全文获取类型
收费全文 | 749篇 |
免费 | 148篇 |
国内免费 | 26篇 |
专业分类
电工技术 | 27篇 |
综合类 | 16篇 |
化学工业 | 438篇 |
机械仪表 | 1篇 |
建筑科学 | 1篇 |
矿业工程 | 11篇 |
能源动力 | 164篇 |
轻工业 | 3篇 |
石油天然气 | 225篇 |
无线电 | 1篇 |
一般工业技术 | 17篇 |
冶金工业 | 12篇 |
原子能技术 | 2篇 |
自动化技术 | 5篇 |
出版年
2023年 | 18篇 |
2022年 | 36篇 |
2021年 | 31篇 |
2020年 | 42篇 |
2019年 | 44篇 |
2018年 | 35篇 |
2017年 | 18篇 |
2016年 | 52篇 |
2015年 | 31篇 |
2014年 | 44篇 |
2013年 | 49篇 |
2012年 | 56篇 |
2011年 | 65篇 |
2010年 | 47篇 |
2009年 | 59篇 |
2008年 | 38篇 |
2007年 | 23篇 |
2006年 | 34篇 |
2005年 | 22篇 |
2004年 | 21篇 |
2003年 | 21篇 |
2002年 | 20篇 |
2001年 | 15篇 |
2000年 | 13篇 |
1999年 | 15篇 |
1998年 | 14篇 |
1997年 | 12篇 |
1996年 | 13篇 |
1995年 | 14篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1951年 | 6篇 |
排序方式: 共有923条查询结果,搜索用时 718 毫秒
41.
《石油化工》2016,45(4):481
采用气相色谱法建立了合成气制烯烃(SGTO)水相产物中低碳醇、醛、酮、酸的测定方法,对分离条件进行优化,使用标准试样测定了线性范围和工作曲线,考察了方法的精密度和准确度,并采用该方法对SGTO实际水相产物中低碳醇、醛、酮、酸进行了测定。实验结果表明,在一定质量浓度范围内,低碳醇、醛、酮、酸各组分均呈现良好的线性关系,相关系数大于0.99。标样的回收率在93.4%~109.8%之间,6次重复测定的相对标准偏差小于3.9%。SGTO实际水相产物中低碳(C1~6)醇、醛、酮、酸的分析结果表明,SGTO实际水相产物中低碳(C1~6)醇、醛、酮、酸的总含量(w)在1.5%~3.0%之间;其中,乙醇的含量最高,丙酮其次。 相似文献
42.
43.
介绍气量波动、紧张时,工艺方面的补救措施,包括调整变压吸附、提氢岗位指标,改变气柜高度,控制循环氢等手段。 相似文献
44.
Yun Gao Babak Ghorbanian Hossein Najari Gargari Wei Gao 《Petroleum Science and Technology》2017,35(21):2074-2079
An important step in developing clean energy and reducing greenhouse gas emissions is the use of clean technologies such as gasification. In this work, we were used a bubbling fluidized bed (BFB) to convert the bitumen oil into a clean syngas in presence of three kinds of Ni/dolomite catalysts. While all three catalysts were acceptable in the process of tar elimination, but DN-22 was more successful in eliminating tar than the other two samples, which might be due to the higher amount of CaO in the composition DN-22. With increase in Ni, the amount of eliminated tars in the tar cracking process was also increased due to the delay in the deactivation of the dolomite catalyst. 相似文献
45.
Dynamic Matrix Control of a Bubble‐Column Reactor for Microbial Synthesis Gas Fermentation
下载免费PDF全文
![点击此处可从《化学工程与技术》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A spatiotemporal metabolic model of a representative syngas bubble‐column reactor was applied to design and evaluate dynamic matrix control (DMC) schemes for regulation of the desired by‐product ethanol and the undesired by‐product acetate. This model was used to develop linear step response models for controller design and also served as the process in closed‐loop simulations. A 2 × 2 DMC scheme with manipulation of the liquid and gas feed flows to the column provided a superior performance to proportional integral (PI) control due to slow process dynamics combining the multivariable and constrained nature of the control problem. Ethanol concentration control for large disturbances was further improved by adding the flow of a pure hydrogen stream as a third manipulated variable. The advantages of DMC for syngas bubble‐column reactor control are demonstrated and a design strategy for future industrial applications is provided. 相似文献
46.
The Effect of Additives on Cu/HZSM-5 Catalyst for DME Synthesis 总被引:6,自引:0,他引:6
Meilin Jia Wenzhao Li Hengyong Xu Shoufu Hou Chunying Yu Qingjie Ge 《Catalysis Letters》2002,84(1-2):31-35
The addition of ZnO or ZrO2 into CuO/HZSM-5 was investigated for DME synthesis from syngas by using the reactive frontal chromatography method, TPR and in situ TPR. These promoters enhanced the catalytic activity of Cu/HZSM-5 and promotion with ZnO and ZrO2 produced a maximum activity, which could be explained by the improvement of the dispersion of Cu and the promotion of CuO reduction. The Cu+ species existing during the reaction have been detected, based on which a Cu0 Cu+1 redox cycle model was put forward. 相似文献
47.
A series of monolithic Ni/γ-Al2O3 catalysts with and without basic promoters (Na, Sr, La, Ce) were prepared. Partial oxidation of methane (POM) to syngas was carried out in a continuous-flow, fixed-bed reactor. The influences of reaction conditions, including temperature, CH4/O2 ratio and space velocity, on the performance of the catalyst were investigated. The results show that at a high space velocity of 1×105 h-1, optimal CH4 conversion can be obtained. Effects of promoters such as Na, Sr, Ce, La were also investigated, and the catalyst samples were characterized by means of temperature-programmed reduction and XRD techniques. XRD suggests that the addition of promoters has no influence on the crystal structure of Ni/γ-Al2O3 catalyst. The results show that the addition of a small amount of promoters improves the reducibility and activity of the catalyst. The side reaction CH4 2 O2→CO2 H2O, is fully restrained and 100% H2 selectivity is achieved when Ce and La are used as promoters, respectively. 相似文献
48.
A systematic study of the size effect of zirconia nanocrystals on nickel-catalyzed reforming of methane with CO2 shows that extremely stable Ni/ZrO2 catalysts are obtainable by hydrogen reduction of impregnated nickel nitrate on zirconia particles with sizes less than 25 nm. The same preparation method with larger particles of zirconia results in catalyst samples that deactivate rapidly in the reforming reaction. Comprehensive characterization with XRD, TPR/TPD, and TEM shows that the stable Ni/ZrO2 catalysts are better described as nanocomposites of size comparable to Ni metal (9-15 nm) and zirconia (7-25 nm) nanoparticles. The high percentage of the Ni-zirconia boundary or perimeter in the nanocomposite catalysts is believed to be crucial for the extremely stable catalytic activity. 相似文献
49.
Ni/SiO2, a methanation catalyst, has been shown to exhibit CO insertion activity. In situ infrared studies of CO/H2 and C2H4/CO/H2 reactions on Ni/SiO2 show that carbonylation of Ni/SiO2 to Ni(CO)4 leads to an inhibition of methanation in CO hydrogenation but an enhancement of formation of propionaldehyde in the C2H4/CO/H2 reaction. 相似文献
50.