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81.
氮化硅的性能及其聚合物材料 总被引:1,自引:0,他引:1
陈继兰 《高分子材料科学与工程》1996,12(6):144-147
叙述了氮化硅(Si3N4)的性能并制备了含Si3N4的聚合物材料,这种材料在医学上具有重要价值,对改变医学方面的概念、和对促进人类健康长寿具有重要意义。 相似文献
82.
Shiro Matsuoka 《Journal of research of the National Institute of Standards and Technology》1997,102(2):213-228
The high frequency end of the relaxation spectrum for polymer molecules involves the rotation of the segmental bonds. This fast relaxation process, however, cannot take place easily in the condensed state crowded by the densely packed conformers, necessitating the slower cooperatively synchronous relaxation. As the temperature is lowered, the domain of cooperativity grows towards the infinite size at the Kauzmann zero entropy temperature, though actually the system deviates from the equilibrium as the glass transition intervenes typically at 50 K above that temperature. The excess enthalpy and entropy drop faster than predicted by the rotational isomeric states which would reach zero only at 0 K. The real ΔCP is greater than that of the RIS value. The actual volume in excess of the crystalline lattice volume, however, points towards zero at 0 K. Thus, a polymer with higher Tg typically exhibits a lower density and modulus in the glassy state. Since the configurational entropy associated with the free volume is proportional to the logarithm of the latter, the Kauzmann temperature can be scaled by ln M, where M is the algebraic average of the conformer molecular weight. The temperature dependence of the most dominant, i.e., the largest equilibrium domain size will result in the Adam-Gibbs and Vogel equations for the characteristic relaxation time. The cooperative domain distribution leads to the relaxation spectrum that follows a power law. The relationship between the characteristic relaxation time and the rate of physical aging is derived. 相似文献
83.
84.
The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002 相似文献
85.
为了不使用任何还原剂而获得聚合物固载高分散零价双金属加氢催化剂,利用金属蒸气法制备了3种不同Pd/Cu质量比的聚合物固载双金属原子簇。透射电镜(TEM)和X衍射(XRD)测定表明,Pd-Cu原子簇粒度很小,平均直径小于3.0nm。X射线光电子能谱(XPS)表明,Pd和Cu均为零价态。Pd-Cu原子簇在异丙叉加氢反应中具有很高的活性和选择性。这些结果提供了令人信服的证据,即金属蒸气法可用于在聚合物孔穴内直接而温和地置入小的零价金属原子簇,而且这样制备的聚合物固载金属原子簇很适合于催化应用。 相似文献
86.
Gelation Properties of Ovalbumin as Affected by Fatty Acid Salts 总被引:2,自引:0,他引:2
NAOKO YUNO-OHTA HIROKO TORYU TAKAHIKO HIGASA HIDEO MAEDA MITSUKO OKADA HIROYUKI OHTA 《Journal of food science》1996,61(5):906-910
The physicochemical properties of heat-induced ovalbumin (OVA) gels containing fatty acid salts (FAS) were investigated. Water-holding ability and transparency markedly increased in the presence of sodium caprate or sodium laurate. At 9% of the protein concentration transparent and hard gels formed; at 7%, transparent and soft gels formed. Scanning electron microscopy showed that the transparent gels had a more homogeneous structure than turbid gels without FAS. Differential scanning calorimetry indicated that denaturation temperature of OVA was decreased and the peaks became broader after addition of FAS. 相似文献
87.
主要针对核桃软糖在气温稍高、湿度较大的环境中容易粘结,造成质量下降和贮藏期缩短的现象,通过改进配方和工艺,防止和延缓核桃软糖粘结,延长了产品的贮藏时间。 相似文献
88.
通过室内实验及同位素测井技术评价高分子聚合物驱油效果 总被引:1,自引:0,他引:1
2500万超高分聚合物室内驱油实验研究了聚合物分子量、浓度、粘度、聚用量、段塞组合等各项性能指标对驱油效果的影响。本文根据室内实验结果,在北一区断西注聚后期开展矿场试验,取得了较好的开发效果。试验前后对比,注入粘度明显增大,月含水上升速度得到有效控制,吸入剖面有了新的动用,有63.1%的油井出现了明显的二次受效特征,取得了显著的经济效益。同时对驱油效果进行系统分析。驱油效果表明:应用2500万超高分聚合物是进一步提高聚驱采收率的有效途径。 相似文献
89.
溶胶-凝胶法制备疏水型SiO-2气凝胶 总被引:2,自引:0,他引:2
以正硅酸乙酯 (TEOS)为硅源 ,用三甲基氯硅烷 (TMCS)为疏水试剂 ,通过溶胶 凝胶法在室温下制备出疏水型SiO2 气凝胶。用傅立叶变温红外 (FT IR)、扫描电镜 (SEM)、透射电镜 (TEM)和吸水性能对疏水型SiO2气凝胶的结构和性能进行了研究 相似文献
90.