低气压等离子喷涂TiO2涂层结构的研究

本研究分析了在低气压等离子喷涂条件下,TiO_2涂层的结构受等离子弧喷涂过程中氧分解量所影响。氧分解量很大程度上依赖于离子气中氢流量的大小,此外喷涂室压力也有一定影响。而等离子弧功率和喷涂距离对TiO_2涂层的氧分解量没有多大影响。在离子气中氢流量不变的条件下,涂层中Ti_3O_5量随喷涂室压力(从100×133.322Pa至400×133.322Pa)增加而增加。     

高速电弧喷涂Fe-Al/Cr3C2复合涂层的组织与性能

采用Fe-Al/Cr3C2粉芯丝材和高速电弧喷涂技术(HVAS)原位合成了铁铝金属间化合物涂层,并研究了涂层的显微组织与性能.结果表明,高速电弧喷涂Fe-Al/Cr3C2涂层中生成了多种物相,主要是Fe3Al和FeAl相,同时还包括Fe3C硬质点相及FeO*Al2O3和Cr2O3氧化物相等.涂层具有很高的热震结合强度及相对基体较高的显微硬度,密度和孔隙率较低.     

钛合金表面等离子喷涂制备ZrO2─Ti系功能梯度涂层

研究了等离子喷涂法制备ＺｒＯ２Ｔｉ系功能梯度涂层。结果表明，采用等离子喷涂工艺制备功能梯度涂层是可行的，涂层与基体除以机械咬合方式结合外，还存在着少量冶金化学反应结合，添加Ｎｉ／Ａｌ和ＳｉＯ２有助于提高涂层的结合强度     

High-velocity oxyfuel reactive spraying of mechanically alloyed Ni-Ti-C powders

Recently, there has been considerable interest in producing cermet coatings with nanoscale carbide grains in the size range 50 to 500 nm. In this article, the production of nanoscale TiC grains in a Ni-based alloy matrix by reactive high-velocity oxyfuel (HVOF) spraying of metastable Ni-Ti-C powder is reported. Mechanical alloying of a Ni(Cr) prealloyed powder and Ti and C elemental powders was performed in a planar-type ball mill, and materials were characterized in detail using x-ray diffraction (XRD) and scanning electron micros-copy (SEM). Phase changes were correlated with milling time and other processing conditions. Results show that, by the selection of appropriate conditions, a metastable Ni-Ti-C powder could be obtained with the nominal composition 50wt.%Ni-40wt.%Ti-10wt.%C. Following sieving and classification, powder was produced with a particle size range of −38 to 8 μm, which is suitable for HVOF spraying. Coatings, approximately 250 μm thick, were deposited by HVOF spraying onto mild steel substrates, and the microstructures formed were investigated. XRD showed that a self-propagating high-temperature synthesis (SHS) reaction had occurred in the powder particles during spraying and that the principal phases present in the coating were TiC and a Ni-rich solid solution; small quantities of NiTi, TiO₂, and NiTiO₃ were also present. SEM revealed that the coatings had a characteristic, splatlike morphology and that TiC formed as a nanoscale dispersion, with a size range of ∼50 to 200 nm, within solidified splats. The microstructures of these reactively sprayed Ni-TiC coatings are briefly compared with those observed in HVOF-sprayed coatings deposited using prereacted SHS powder. The original version of this paper was published as part of the ASM Proceedings, Thermal Spray 2003: Advancing the Science and Applying the Technology, International Thermal Spray Conference (Orlando, FL), May 5–8, 2003, Basil R. Marple and Christian Moreau, Ed., ASM International, 2003.     

Microstructure Control of Thermally Sprayed Co-Based Self-Fluxing Alloy Coatings by Diffusion Treatment

This article describes microstructure control aimed for wear-resistance improvement of Co-based (Co-Cr-W-B-Si) self-fluxing alloy coating by diffusion treatment. The diffusion treatments of thermally sprayed Co-based self-fluxing alloy coating on steel substrate were carried out at 1370-1450 K for 600-6000 s under an Ar gas atmosphere. Microstructural variations of the coating and the interface between the substrate and the coating were investigated in detail. A proper diffusion treatment precipitates two kinds of fine compounds in Co-based matrix. X-ray diffractometer (XRD) and electron probe microanalyzer (EPMA) analysis revealed these precipitates to be a chromium boride dissolving cobalt and a tungsten boride containing cobalt and chromium. The size of each precipitate became larger with increasing treatment temperature and time. A coating with the proper size borides showed a superior wear-resistance. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

