全文获取类型
收费全文 | 28428篇 |
免费 | 2129篇 |
国内免费 | 973篇 |
专业分类
电工技术 | 432篇 |
技术理论 | 1篇 |
综合类 | 1263篇 |
化学工业 | 12950篇 |
金属工艺 | 540篇 |
机械仪表 | 410篇 |
建筑科学 | 1047篇 |
矿业工程 | 241篇 |
能源动力 | 710篇 |
轻工业 | 2889篇 |
水利工程 | 77篇 |
石油天然气 | 2832篇 |
武器工业 | 267篇 |
无线电 | 1812篇 |
一般工业技术 | 5286篇 |
冶金工业 | 348篇 |
原子能技术 | 136篇 |
自动化技术 | 289篇 |
出版年
2024年 | 149篇 |
2023年 | 459篇 |
2022年 | 510篇 |
2021年 | 711篇 |
2020年 | 777篇 |
2019年 | 806篇 |
2018年 | 760篇 |
2017年 | 946篇 |
2016年 | 991篇 |
2015年 | 923篇 |
2014年 | 1484篇 |
2013年 | 1683篇 |
2012年 | 1789篇 |
2011年 | 1963篇 |
2010年 | 1407篇 |
2009年 | 1548篇 |
2008年 | 1428篇 |
2007年 | 1687篇 |
2006年 | 1750篇 |
2005年 | 1355篇 |
2004年 | 1202篇 |
2003年 | 1158篇 |
2002年 | 1063篇 |
2001年 | 950篇 |
2000年 | 767篇 |
1999年 | 658篇 |
1998年 | 568篇 |
1997年 | 412篇 |
1996年 | 278篇 |
1995年 | 220篇 |
1994年 | 224篇 |
1993年 | 193篇 |
1992年 | 155篇 |
1991年 | 118篇 |
1990年 | 64篇 |
1989年 | 51篇 |
1988年 | 42篇 |
1987年 | 32篇 |
1986年 | 33篇 |
1985年 | 69篇 |
1984年 | 50篇 |
1983年 | 38篇 |
1982年 | 36篇 |
1981年 | 3篇 |
1980年 | 14篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1959年 | 1篇 |
1951年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
从测得的竞聚率计算了单体链节在聚[苯乙烯-甲基丙烯酸β(甲基亚硫酰基)乙酯](PSM)中的序列分布。苯乙烯(S)或甲基丙烯酸β(甲基亚硫酰基)乙酯(M)的长序列的概率随着PSM中相应单体含量的增加而增加。对于S和M摩尔分数大致相等的PSM,单体链节的长序列分布函数值相接近。用与此结构相近的PSM合成的稀土金属络合物,其催化活性不佳。在M短序列分布和S长序列分布较高的情况下,络合物的催化活性最好。所得聚丁二烯的微观结构与PSM中单体单元的分布无关。 相似文献
22.
NaY晶化母液制备硅铝胶的技术探讨 总被引:3,自引:0,他引:3
在导向剂法合成Y型分子筛的工艺下,晶化母液中SiO2的含量为50~55g/l,Na2O含量为20~25g/l,相当于模数为1.65~2.58的稀水玻璃,将晶化母液分离处理后,在晶化母液中加入一定量的硫酸铝溶液使硅沉淀,经过滤和水洗后即可制备出合格的硅铝胶,以便进行重新利用。 相似文献
23.
24.
A quantum chemical study of the binding of Li+ cation to polyalkyloxides has been carried out. The lithium cation interaction with three polyalkyloxides (polyethylene oxide (PEO), polytrimethylene oxide (PTMO), and polypropylene oxide (PPO)) has been investigated using ab initio molecular orbital theory at the HF/6-31G* level with molecular models for the polymers. Coordination by one to six oxygens was considered. In addition, higher level calculations were carried out using G3(MP2) theory for coordination of Li+ by one oxygen. For coordination of lithium by one oxygen, the binding energy ordering is PTMO>PPO>PEO, with PTMO having the largest lithium cation affinity. The same ordering is found for larger coordination numbers with the exception of coordination by six oxygens, where the ordering changes due to the steric interactions. 相似文献
25.
Banded textures produced in a thermotropic liquid crystal polymer by shearing between glass slides are examined by using both transmission electron and polarized light microscopy. The periodic variation in director orientation about the shear axis, as measured by light microscopy, is shown to be distinctly different from that indicated by electron diffraction. Measurements of birefringence and observation of Zernicke phase contrast indicate periodic variations in optical properties of the polymer, in step with the bands. Such effects are accounted for in terms of a synchronous rotation of the planar aromatic groups about the molecular chain axes. Evidence for an out-of-plane component of molecular orientation is also presented. 相似文献
26.
