液态CO2相变致裂强化瓦斯预抽试验研究

针对单一低透气性煤层瓦斯含量高、预抽效果不理想的情况,采用液态CO2相变致裂技术,在穿层钻孔中利用瞬间产生的高压CO2气体冲击煤体,产生大量裂隙并促使裂隙发育、扩展,以达到提高煤层透气性的目的.在河南焦煤能源有限公司九里山16051底抽巷进行的试验表明:液态CO2相变致裂技术可有效提高瓦斯抽采效果,试验后平均抽采流量0.057 m3/min,是试验前平均流量的4.3倍,是相同抽采时间内水力冲孔措施平均抽采流量的2.3倍;抽采体积分数也有所提升;在试验考察期内流量衰减系数降低到0.046 d-1,增透效果显著.     

基于Mahout的个性化推荐系统架构

针对互联网企业的实际和用户需求,构建一种基于Mahout的个性化推荐系统架构。通过分析网站的数据特点,将数据分为静态数据和动态数据。当数据量不大时,根据数据特点选用Mahout单机内存推荐算法进行计算;当数据量很大时搭建分布式集群,将业务系统的静态数据定时地增量导入到Hadoop的HDFS中,然后用Mahout分布式推荐算法访问HDFS。计算后的结果,保存到业务系统的数据库中,与动态数据合并作为在线响应的输出。实验证明该方案可以绕过海量数据的高并发在线分析的问题,有效地缓解系统响应时间的压力。     

基于PIC单片机的智能充电器设计

针对现有充电器存在的问题和不足,设计了一款基于PIC单片机的智能充电器.可利用单片机功能的灵活性对电池快速充电,通过按键对充电器进行设定,具有良好的人机交互.单片机可以直接生成半桥波,降低成本,并可通过采样电压和电流直接控制占空比来改变输出电压.     

全浮芯棒二辊孔型中轧管金属变形行为研究

为分析连轧荒管管壁收缩的原因,借助有限元模拟软件MSC.Super Form,对宝钢Φ140 mm全浮芯棒连轧管机组Φ119 mm主孔型系钢管的单机架轧制过程进行数值模拟仿真,研究轧制过程中不同工艺参数对金属变形行为的影响,分析产生壁厚收缩缺陷的倾向性。结果表明：孔型顶部的壁厚压下量一定时,孔型开口处壁厚随空减坯径壁比的增大由＂增壁＂变为＂减壁＂,并且存在一临界径壁比;径壁比一定时,孔型开口处壁厚变化随压下量的增大由＂增壁＂变为＂减壁＂,并存在临界压下量;径壁比、压下量均一定时,单机架轧制高钢级时孔型开口处壁厚值相对较大。     

Solution growth of millimeter-scale Na2SiF6 single crystals for Mn4+-doping as red phosphor

The cation exchange method has been demonstrated to be efficient in doping Mn⁴⁺ ions into various fluorides to synthesize the red-emitting LED phosphors. This paper, however, reports the challenge in using this method to dope Mn⁴⁺ into the Na₂SiF₆ single crystals, to prepare the fluoride phosphor in single-crystal form, a state-of-the-art study in the white LED lighting field. The millimeter-sized Na₂SiF₆ single crystals with a uniform columnar morphology (2–3 mm in length) were successfully grown in solution by a slow cooling process after optimizing the precursors. Then, the crystals were soaked in the HF solution dissolved with K₂MnF₆ to implement Mn⁴⁺-doping via the cation exchange process. Evaluation of the Mn⁴⁺-doping behavior reveals that the Mn⁴⁺ ↔ Si⁴⁺ cation exchange is less efficient in the case of single crystal host compared with the polycrystalline powdery ones and by-reactions also occur which generates new phases. The Na₂SiF₆ single crystals doped with Mn⁴⁺ exhibit a series of discrete sharp peaks with intense zero phonon line emission at 617 nm under 450 nm blue irradiation. This study may trigger the exploration of new single crystal fluoride phosphor.     

Effects of PSMA and experimental conditions on the morphologies of BaCO3 whiskers

BaCO3 whiskers exhibiting different morphologies were fabricated by a simple precipitation reaction of barium ch/oride with sodium carbonate in the absence and presence of poly-（styrene-alt-maleic acid） （PSMA） as a crystal growth modifier at room temperature. The as-prepared products were characterized by scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, and X-ray diffraction （XRD）. The influences of experimental parameters on the size and morphology of BaCO3 whiskers were investigated and discussed. It was found that the as-prepared BaCO3 whiskers are single crystals with diameter ranging from 100 to 300 run, and grow along the crystallographic a-axis or [100] direction. BaCO3 whiskers with different morphologies, such as branching and dendritic structure, can be obtained depending on the experimental conditions. With increasing PSMA concentration, the diameter of BaCO3 whiskers decreases.     

镍基单晶合金枝晶典型区域相成分最优化测算法

建立了用于测算镍基单晶高温合金枝晶典型区域相成分的最优化数学模型.根据电子探针对枝晶典型区域成分的测定结果,运用BFGS拟Newton法及CONSTR约束优化算法,可以计算枝晶各典型区域中γ和γ＇相成分.以镍基单晶合金CMSX-2和CMSX-4为对象,对优化测算结果进行了分析,证实了该方法的可行性.     

纳米CeO2单晶的制备与热处理对粒径的影响

以Ce(NO3)3·6H2O为铈源、NH3·H2O为沉淀剂,用化学沉淀法通过对陈化时间的控制,制备了单分散的单晶纳米CeO2粒子,并用XRD、TEM、ED、BET、TG-DTA等测试手段对产物的物相结构、形貌和纳米尺度进行了表征.XRD分析表明,制得的纳米CeO2粒子为萤石结构且晶型比较完整. 通过控制热处理的温度和陈化时间可以控制粒子的大小.TEM和ED分析表明产物颗粒基本为球形,分散性较好且为单晶. 通过TG-DTA结果可以断定所制备的前驱体结构式为CeO2·1/2H2O.     

调制波长对Cu／Ni金属多层膜力学性能的影响

用电沉积法在低碳钢基体上制备了具有不同调制波长(一个调制波长等于单层Cu膜与单层Ni膜厚度之和)的Cu/Ni金属多层膜，研究了多层膜硬度与其中单层膜厚度之间的关系。结果表明，当膜厚在亚微米范围内时，Cu/Ni多层膜的屈服强度(为硬度值的1/3)与单层膜厚之间符合基于位错塞积模型的Hall-Pctch(H-P)关系式；而当单层膜厚小于100nm时，屈服强度与膜厚的关系偏离了H-P线性关系。基于程开甲等人位错稳定性理论首次对金属多层膜变形行为偏离Hall-Petch关系的现象作了定量解释。     

"KQDL系列冲天炉"成果研讨

针对冲天炉,冷风炉、热风炉、水冷却炉存在的问题试制出了"KQDL系列冲天炉".论述了"KQDL系列冲天炉"采用空气冷却、强化预热、单排龙卷风供风原理和特点.通过生产实践与传统冲天炉的比较,认为这种新型冲天炉可给企业带来明显的经济效益,同时可使铁水质量明显提高,这种新型冲天炉有很高的性价比,可使冲天炉的设计更上一层楼.