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A novel synthesis methodology is reported for the preparation of NiS submicron particles in a green solvent 1-butyl-3methylimidazolium tetrafluoroborate (BMImBF4) ionic liquid (IL), using ultrasonic sonochemical technique. Structural, morphological and optical properties of nickel sulfide powders were obtained by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and diffuse reflectance spectroscopy (DRS). Composition was corroborated by energy dispersive X-ray spectroscopy (EDXS), both in the SEM and in the TEM. Regular shape particles were obtained under high-intensity ultrasonic irradiation for 105 min from the reaction between nickel nitrate and thioacetamide in ethanol/BMImBF4 (80:20), respectively. After vacuum annealing treatment at 180 °C overnight, spherical crystalline NiS particles were observed. The powders showed a band gap of 0.74 eV. 相似文献
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Efficient,Selective, and Reversible SO2 Capture with Highly Crosslinked Ionic Microgels via a Selective Swelling Mechanism
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Ling Xia Qing Cui Xian Suo Yuhui Li Xili Cui Qiwei Yang Jianhong Xu Yiwen Yang Huabin Xing 《Advanced functional materials》2018,28(13)
SO2 capture through physisorption is a promising environmental benign technology to eliminate the emission of SO2. However, designing an efficient adsorption material with high capacity and selectivity of SO2 as well as excellent reversibility remains challenging. Here, a class of highly crosslinked nonporous poly(ionic liquid)s (PILs) xerogels is prepared with high ionic density by photopolymerization of Gemini IL monomers and a microfluidic technology is further explored to prepare the corresponding monodisperse PIL microgels with uniform and controllable sizes at the diameter range from 43 to 250 µm. This kind of novel dense nonporous ionic xerogels/microgels completely exclude the adsorption of common gases (CO2, CH4, etc.), but exhibit very high SO2 adsorption capacity (498 mg g?1) via selective swelling mechanism. Unprecedented SO2/CO2 and SO2/CH4 uptake selectivities with the value up to 614 and 1992, respectively, are achieved. The selective swelling mechanism is validated by optical microscope and differential scanning calorimetry measurements. More importantly, these kinds of xerogels show excellent reversibility in adsorption–desorption cycles. Column breakthrough experiments confirm the excellent performance of these PIL xerogels in SO2 capture. This work demonstrates that designing a nonporous material that has specific swelling interactions with certain molecules can be an effective strategy for realizing extremely high selectivity. 相似文献
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掺稀土离子液体激光器的研究进展 总被引:5,自引:0,他引:5
综合介绍了掺稀土离子液体激光器的主要发展历程,分析了掺稀土离子液体激光材料研究过程中需要解决的主要问题包括降低无辐射跃迁、增大溶解度和减少热致折射率梯度引起的光偏折损耗等.重点介绍了稀土离子在溶液中的无辐射跃迁机理以及降低无辐射跃迁的措施. 相似文献
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对共光路径向剪切干涉(CRSI)的近场重建算法和LCTV的强度调制特性进行了分析.首先利用CRSI测量了实验中的LCTV强度调制特性的线性区域,然后将LCTV处于强度调制状态下模拟产生一任意强度分布,并使其灰度值限定在它的强度调制线性区域内,再进行径向剪切干涉测量,获取了该强度分布的干涉条纹图.从干涉图中提取出背景强度后,运用环路径向剪切干涉仪的近场重建迭代算法进行运算,得到了模拟光强的近场分布.本文同时对这一近场分布进行了数值仿真与实验研究,并对实验中出现的误差从理论上进行了合理的分析,进一步验证了实验方法的可行性和环路径向剪切干涉仪的近场重建迭代算法的正确性. 相似文献
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Min-Kun Dai Jan-Tien Lian Tai-Yuan Lin Ming-Chung Chen Yian Tai Yang-Fang Chen 《Organic Electronics》2012,13(11):2229-2234
The influence of nematic liquid crystal molecules on the electrical properties and microstructure of polymer semiconductors poly(3-hexylthiophene) (P3HT) was investigated. It was found that the introduction of nematic liquid crystal molecules can significantly improve the performance of P3HT thin-film transistors, providing better electrical characteristics and enhanced mobility. The field-effect mobility of the device with liquid crystal modification can be enhanced by up to a factor of ten with respect to that of the pure P3HT device. UV–visible absorption spectroscopy, X-ray diffraction, and atomic force microscopy measurements show that the enhancement of charge-carrier mobility is achieved through a more highly organized morphology and a reduction in the density of traps presents in the P3HT/liquid crystal structure. The results shown here therefore illustrate a high-performance solution-processable thin-film transistors, which is quite feasible and can pave a key step for the practical applications of organic electronic devices. 相似文献