小型钨丝电热原子吸收光谱仪的电源

随着对分析仪器的小型化、便携式需求的提高,钨丝电热原子吸收光谱仪在便携式分析仪器方面显示了很大的潜力.为进一步满足现场分析的需要,以单片机为芯片,为小型钨丝电热原子吸收光谱仪的空心阴极灯和钨丝电热原子化器设计稳定的一体化恒流电源;并编写PC机的控制软件,以USB或RS232方式与电源通信,方便控制空心阴极灯和钨丝电热原子化器电流,以及原子吸收过程.以此电路设计的小型钨丝电热原子吸收光谱仪对镉、铅、金和银的标准溶液测试结果为:检出限分别为(0.1,6.0,5.0,0.6)μg/L,相对标准偏差分别为8.2%,5.3%,6.0%和7.2%.测试结果表明:电源很稳定,达到了文献报道的钨丝电热原子吸收光谱的分析性能.     

Monitoring the Dynamic Process of Formation of Plasmonic Molecular Junctions during Single Nanoparticle Collisions

The capability to study the dynamic formation of plasmonic molecular junction is of fundamental importance, and it will provide new insights into molecular electronics/plasmonics, single‐entity electrochemistry, and nanooptoelectronics. Here, a facile method to form plasmonic molecular junctions is reported by utilizing single gold nanoparticle (NP) collision events at a highly curved gold nanoelectrode modified with a self‐assembled monolayer. By using time‐resolved electrochemical current measurement and surface‐enhanced Raman scattering spectroscopy, the current changes and the evolution of interfacial chemical bonding are successfully observed in the newly formed molecular tunnel junctions during and after the gold NP “hit‐n‐stay” and “hit‐n‐run” collision events. The results lead to an in‐depth understanding of the single NP motion and the associated molecular level changes during the formation of the plasmonic molecular junctions in a single NP collision event. This method also provides a new platform to study molecular changes at the single molecule level during electron transport in a dynamic molecular tunnel junction.     

用BASIC单片机实现油品密度的测量

油品的密度与温度有着确定的对应关系,通过测量温度可以间接测量密度。根据这一关系可以利用小巧的ＢＡＳＩＣ单片机设计一个价廉、实用的密度计。经实验对比,其稳定性较好,反应灵敏,测量较准确,较常规方法更方便快捷     

Approximate dynamic programming solutions with a single network adaptive critic for a class of nonlinear systems

Approximate dynamic programming (ADP) formulation implemented with an adaptive critic (AC)-based neural network (NN) structure has evolved as a powerful technique for solving the Hamilton-Jacobi-Bellman (HJB) equations. As interest in ADP and the AC solutions are escalating with time, there is a dire need to consider possible enabling factors for their implementations. A typical AC structure consists of two interacting NNs, which is computationally expensive. In this paper, a new architecture, called the ‘cost-function-based single network adaptive critic (J-SNAC)’ is presented, which eliminates one of the networks in a typical AC structure. This approach is applicable to a wide class of nonlinear systems in engineering. In order to demonstrate the benefits and the control synthesis with the J-SNAC, two problems have been solved with the AC and the J-SNAC approaches. Results are presented, which show savings of about 50% of the computational costs by J-SNAC while having the same accuracy levels of the dual network structure in solving for optimal control. Furthermore, convergence of the J-SNAC iterations, which reduces to a least-squares problem, is discussed; for linear systems, the iterative process is shown to reduce to solving the familiar algebraic Ricatti equation.     

Array SSL VPN如何保障番禺有线办公网的安全运行

企业办公自动化系统的应用十分广泛,随着互联网的高速发展,WEB应用成为主流,OA系统在互联网上的延伸成为大趋势,本文阐述在WEB应用中如何保障数据和系统安全的手段和方法。     

基于单字音特征提取的说话人识别方法

证实普通话可以分解为辅音音素和单元音音素通过过度音的连接,提出一种单字音特征提取方法。该方法在传统的帧特征提取基础上,对相关帧进行二次处理,得到单字语音中的多个代表帧,将代表帧进行拼接作为单字的特征矢量。这种特征提取方法能更好地表现说话人单字发音中相邻语音帧之间的连续性。仿真实验表明该方法在说话人识别系统的应用中达到较高的识别率,使识别时间进一步缩短。     

单件小批量生产排产逆序递推法应用研究

针对单件小批量型生产企业,为了保证交货期和控制原材料、在制品库存,提出一种生产排产算法--逆序递推算法.本文在算法中考虑到了生产扰动对交货期的影响,并结合实例作出逆序递推排产甘特图来指导生产.     

PC机与多单片机组成串行通信的新尝试

以实际应用的小型集散变频调速系统为例 ,介绍一种PC机与多AT89C2 0 51单片机之间串行通信的接口电路 ,并提出一种新的通信方法 ,即采用QBASIC语言提供通信语句来编写多机通信程序。该方法硬件紧凑 ,软件编程简单可靠。     

单苯环氯取代指数法预测二噁类化合物PCDDs的正辛醇/水分配系数

采用单苯环氯取代指数作为氯代二苯并二口恶口英类化合物 (PCDDs)的分子结构描述符 ,通过正向逐步线性回归方法建立了PCDDs的logKow与分子结构描述符之间的定量关系模型。与文献报道的MOD模型相比 ,该模型不仅具有显著的相关性 (n =43,Radj=0 898,SE =0 195 ,在α =0 0 5时 ,F =2 0 45 5 ,p =0 0 0 0 0 ) ,而且对于分子结构具有更好的区分能力。利用建立的模型 ,对没有logKow文献值的其他 33种PCDDs化合物给出了预测值     

应用MODIS资料对城乡地表热通量的估算

为了揭示城市热岛形成机制,基于MODIS资料,结合自动气象站实测的气象资料,利用地表能量参数化方法估算了地表热通量,分析了城乡地表热通量的空间分布及变化特征.结果表明城乡地气热交换差异明显,与相关文献对比证明该方法是可行、有效的.