The GIAO-SCF method for calculating isotropic nuclear magnetic shielding values has been utilized to explain certain features in the 1H-NMR spectrum of 2-methylene-8,8-dimethyl-1,4,6,10-tetraoxaspiro[4.5] decane. Population distributions of the low-energy conformers based on their ab initio energies were used to produce weighting factors for the individual calculated shielding values to calculate the weighted average of the shielding values for a complete set of conformers. The differences in 1H chemical shifts between the hydrogens of the two methyl groups and between the axial and equatorial hydrogens in 2-methylene-8,8-dimethyl-1,4,6,10-tetraoxaspiro[4.5] decane were shown to be due to energy differences between the chair and boat orientations of the six-membered ring and contribution from a twist-boat conformation. Results suggest a hypothesis that intramolecular differences in chemical shift might be calculated to a greater degree of accuracy than chemical shifts calculated relative to a standard. 相似文献
Energy windowing is an algorithmic alarm method that can be applied to plastic scintillator-based radiation portal monitor (RPM) systems to improve operational sensitivity to certain threat sources while reducing the alarm rates from naturally occurring radioactive material. Various implementations of energy windowing have been tested and documented by industry and at Pacific Northwest National Laboratory, and are available in commercial RPMs built by several manufacturers. Moreover, energy windowing is being used in many deployed RPMs to reduce nuisance alarms and improve operational sensitivity during the screening of cargo. This paper describes energy windowing algorithms and demonstrates how these algorithms succeed when applied to “controlled” experimental measurements and “real world” vehicle traffic data. 相似文献
Four experiments tested the hypothesis that people who are concerned with impression management cope with stereotype threat through denial. Consistent with this hypothesis, temporary employees threatened by a stereotype of incompetence (Study 1) and hostel-dwelling older adults (Study 2) were more likely to deny incompetence if they were high in impression management. African Americans (Study 3) showed a similar pattern of denying cognitive incompetence, which emerged primarily when they were interviewed by a White experimenter and had attended a predominantly Black high school. In Study 4, White students who expected to take an IQ test and were threatened by a stereotype of being less intelligent than Asians were more likely to deny that intelligence is important if they were high in impression management. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
In industry continuous or impulse noise does not occur exclusively; rather it is a combination of both. If low-level continuous noise or impulse noise (below 120 dB) is added to an already existing high-level continuous noise this often numerically causes no essential increase in the rating level. Yet, it cannot be expected that also aural strain of these exposures is always negligible. Therefore, in a cross-over test series, ten male subjects (Ss) were exposed to white noise of 94 dB(A) for 1 h (TS I), energy-equivalent to an 8 h-rating level LArd of 85 dB(A). In a second test series (TS II) the same exposure was combined with 900 energetically negligible 5-ms impulses with a noise level of 113 dB(A) which increased the rating level by only 0.4 dB. The noise exposure of TS I and TS II was followed by an idealized resting phase in a soundproof cabin. In a third test series (TS III) the continuous noise of 94 dB(A) / 1 h was followed by 3 h of white noise at 70 dB(A). Such an additional load increases the LArd by merely 0.1 dB to 85.1 dB(A). In all three test series, the noise-induced temporary threshold shift (TTS2) and its restitution were measured. The continuous noise exposure of 94 dB(A) for 1 h was associated with a TTS2 of around 20 dB which disappeared completely after about 2 h. The additional impulse noise caused a small increase in the TTS2 and a prolongation of the restitution time. The maximum mean temporary threshold shift for the group increased only slightly (from 22.5 to 25.9 dB, which nevertheless can be statistically proven at a significance level of p 0.99). Yet, more importantly, the restitution time increased from 126 to 175 min, i. e. 3 h, which can be statistically proven at a significance level of p0.95. The TTS2-values of TS III did not differ significantly from those resulting from TS I. That was expected as the conditions up to that point in time were identical. But due to the additional subsequent exposure, the mean restitution time increased considerably from 126 min up to 240 min (4 h). The mean total physiological cost represented by the integrated restitution temporary threshold shift (IRTTS) increased in TS II by approximately 40% and in TS III even by 140%.
Relevance to industry
The results of the study show that levels of noise which have no influence on the rating level which traditionally is calculated according to the energy-equivalence principle are often of great importance, as they can lead to considerably prolonged restitution times. Therefore, the purely energy-equivalent determination of the rating level of both impulse noise and low sound levels can lead to an underestimation of latent problems so that over time a reversible TTS can evolve into a permanent threshold shift. The results are also of importance for the acoustic design of break rooms for noise-exposed workers. There should be conditions that allow an undisturbed restitution of hearing. 相似文献