信号的ＤＯＡ估计性能比不利用时域特性的ＭＬ方法有明显改善，Ｍｏｎｔｅ－Ｃａｒｌｏ实验验证了本文方法的有效性。     

EXPERIMENTAL STUDIES AND NUMERICAL CALCULATION ON TURBULENT BOUNDARY LAYER OF WATER FLOW ALONG CURVED SURFACE

This paper will introduce experimental studies and numerical calculation onturbulent boundary layer of water flow along curved surface in our country in recent years.Onthe basis of the experimental studies,the effects of curvature and roughness on velocitydistribution and pressure distribution and the change of turbulent flow boundary layer onoverflow bucket concave surface is discussed.We proposed the empirical formula of velocity,pressure and the change of turbulent flow boundary layer on outlet bucket concave.According tothe momentum principle,we have deduced the momentum integral equation full water depthboundary layer and using the element as control unit inside the boundary layer on concavesurface of bucket.Combining with continuity equation,we have computed the boundary layerdevelopment on the bucket of a spillway.Compared with the field experimental data,thecalculation results are available.Under polar coordinates,a mathematical model for simulatingtime-averaged flow characteristics in concave surface of bucket is established.The turbulent flowfield on concave surface of bucket is calculated by SIMPLE method and this mathematicalmodel.The flow velocity field,pressure field,distribution of turbulent kinetic energy,distribution of turbulent energy dissipating rate and distribution of shear stress are available.Thecalculation value is consistent with measured test data.     

带限信号高频重建的一种新的正则外推算法

本文提出生种新的带限信号的外推方法，该方法能够很好地抑制噪声干扰，且计算复杂性较低，本文给出算法，证明了收敛性，最后给出了误差计算机实验结果。     

CPAM的分子参数对页岩抑制性的影响

通过合成的一系列具有不同分子量的聚丙烯酰胺的阳离子化制得具有不同分子参数的阳离子聚丙烯酰胺（ＣＰＡＭ）。经评价实验就分子参数对页岩抑制性的影响进行研究     

一个矢量形式的双圆弧插值算法

本文在分析数控插补最常用的双圆弧插值算法特点的基础上，将以局部坐标系中的三角运算为核心的传统双圆弧插值算法，改造成为以整体坐标系中的线性运算为核心的矢量形式的双圆弧插值算法，从而减少了计算的复杂性和程序的复杂性，提高了效率和可靠性。     

激光热源形成过程的定量描述

研究了热传导方程的通解，进而提出激光热源形成的微观机理和热源形成过程的三个理论计算式。对激光热效应的应用具有指导意义。     

热分层流动计算中若干差分格式的比较

本文应用常规的守恒方程及湍流模型，对二维池内热分层流动建立了数学模型，并在Ｐａｔａｎｋａｒ的压力校正法基础上对该数学模型进行了数值计算，计算中的差分格式为乘方格式、一阶迎风、二阶迎风和ＱＵＩＣＫ。通过与实验的比较分析，建议计算应采用ＱＵＩＣＫ格式，并在进行风格独立性试验的基础上使用加密网络。     

变形温度和变形程度对Ti－31合金性能和组织的影响

通过高温和室温拉伸试验，研究了变形温度和变形程度对Ｔｉ－３１合金板材性能和组织的影响。结果表明，合金在７５０～８５０℃的温度下变形５％～２０％空冷后，其室温机械性能均能达到材料的技术指标要求。并发现了材料在９００℃的临界变形区。