MEMS气体流量传感器的简易流量测试装置

为了完成所研制的MEMS气体流量传感器样品的流量测试与标定,设计制作了一种由标准流量发生器和传感器信号读出与数据采集电路组成的简易流量测试装置。标准流量发生器由注射器和可更换的砝码组成,利用不同的砝码配重,在注射器出气口产生合适的恒定气体流速。通过理论分析和Ansys有限元数值仿真,验证了简易标准流量发生器的可行性。传感器信号读出与数据采集电路基于内建多路A/D转换器的单片机实现,具有传感器加热电阻器的恒温控制、流量信号的数字检测和显示的功能。采用该简易流量测试装置对自行研制的MEMS气体流量传感器进行了流量测试与标定,获得了待测器件的标定参数、传感器流量测量的绝对误差和相对误差。     

Separation and identification of phenolic acids and related compounds by gas chromatography and fourier transform infrared spectroscopy

Phenolic acids and related compounds were separated by gas chromatography using three separate columns. One of these columns was coupled to a Fourier transform infrared spectrometer. The trimethylsilyl derivatives could be separated and identified by comparing the relative retention times of the three different columns. However, where there was overlap, the accompanying infrared data clearly distinguished between the questionable derivatives, thus enabling characterization of all derivatives.The use of trade, firm, or corporation names in this article is for the information and convenience of the reader. Such use does not constitute an official endorsement or approval by the U.S. Department of Agriculture or the Forest Service of any product or service to the exclusion of others that may be suitable.     

高精密恒温系统在NDIR气体分析仪中的应用

当前基于非分光红外（NDIR）技术的气体分析仪设计过程中存在很多干扰源,这些干扰源对检测精度影响的轻重程度各有不同,其中,红外池中,温度的稳定性对气体的吸收影响大,此外,对于特定的吸收气体,恒温点同样重要。设计了一种基于增量式PID算法的高精度温控系统,选择对气体吸收影响最小的恒温点,并控温范围为±0.1℃,相比现有同类温控系统,精度提高近10倍。通过试验比较不控温情况下的结果和应用在本恒温系统中的测试结果表明：高精度恒温系统下,NDIR气体分析仪的信噪比得到了明显改善。该成果将直接应用到国家＂十二·五＂计划项目中。     

动态三螺杆挤出机制备热塑性硫化胶的研究

对比分析了动态热塑性硫化胶(TPV)的加工设备,着重介绍了附加振动力场的三螺杆反应挤出机的结构特点以及利用该机进行三元乙丙橡胶/聚丙烯(EPDM/PP)的动态全硫化,对制品的物理力学性能和微观结构分别进行了测试分析和电镜扫描。结果表明,振动力场作用下EPDM/PP共混体系反应挤出动态硫化加工可有效地实现动态硫化反应、硫化橡胶的粉碎和分散以及相态反转,振动力场的作用明显提高了TPV性能。     

Study of Hydrodynamics,Mixing and Gas‐Liquid Mass Transfer in a Split‐Rectangular Airlift Reactor

Global hydrodynamic characteristics, liquid mixing and gas‐liquid mass transfer for a 63 L split‐rectangular airlift reactor were studied. Correlations for gas holdup and overall liquid circulation velocity were derived for the air‐water system as a function of the specific power input; these were compared to data and correlations for reactor volumes between 4.7 L and 4600 L. A partial recirculation of small bubbles in the riser was observed when U_gr > 0.03 m/s, which was attributed to the use of a single‐orifice nozzle as the gas phase distributor. The dimensionless mixing time and the overall axial dispersion coefficient were nearly constant for the range of gas flow rates studied. However, values of K_L/d_B were greater than those reported in previous studies and this is caused by the partial recirculation of the gas phase in the riser. While scale effects remain slight, the use of a gas distributor favouring this partial recirculation seems adequate for mass transfer in split‐rectangular airlift reactors.     

尾气脱硫装置在金隆公司的应用

介绍了新型高效尾气脱硫系统的设计及运行情况。该系统能确保尾气二氧化硫排放小于292mg／m^3，钠法和钙法运行时脱硫效率分别达到98％和95％。运行中循环液pH值和脱硫洗涤器喷嘴压力是影响脱硫效率的主要因素。     

除油型水力旋流分离器压降研究

采用各向异性k ε模型,用有限差分法,以SIMPLE算法为基础对旋流器内流场进行了数值模拟,通过数值计算得到了液液水力旋流分离器溢流管直径对压力降的影响、压降与流量的关系。通过算例与实验校验,得出各向异性κ ε模型能够模拟旋流器内湍流流场。     

溴虫腈土壤和甘蓝微量残留量的气相色谱法测定

采用气相色谱法定量分析溴虫腈土壤和甘蓝微量残留量。样品经丙酮提取 ,液 液分配及氧化铝柱层析法净化后 ,以GC ECD测定 ,DB 170 1毛细管柱 ,氮气为载气 ,柱温 2 6 0℃ ,汽化室温度 2 5 0℃ ,检测器温度 2 80℃ ,外标法定量。该方法快速、准确 ,在 0 0 1～ 2 0 0mg/L范围内线性相关系数r2 =0 9999,平均回收率 90 0 %～ 10 3 6 7% ,变异系数 4 4 8%～ 5 89% ,最小检测量 2× 10 12 g ,最低检出浓度 3 3× 10 4mg/kg。     

All-glass system for preparative gas chromatography using capillary columns

A zero dead-volume all-glass-lined stainless-steel effluent splitter with a modified thermal gradient collector was designed for preparative gas chromatography using glass capillary columns. This system gives efficient collection of extremely pure samples of the 1-ng to 10-g range for spectral analysis and biological testing.Approved as TA 15656 by the director of the Texas Agricultural Experiment Station in cooperation with ARS, USDA. Supported by the Texas Department of Agriculture interagency agreement IAC-0487 (78-79).     

Methods to determine solubility parameters of polymers using inverse gas chromatography

Experimental values of the Flory–Huggins parameter, χ, between polymers and solvents, are frequently used to determine the solubility parameters of the polymers. A method using nonlinear curve fitting of RTχ/V was compared to the linear regression method commonly used. It was found that the formulas for the solubility parameter were the same, but the linear method produced a slightly different entropy term. The nonlinear method gave a lower correlation coefficient and wider confidence intervals and was more effective at distinguishing systems than the linear model. The effect of the deviation of probes in the solubility parameter model is discussed. Using probes with low solubility parameters to measure the polymer solubility parameter gave wider confidence intervals. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2894–2902, 2004