采用溶胶凝胶方法成功地制备了掺杂稀土铽离子的 Zn O和 Mg0 .1 5Zn0 .85薄膜。通过对 X射线衍射结果的分析表明 ,稀土离子替代了 Zn2 +的格位 ,进入了半导体基质的晶格中。从阴极射线发光结果可以发现 ,在Mg0 .1 5Zn0 .85O基质中 ,可以观察到来源于稀土铽离子各能级的发射 ,而 Zn O:Tb的薄膜只能观察到较强的铽离子 5D4 — 7F5能级的跃迁。这可能是由于 Mg0 .1 5Zn0 .85O基质的能隙 (3 .65 e V)比 Zn O更宽 (3 .3 e V) ,其对铽离子的能量传递更有效的缘故。 相似文献
27.
28.
Poly(vinyl alcohol) is crosslinked in dilute solution (c=0.1 wt%) with glutaraldehyde. The reaction product is characterized by viscometry and gel permeation chromatography (g.p.c.). The intrinsic viscosity decreases with increasing degree of crosslinking and does not depend on temperature. G.p.c. reveals that the reaction product is not homogeneous, but consists of a mixture of particles with different sizes, possibly both intra- and intermolecularly crosslinked molecules. The intramolecularly crosslinked molecules are smaller in size than the initial polymer molecules and their size depends on the degree of crosslinking. They possess a narrow particle size distribution even if the initial polymer sample had a broad molecular weight distribution. 相似文献
29.
Paul J. Flory 《Polymer International》1985,17(2):96-102
The earliest investigations on rubber elasticity, commencing in the 19th century, were necessarily limited to phenomenological interpretations. The realisation that polymers consist of very long molecular chains. commencing c. 1930, gave impetus to the molecular theory of rubber elasticity (1932-). according to which the high deformability of an elastomer, and the elastic force generated by deformation, stem from the configurations accessible to long molecular chains. Theories of rubber elasticity put forward from 1934-1946 relied on the assumption that the junctions of the rubber network undergo displacements that are affine in macroscopic strain. The theory of James and Guth (1947) dispensed with this premise, and demonstrated instead that the mean positions of the junctions of a ‘phantom’ network consisting of Gaussian chains devoid of material properties are affine in the strain. The vital significance of the distinction between the actual distribution of chain vectors in a network and their distribution if the junctions would be fixed at their mean positions went unnoticed for nearly 30 years. Experimental investigations, commencing with the incisive work of Gee in 1946. revealed large departures from the relationship of stress to strain predicted by the theories cited. This discrepancy prompted extensive studies, theoretical and experimental, during succeeding years. Inquiry into the fundamentals of polymer networks, formed for example by interlinking very long polymer molecules, exposed the need to take account of network imperfections, typically consisting of chains attached at only one end to a network junction. Various means were advocated to make corrections for these imperfections. The cycle rank ζ of the network has been shown (1976) to be the fundamental measure of its connectivity, regardless of the junction functionality and pattern of imperfections. Often overlooked is the copious interpenetration of the chains comprising typical elastomeric networks. Theories that attempt to represent such networks on a lattice are incompatible with this universal feature. Moreover, the dense interpenetration of chains may limit the ability of junctions in real networks to accommodate the fluctuations envisaged in the theory of phantom networks. It was suggested in 1975 that departures from the form predicted for the elastic equation of state are due to constraints on the fluctuations of junctions whose effect diminishes with deformation and with dilation. Formulation of a self-consistent theory based on this suggestion required recognition of the non-affine connection between the chain vector distribution function and the macroscopic strain in a real network, which may partake of characteristics of a phantom network in some degree. Implementation of the idea was achieved through postulation of domains of constraint affecting the equilibrium distribution of fluctuations of network junctions from their mean positions. This led in due course to a theory that accounts for the relationship of stress to strain virtually throughout the ranges of strain accessible to measurement. The theory establishes connections between structure and elastic properties. This is achieved with utmost frugality in arbitrary parameters. 相似文献
30.
Sol–gel films are actively investigated during the last decade as possible candidates for environmentally friendly pre-treatments. However, the important drawback in this case is the lack of active corrosion protection and self-healing ability. 相似文献