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61.
The catalytic reforming of methane by steam is an important industrial process that produces H2, CO and CO2, thus chemically transforming natural gas, coal gas and light hydrocarbon feedstocks to synthesis gas or hydrogen fuel. Methane-steam reforming may consist of a number of reactions depending on the reforming catalyst, operating conditions and feedstock composition, The typical industrially desirable reactions are the reverse of methanation (CH4 + H2O = CO + 3H2) and the water-gas shift (CO + H2O = CO2 + H2). Both reactions are equilibrium limited and the composition of the mixture that exits the reformer is in accordance with the one calculated thermodynarmically. Removal of reaction products at the reactor exit by means of selective membrane permeation can offer improved CH4 conversions and CO2 and H2 yields, assuming the subsequent utilization of the reject streams by a second methane-steam reformer. We numerically investigated the feasibility of a system of two tubular methane-steam reformers, in series with an intermediate permselective polyimide membrane permeator, as means of improving the overall CH4 conversion and the H2, CO2 yields over conventional methane-steam reforming equilibrium reaction-separation schemes that are currently in industrial practice. The unique feature of the permselective polyimide separator is the simultaneous removal of H2 and CO2 versus CH4 and CO from the reformed streams. The utilized 6FDA-3,3', 5,5'-TMB aromatic polyimide was reportedly characterized [10] and found to exhibit superior permselective properties compared with other polyimides of the same or different dianhydride sequence. Conversion and yield of the designed reactor-membrane permeator reforming system can be maximized by optimizing the permselective properties of the membrane material and the design variables of the reactors and the permeator. Product recovery and purity in the permeate stream need to be compromised to overall enhance methane conversion and product yield. The operating variables that were varied to investigate their effect on the magnitude of conversion and yield included the inlet pressure of the first reformer, the temperature of both reformers, and the permeator dimensionless Pe' number (variation of the first two variables results to a drastic change in the composition of the reformed stream that enters into the permeator). The numerical results show that the new reformer-membrane permeator cascade process can be more effective (it can offer increased CH4 conversions and H2, CO2 yields) than conventional equilibrium methane-steam reforming reaction-separation processes currently in practice. 相似文献
62.
微铬含量CO中温变换催化剂本征动力学的研究崔波,赵素芳,刘鹏照,宋世英,张洪全(青岛化工学院化学工程系,青岛266042)关键词:催化剂,一氧化碳变换反应,铁催化剂,动力学1前言一氧化碳变换反应是化学工业中制氢的重要反应,长期以来所用的一氧比碳中变催... 相似文献
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64.
研究了文本数字水印在追溯涉密纸质文档中的重要意义,介绍了常见的文本数字水印技术,分析了Brassil经典行移编码文本数字水印技术,在算法的标记策略中引入检验编码,文本行分割划段和引入基调行三个方面进行改进,改进后算法具有更大水印信息容量,更强的鲁棒性和可控的计算量. 相似文献
65.
Dewi Tristantini Sara Lögdberg Börje Gevert Øyvind Borg Anders Holmen 《Fuel Processing Technology》2007
The Fischer–Tropsch synthesis over Co/γ-Al2O3 and Co–Re/γ-Al2O3 was investigated in a fixed-bed reactor at 20 bar and 483 K using feed gases with molar H2/CO ratios of 2.1, 1.5 and 1.0 simulating synthesis gas derived from biomass. With lower H2/CO ratios in the feed, the CO conversion and the CH4 selectivity decreased, while the C5+ selectivity and olefin/paraffin ratio for C2–C4 increased slightly. The water–gas shift activity was low for both catalysts, resulting in high molar usage ratios of H2/CO (close to 2.0), even at the lower inlet ratios (i.e. 1.5 and 1.0). For both catalysts, the drop in the production rate of hydrocarbons when shifting from an inlet ratio of 2.1 to 1.5 was significant mainly because the H2/CO usage ratio did not follow the change in the inlet ratio. The hydrocarbon selectivities were rather similar for inlet H2/CO ratios of 2.1 and 1.5, while significantly deviating from those for an inlet ratio of 1.0. With the studied catalysts, it is possible to utilize the advantages of an inlet ratio of 1.0 (higher selectivity to C5+, lower selectivity to CH4, no water–gas shifting of the bio-syngas needed prior to the FT reactor) if a low syngas conversion is accepted. 相似文献
66.
A novel process was developed for the bitumen emulsion upgrading, wherein emulsion breaking and upgrading occurred in the same reactor using H2 generated in situ from the water in the emulsion via the water gas shift reaction (WGSR). In this study, dibenzothiophene (DBT) was chosen as a model compound to investigate the effect of water and in situ H2 on hydrodesulfurization (HDS). All the experiments were performed in a 1-L autoclave reactor at temperatures between 300 and 380 °C using in situ H2 and ex situ H2 (externally supplied H2) over a dispersed Mo catalyst formed from phosphomolybdic acid (PMA). At very low water content, water was found to promote the HDS reaction in the ex situ H2 run probably because it facilitates the formation of more active dispersed MoSx species. At higher water content, however, water inhibits every individual reaction in the reaction network in the HDS of DBT, blocking the hydrogenation pathway more than the hydrogenolysis pathway. The relative reactivity of the in situ and ex situ H2 depends on the water content present in the reaction system. At an optimized mole ratio of H2O:CO (1.35), higher HDS activity was observed in the in situ H2 run compared to ex situ H2 run, and particularly, the hydrogenation pathway was promoted in the in situ H2 run. 相似文献
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68.
为了解决传统零电压零电流开关(ZVZCS)PWMDC/DC变换器滞后桥臂零压范围较小、环流损耗大的问题,采用串联双变压器、滞后桥臂带辅助网络和倍压整流电路,提出了一种新型零电压零电流移相全桥变换器.首先分析了变换器在稳态下的各种工作状态,给出了相关计算公式,并制作了一台实验样机进行原理验证.实验结果表明:该变换器能够在较宽的负载范围内实现滞后桥臂的零电压开通,重载下实现零电流开通,从而极大地降低高频电路初级开关损耗和次级电磁干扰. 相似文献
69.
通过对K-原子的理论分析,利用DD光学模型势,数值求解相应的Klein-Gordon方程,得到了从K6-Li到K5?6 Ni中N=Z的K?原子的能级移动和能级宽度,理论计算结果与实验数据基本一致,其结果表明了DD光学模型势在K-原子中应用的正确性. 相似文献
70.
介绍了直接甲酸燃料电池(DFAFC)阳极电催化机理,以及Pt基、Pd基附载型和非附载型阳极催化剂的发展状况,分析了金属合金d-带能级移动和金属表面偏析对直接甲酸燃料电池催化活性的影响,对筛选阳极催化剂合金材料具有一定的指导作用. 相似文献