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171.
172.
用ASPENPLUS对高压水煤浆气化过程做了模拟计算,得到不同气化温度下的粗合成气中甲烷含量,为实际生产中间接预测气化炉温度提供参考。 相似文献
173.
Supported nickel catalysts prepared using commercial sintered low surface area porous catalyst carriers (containing SiO2 and/or Al2O3) precoated with MgO, CaO or rare-earth oxide show very much higher activity, selectivity and productivity in methane-to-syngas conversion reactions, than the catalysts prepared using catalyst carriers without any precoating. Among the precoating metal oxides, the best performance is observed for MgO. 相似文献
174.
根据IGCC系统中净燃气过热器中流体的特点和参数,对净燃气过热器进行了选型和设计,提出了采用Aspen软件来确定合成气的物性参数,并将计算结果与采用Aspen软件计算的结果进行了对比,验证了本设计方法的正确性. 相似文献
175.
以废弃活性炭为原料,以Fe4ATP6复合载氧体为载氧体,在间歇高温流化床中考察了废弃活性炭化学链气化制富氢合成气反应的较优条件及复合载氧体的循环反应特性。结果表明,Fe4ATP6复合载氧体具有提供晶格氧及催化气化的双重作用,显著提高了碳转化率,促进了废弃活性炭气化过程,反应活性良好。废弃活性炭化学链气化制富氢合成气的优化反应条件:900℃、水蒸气流量为0.25 g·min-1、OC/C比为1。在上述条件下,碳转化率达92.15%,合成气产量达1.20 L·g-1,其中H2产量为1.09 L·g-1,平均浓度为55.30%。10次循环实验表明Fe4ATP6复合载氧体的反应活性略有降低,通过SEM、XRD分析载氧体的表面形貌、物质组成发现,载氧体反应后结构变化较大,粒径减小,生成了无反应活性的硅酸铁。 相似文献
176.
合成气一步法合成二甲醚研究 总被引:2,自引:0,他引:2
结合国内外二甲醚研究现状,从合成气一步法合成二甲醚的分类、工艺、热力学、动力学、催化剂等方面进行了阐述,并对合成气一步法制取二甲醚进行了技术评价。 相似文献
177.
Shen‐Jun Dai Yi‐Quan Yang You‐Zhu Yuan Ding‐Liang Tang Ren‐Cun Lin Hong Bin Zhang 《Catalysis Letters》1999,61(3-4):157-160
The catalysts K2MoS4/SiO2 promoted with transition metal oxides Fe2O3, CoO, NiO and MnO2 were prepared and used to catalyze the synthesis of methanethiol from H2Scontaining syngas. The results of activity assay show that the catalysts promoted with Fe2O3, CoO and NiO can remarkably increase the hour space yield of methanethiol. Nevertheless, MnO2 was found to have a disadvantageous effect on the selectivity of methanethiol. The results of XRD and XPS characterization indicate that the addition of the transition metal oxides promoters is in favor of the formation of a Mo–S–K active phase and also retards the decomposition of K2MoS4 to MoS2, thereby suppressing both the deep reduction of Mo species and the formation of (S–S)2 species, which are reflected by the increment of the concentration ratios of both Mo6+/Mo4+ and S2/(S–S)2. 相似文献
178.
Supported K2CO3/Co–MoS2 on activated carbon was prepared by a co-impregnation technique and has been characterized by X-ray diffraction (XRD) and BET. Active ingredients ranged from 39 to 66% and included molysulfide and cobalt sulfide. XRD analysis indicates that cobalt and molybdenum sulfides are found in the Co3S4 and Co9S8 phases. These catalysts were performance tested in a fixed-bed reactor under higher alcohol synthesis conditions, 2000–2400 psig and 270–330°C. Active chemicals on the carbon extrudates decreased the surface area dramatically, as measured by BET. Surprisingly, at the high level of active chemicals, alcohol productivity and selectivity were decreased. An increase in the reaction temperature led to a decrease in the selectivity of methanol and an increase in selectivity of hydrocarbons. Total alcohol productivity was also increased as gas hourly space velocity (GHSV) was increased. Co9S8 may play a role in the catalyst aging process. In prolonged reaction periods (140 h), sulfur is lost from the surface, possibly as H2S. The quantity of Co9S8 on the surface appears to increase as the catalyst ages. 相似文献
179.
The catalytic effect of NO
x
on methane oxidation in the absence of any solid catalyst has been investigated. The experimental results show that NO
x
has very good catalytic activity in the partial oxidation of methane. The predominant products for reactions in a CH4-O2-NO
x
co-feed mode are CO, CO2, H2O and H2, CH3OH, HCHO, and C2H4. Aromatics are also observed. 相似文献
180.
By performing the CH4 + CO2 and CD4 + CO2 reactions alternately over SiO2-supported nickel catalysts in a pulse micro-reactor, normal deuterium isotope effects on both the methane conversion reaction and on the CO formation reaction have been observed in the process of CO2 reforming of methane. Based on the observed CH4/CD4 isotope effects, the pathways for the formation of CO are discussed. 相似文献