Bunsen section thermodynamic model for hydrogen production by the sulfur–iodine cycle

A model for the Bunsen section of the Sulfur–Iodine thermo-chemical cycle is proposed, where sulfur dioxide reacts with excess water and iodine to produce two demixing liquid aqueous phases (H₂SO₄ rich and HI rich) in equilibrium. Considering the mild temperature and pressure conditions, the UNIQUAC activity coefficient model combined with Engels' solvation model is used. The complete model is discussed, with HI solvation by water and by iodine as well as H₂SO₄ solvation by water, leading to a very high complexity with almost hundred parameters to be estimated from experimental data. Taking into account the water excess, a successful reduced model with only 15 parameters is proposed after defining new apparent species. Acids total dissociation and total H⁺ solvation by water are the main assumptions. Results show a good agreement with published experimental data between 25 °C and 120 °C.     

Analysis of the influence of the level of residual stresses on the ultimate stresses in a cycle for welded structures according to the results of testing of small-size specimens

We propose a procedure for the determination of the diagrams of ultimate stresses in a cycle for welded joints with preliminarily induced steady-state residual stresses according to the results of testing of small-size specimens without residual stresses. Translated from Problemy Prochnosti, No. 3, pp. 107–115, May–June, 2009.     

季节性冻土深基坑支护技术研究

通过对中国地质大学(北京)综合游泳馆工程拟建场地土层的土质、深度及基坑深度的分析与比较,确定出基坑深度范围内土层的土质。介绍了季节性冻土深基坑支护经常出现的问题,并分析了这些问题出现的原因。对常用土钉支护方法在季节性冻土深基坑支护中运用的局限性做了总结,最后提出一种改进的土钉支护方法。该法针对冻土发生冻融循环时冻胀与融沉的特点采取了相应的控制措施,从而保证了季节性冻土深基坑的稳定性。该法操作简单可行,实践证明效果明显。     

Controlled and modified atmospheres influence chilling injury,fruit quality and antioxidative system of Japanese plums (Prunus salicina Lindell)

Our objective was to compare the effects of controlled atmosphere (CA) and modified atmosphere packaging (MAP) on fruit quality, chilling injury (CI) and pro‐ and antioxidative systems in ‘Blackamber’ Japanese plums. Matured fruit were stored for 5 and 8 weeks at 0–1 °C in normal air, CA‐1 (1% O₂ + 3% CO₂), CA‐2 (2.5% O₂ + 3% CO₂) and MAP (~10% O₂ and 3.8% CO₂). CA was more effective than MAP in retention of flesh firmness and titratable acidity during cold storage. Fruit stored in CA‐1 showed reduced CI and membrane lipid peroxidation after 5 and 8 weeks of cold storage. Low O₂ atmospheres appeared to limit the generation of reactive oxygen species (ROS) and their efficient scavenging through the concerted action of superoxide dismutase and peroxidase. The role of ascorbate–glutathione (AsA–GSH) cycle in the regulation of oxidative stress was also studied during and after storage in different atmospheres. In conclusion, optimum CA conditions delayed fruit ripening and CI through augmentation of antioxidative metabolism and suppression of oxidative processes.     

Pavement Life-Cycle Cost and Asphalt Binder Quality: Theoretical and Experimental Investigation

Quality control/quality assurance tests can be used to demonstrate that an as-constructed pavement has characteristics different from the contracted specifications of the as-designed pavement because the bitumen employed was of insufficient quality. Many different issues affect asphalt binder quality. Such problems can significantly increase the pavement life-cycle cost, which means that a pay adjustment (PA) is needed. Unfortunately, the quantitative analysis of this issue is very complex. The objectives of this study were to model the dependence of the pavement life-cycle cost on asphalt binder quality and to determine the quantitative relationship between bitumen viscosity and the PA for a given class of boundary conditions. In addition to modeling this problem theoretically, experiments and simulations were carried out through the use of the Mechanistic-Empirical Pavement Design Guide. We then derived the consequences of these effects on life-cycle cost by using a specific life-cycle cost model. Our results demonstrate that asphalt binder viscosity can strongly affect the expected pavement life and the PA, and thus needs to be taken into account in contract and construction management.     

Heat rejection pressure optimization for a carbon dioxide split system: An experimental study

Recent studies indicate carbon dioxide (R744) as a valid alternative to classical substances such as HFCs used in vapour compression plants. However a transcritical refrigeration cycle is needed because the critical temperature of carbon dioxide is usually near the ambient temperature. Consequently the carbon dioxide refrigerator performances are significantly influenced by the heat rejection pressure. In this paper an experimental investigation on working optimization for a “split-system” to cool air in residential applications is presented: by varying the heat rejection pressure an optimum working condition has been found at different ambient temperatures. Furthermore a simplified model to predict the optimum heat rejection pressure is shown and a comparison with experimental results is carried out. Both the model validation and the experimental results suggest that the heat rejection pressure optimization is an convenient method to improve the performance of a carbon dioxide split system. Finally an algorithm based on the aforementioned model has been proposed in order to control an electronic back pressure valve by means of a PLC.     

Global warming potential of the sulfur–iodine process using life cycle assessment methodology

A life cycle assessment (LCA) of one proposed method of hydrogen production – thermochemical water-splitting using the sulfur–iodine cycle couple with a very high-temperature nuclear reactor – is presented in this paper. Thermochemical water-splitting theoretically offers a higher overall efficiency than high-temperature electrolysis of water because heat from the nuclear reactor is provided directly to the hydrogen generation process, instead of using the intermediate step of generating electricity. The primary heat source for the S–I cycle is an advanced nuclear reactor operating at temperatures corresponding to those required by the sulfur–iodine process. This LCA examines the environmental impact of the combined advanced nuclear and hydrogen generation plants and focuses on quantifying the emissions of carbon dioxide per kilogram of hydrogen produced. The results are presented in terms of global warming potential (GWP). The GWP of the system is 2500 g carbon dioxide-equivalent (CO₂-eq) per kilogram of hydrogen produced. The GWP of this process is approximately one-sixth of that for hydrogen production by steam reforming of natural gas, and is comparable to producing hydrogen from wind- or hydro-electric conventional electrolysis.     

Investment in new product reliability

Product reliability is of great importance to both manufacturers and customers. Building reliability into a new product is costly, but the consequences of inadequate product reliability can be costlier. This implies that manufacturers need to decide on the optimal investment in new product reliability by achieving a suitable trade-off between the two costs. This paper develops a framework and proposes an approach to help manufacturers decide on the investment in new product reliability.     

摩托车变速箱生产线的PI控制器设计

为了有效控制摩托车变速箱生产线的节拍,采用了级联控制方式,在生产线中设计了PI控制器,按照摩托车变速箱体零件的加工工艺,将箱体加工分为3个阶段,在每两个加工工段的反馈通路上,设置了PI控制器,经迭代求解、仿真验证,确定了制造系统PI控制器的合理参数,增强了生产线的流畅性和控制系统的鲁棒性。