Effect of Powder Injection Location on Ceramic Coatings Properties When Using Plasma Spray

The effect of powder injecting location of the plasma spraying on spraying properties was studied. Three different powder-injecting methods were applied in the experiment. In the first method, the particles were axially injected into the plasma flow from the cathode tip. In the second method, the particles were radially injected into the plasma flow just downstream of the anode arc root inside the anode nozzle. In the third method, the particles were radially injected into the plasma jet at the nozzle exit. The alumina particles with a mean diameter of 20 μm were used to deposit coatings. Spraying properties, such as the deposition efficiency, the melting rate of the powder particles, and the coating quality were investigated. The results show that the spraying with axial particle injecting can heat and melt the powder particles more effectively, produce coatings with better quality, and have higher deposition efficiency. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

Flame-Sprayed Glaze Coatings: Effects of Operating Parameters and Feedstock Characteristics Onto Coating Structures

Many substrates do not sustain the conventional glazing process (i.e., vitreous glazing) due to the relatively high temperature required by this treatment (i.e., up to 1400 °C in some cases) to fuse glazes after their application on the surface to be covered. Flame spraying could appear as a solution to circumvent this limitation and to avoid thermal decomposition of substrates. This contribution describes some structural attributes of glaze coatings manufactured by flame spraying. It also discusses the influence of the feedstock powder morphology and some of its physical properties on coating characteristics. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

融合改进 Padim 建模和 ResNet 网络的 喷涂质量检测算法

为了满足喷涂机器人对于喷涂质量检测的需求,采用迁移学习对改进 Padim 建模和 ResNet 网络进行融合,构建自主喷 涂机器人喷涂质量检测一体化模型。 该模型提取一次图像特征可同时用于缺陷定位和分类。 在缺陷定位端,通过改进 Padim 模型以减少特征冗余所造成网络的计算消耗,首先将 ResNet-18 网络获取的 patch 嵌入向量语义层由原先前 3 层改为单 2 层,然 后特征表达由 100 维降维至 20 维,最后训练正样本得到正态分布模型与测试图像进行缺陷定位。 在缺陷分类端,对预训练 ResNet-18 网络进行负样本二次训练,得到 ResNet-18 分类模型对测试图像进行缺陷分类。 经过实验,将一体化模型移植在 jetson nano 移动端中,参数量仅为 11. 69 M,定位精度 94. 5%,分类准确率高达 99. 6%,在机器人位移速度 0. 02 m/ s 下检测时间 为 0. 730 s,不会出现缺帧漏检情况,满足实时检测的要求。     

RDX基复合物静电喷雾法制备及性能研究

采用静电喷雾技术制备了以氟橡胶(F2604)、聚乙烯醇缩丁醛(PVB)及三硝基甲苯(TNT)为包覆材料的黑索今(RDX)基复合颗粒,对所制备的复合颗粒进行扫描电镜(SEM)、傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)和差示扫描量热仪(DSC)分析,得到超细包覆粒子的包覆效果及其热分解特性。结果表明:F2604/RDX与PVB/RDX复合颗粒为形貌规整、粒径均一的球形颗粒,而TNT/RDX复合颗粒为不规则多面体;F2604/RDX、PVB/RDX与TNT/RDX复合颗粒的红外吸收峰和X射线衍射峰位置与RDX一致;PVB/RDX复合物活化能最低,为137.059 k J/mol。     

不同喷涂工艺下NiCoCrAlYTa涂层的显微结构和性能

为探索不同喷涂工艺对NiCoCrAlYTa涂层的显微结构和性能的影响规律,确定最优工艺,采用大气等离子、低压等离子、常规超音速火焰和低温超音速火焰4种工艺在镍基单晶高温合金表面制备了NiCoCrAlYTa涂层。采用X射线衍射(XRD)、扫描电镜(SEM)和显微硬度计等分析手段对喷涂态涂层的相组成、显微结构和显微硬度等进行了表征。结果表明,不同喷涂工艺下涂层的相组成均为γ′-Ni_3Al、β-NiAl和γ-Ni固溶体。低压等离子和超音速火焰喷涂的涂层致密且孔隙率低,其中超音速火焰喷涂的涂层孔隙率低于1%。低压等离子和低温超音速火焰喷涂的涂层氧含量很低,控制在0.3%~0.6%的范围。综合来说,低温超音速火焰喷涂工艺制备的涂层结构致密,孔隙率和氧含量很低。该工艺是沉积NiCoCrAlYTa涂层的首选。