Direct Spectroscopic Determination of Europium(Ⅱ) Concentration During Europium(Ⅲ) Electro-Reduction in Hydrochloric Acid Medium

UV-Vis spectroscopy was used to directly determine the concentration of Eu(Ⅱ) during electroreduction of Eu(Ⅲ) in hydrochloric acid medium. Electroreduction was carried out in a flow type electrolyzer with glassy carbon cathode at the constant potential of -800 mV vs. Ag/AgCl. The effects of oxygen and concentration of hydrochloric acid on the system were investigated. For 0.01 mol·L-1 hydrochloric acid, calibration curves for Eu(Ⅱ) absorption bands at 248 and 320 nm were constructed. Molar absorption coefficients were estimated to be 2016 and 648 L·mol-1·cm-1, respectively. The absorbance strongly decreased with decrease in pH of the solution, whereas concentration of chloride had only a negligible effect.     

Monolithic Catalysts with Low Noble-Metal Content for Exhaust Purification of Small Gasoline Engines

A series of low noble-metal coment monolithic catalysts for exhaust purification of small gasoline engines was investigated, and it was found that the Pt/Rh-OSM/Al2O3 （where OSM was oxygen storage material） catalyst with Ce0.5Zr0.5-MnOx（3%MnOx） OSM held low light-off temperature for CO, HC, and NO; quite wide three-way window, and outstanding thermal stability. The catalyst could efficiently comrol exhaust emission of small gasoline engines.     

Effect of Y2O3 Content on Microstructure of Gradient Bioceramic Composite Coating Produced by Wide-Band Laser Cladding

Hydroxyapatite (HA) ,a kind of bioactive materi-al , has wide application prospect in hard tissue re-placemen and repairment due to its si milar chemicalcomposition and crystallographic structure to that ofbone mineral[1 ,2]. Since HA has lowstrength (50 …     

稀土永磁及磁记录材料的矫顽力与有效激活体积

指出了文献 [1]中的一个错误。给出了不同模型的稀土永磁材料以及磁记录材料的矫顽力 Hc和有效激活体积υ之间的正确关系 ,这样的关系被表示成一个复杂的函数关系 ,同时指出 ,对不同模型的稀土磁性材料 ,这个函数关系是不同的     

担载型含稀土三组份体系在二氧化碳甲烷化反应中的催化性能

用浸渍法制备了一系列氧化锆担载的含稀土Ⅷ族金属催化剂，对其在二氧化碳甲烷化过程中的催化活性作了研究，并用漫反射紫外可见光谱，ＦＴＩＲ等手段对催化剂作了表征。结果表明，含稀土新型催化剂具有催化活性高，目标产物选择性好等优点；稀土主要以氧化物形式存在于催化剂表面，参与对氢及表面含碳物种的吸附及活化；含稀土三组份催化剂的活性与所添加稀土三价离子的４ｆ电子数有关。     

35CrMoCe稀土钢离子硫氮碳复合渗特性研究

采用金相显微镜，Ｘ射线衍射仪，透明电子显微镜，扫描电子显微镜等仪器分析对比３５ＣｒＭｏ钢和３５ＣｒＭｏＣｅ钢离子硫氮碳复合渗特性，探讨了稀土铈和加速离子硫氮碳复合渗的原因，研究结果表明，两种钢的复合渗层均由硫化物层，氮碳化物层的扩展层构成；稀土铈显著地提高了渗层深度，铈具有细化组织的作用，提供了更多可供氮碳原子扩散的通道。     

乳状液膜法制备草酸稀土

系统研究了在乳状液膜内水相直接制备草酸稀土的方法，讨论了内水相草酸浓度、表面活性剂浓度、载体浓度、外水相酸度和外水相稀土浓度对迁移率的影响，找到了制备草酸稀土的最佳条件，草酸稀土经灼烧所得的氧化物含ＲＥ２Ｏ３〉９９．５％，与萃取法相比，此方法具有成本低、能耗少、污染程度低的特点，具有工业化前景。     

羧酸酯稀土对聚氯乙烯的热老化稳定作用研究

用热烘法研究了羧酸酯稀土对聚氯乙烯的热老化稳定作用。利用紫外／可见光谱分析跟踪共轭双键在热老化过程中的变化，比较ＣＥＲＥＳ，有机锡及两者的复合稳定剂的热老化稳定性能，发现ＣＥＲＥＳ与有机锡的稳定性能相当，复合稳定剂具有协同效应。     

2000～2001年金属磁性功能材料新进展

综述了金属磁性功能材料在2000－2001年间的若干新进展，内容包括：（1）高性能稀土永磁合金；（2）高性能硅钢合金；（3）Fe-N系新磁性材料；（4）磁电子学；（5）形状记忆磁性材料。