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61.
The mismatch between the thermal expansion coefficients of ceramics and metals and the differential stresses it causes at
the interface create problems in metal to ceramic joining. Research has been con-ducted to solve this problem in thermal barrier
coating technology. Previous studies have considered met-al-ceramic multilayers or graded-coatings, which include a metallic
bond coat. In this study, a graded plasma-sprayed metal-ceramic coating is developed using the deposition of premixed metal
and ceramic powders without the conventional metallic bond coat. Influences of thickness variations, number, and composition
of the layers are investigated. Coatings are prepared by atmospheric plasma-spraying on In-conel 718 superalloy substrates.
Ni-Cr-Al and ZrO2 -8 % Y2O3 powders are used for plasma spraying. Ad-hesive and cohesive strength of the coatings are determined. The concentration profile
of the elements is determined by x-ray energy-dispersive analysis. The microstructure and morphology of the coatings are investigated
by optical and scanning electron microscopy (SEM). Results show that the mixed metal-ce-ramic coating obtained with the deposition
of premixed powders is homogeneous. The morphology and microstructure of the coatings are considered satisfactory. 相似文献
62.
Youtao Xie Xuebin Zheng Xuanyong Liu Chuanxian Ding 《Journal of Thermal Spray Technology》2007,16(4):588-592
Titanium/dicalcium silicate composite coatings with different ratios (weight ratios as Ca2SiO4: Ti = 3:7, 5:5, 7:3) were prepared by plasma spraying. Effects of titanium addition on coating properties, such as bonding
strength, flexural modulus, and dissolution in simulated physiological environment, were studied. Results showed that the
bonding strength between coating and Ti-6Al-4V substrate increased with increase of titanium content in the composite coatings.
It was explained by the narrowed dissimilarity of thermal expansion coefficients between the coatings and substrates. Degradation
of mechanical properties after immersion in simulated body fluid was also studied. The dissolution of dicalcium silicate in
the composite coatings resulted in the decrease of flexural strength and flexural modulus of the coatings in the simulated
physiological environment. The higher titanium content in the composite coatings, the stabler are the composite coatings in
the physiological environment. 相似文献
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65.
The corrosion characteristics of a wire-are-sprayed stainless steel coating on mild steel have been investigated in regards
to atomizing gases and sealing treatment. Salt spray test was performed. The corrosion behavior of the coating was observed
under a microscope succesively through a cycling test of wetting and drying in a salt solution. The sealing-treated coating
was found to rust faster compared with the non-sealing-treated coating; it protected the mild steel substrate against corrosion,
but even it deteriorated the coating itself due to the interruption of the substrate as an anode. The air-atomized coating
ruste more heavily than the nitrogen-atomized one. Four different phases were observed in the coating in regards to corrosion
behavior; namely, chromium-based oxide, iron-based oxide, chromium-depleted metallic phase, and stainless steel matrix phase.
It was found that the chromium-depleted metallic phase and the iron-based oxide are non-corrosion-resistant, whereas the chromium-based
oxide and the stainless steel matrix phase are corrosion-resistant. 相似文献
66.
为了研究热喷涂工艺对爆炸喷涂Al-Cu-Cr准晶涂层组织和硬度的影响规律,采用三种爆炸喷涂工艺参数在Q235A低碳钢基体上制备涂层,借助XRD、SEM和OM等技术手段对粉末和涂层的组织结构进行分析,并检测涂层横截面的孔隙率和显微硬度。结果表明,用于喷涂的A165Cu20Cr15准晶粉末中含有二十面体准晶相i-A165Cu24Cr11和极少量具有单斜结构的晶体相θ-Al13Cr2(即Al83Cu4Cr13);而爆炸喷涂涂层中除i和θ两相外,生成了新相——体心立方结构的α-Al69Cu18Cr13(准晶i的晶体类似相)和Al2O3相。涂层呈典型层状结构,其它条件不变的情况下,涂层中各晶体相与准晶相i最强峰衍射强度的比值α/i、θ/i和Al2O3/i随爆炸喷涂工作气体流速的成比例提高而增加,同时涂层截面的孔隙率下降而显微硬度HV0.1升高。 相似文献
67.
目的提高生物医用钛合金涂层的结合力与生物活性。方法采用阳极氧化法在Ti-10Mo-28Nb-3Zr-6Ta合金表面先制备纳米氧化管,接着通过等离子喷涂法在纳米氧化层表面喷涂HA生物涂层,制备HA/MO纳米管复合涂层,对合金进行表面改性。在等离子喷涂法制备复合涂层时,通过改变喷涂电压和喷涂距离,对涂层的显微结构和物相组成进行探究,获得最佳制备工艺参数,同时对最佳工艺参数制备的复合涂层,通过电化学工作站实验、自动划痕仪测试、仿生矿化法试验和MTT法(四唑盐比色法)试验,分别评价复合涂层的耐腐蚀性能、附着力、生物活性和细胞毒性。结果在钛合金用阳极氧化法预处理的前提下,通过等离子喷涂制备HA/MO纳米管复合涂层,当喷涂电压为40V、喷涂距离为100mm时,制备出的HA/MO纳米管复合涂层涂覆均匀,涂层厚度在50μm左右,耐蚀性得到提高,结合力最佳,为14.8 N。HA/MO纳米管复合涂层具有良好的生物活性,通过培养细胞进行毒性实验,HA/纳米管复合涂层试样的毒性分级为0级,对细胞无影响,且从细胞增殖速率分析,试样表现出优异的细胞活性,对细胞的增长速率促进效果最好。结论 HA/MO纳米管复合涂层可以有效提高耐蚀性和结合强度,同时提高材料的生物活性。 相似文献
68.
研究了激光重熔Ni60 20% WC喷涂层的组织和性能,通过对涂层显微组织、硬度、耐磨性等试验的结果分析表明:火焰喷涂后的Ni基WC喷涂层经激光重熔处理后,涂层中有新的硬质相和共晶组织形成,WC均匀地分布在涂层中.涂层中除了包含γ固溶体外,还有WC,W2C,Ni3B,CrB,Cr7C3,Cr23C6,Cr2B,(Fe,Ni)23C6等硬质相和化合物.这些化合物有效地改善了涂层的组织和性能,得到了硬度和耐磨性较好的喷涂层.涂层表面的硬度值可以达到HRC60,涂层截面的显微硬度可以达到800 HV. 相似文献
69.
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