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51.
《Journal of Process Control》2014,24(8):1225-1236
This paper presents a warm-started Dantzig–Wolfe decomposition algorithm tailored to economic model predictive control of dynamically decoupled subsystems. We formulate the constrained optimal control problem solved at each sampling instant as a linear program with state space constraints, input limits, input rate limits, and soft output limits. The objective function of the linear program is related directly to the cost of operating the subsystems, and the cost of violating the soft output constraints. Simulations for large-scale economic power dispatch problems show that the proposed algorithm is significantly faster than both state-of-the-art linear programming solvers, and a structure exploiting implementation of the alternating direction method of multipliers. It is also demonstrated that the control strategy presented in this paper can be tuned using a weighted ℓ1-regularization term. In the presence of process and measurement noise, such a regularization term is critical for achieving a well-behaved closed-loop performance. 相似文献
52.
The hydrolytic decomposition of dichlorodifluoromethane (CFC-12) on various modified zirconium oxide surfaces has been studied. The reaction was carried out under flow conditions at 500°C. Complete CFC-12 conversion and long-time stability of the catalysts were achieved accompanied by a limitation of the undesired CFC-13 formation. A maximum CFC-12 conversion was observed on catalysts of sulfated zirconia or zirconia obtained from temperature-controlled calcination of zirconium oxide hydrate. The reaction depends on the presence or in situ formation of Brønsted acid sites. FTIR-photoacoustic measurements were performed on pyridine complexes chemisorbed on the catalyst surface in order to analyze the changes in the catalyst's acidity. The effects of the temperature and water in the reaction gas on the catalyzed decomposition of CFC-12 are examined. 相似文献
53.
针对多数流形学习算法是基于单一流形的假设,当高维数据集中存在多个流形,流形学习算法可视化效果差问题,借鉴流形曲面在二维平面空间展开的思想提出基于局部保持的的子流形可视化方法。利用奇异值分解和k均值聚类方法将流形数据划分为多块子流形,计算第一流形切块中心与其余切块中心的拓扑结构关系,在目标低维空间保持上述中心间拓扑结构下逐一对流形切块投影展开,最后在人脸数据集上进行实验。实验结果表明:该方法较好保持了子流形内的数据间的拓扑结构。 相似文献
54.
纳米铜锰复合氧化物固相反应法的制备与表征 总被引:1,自引:0,他引:1
以乙酸铜、乙酸锰与草酸为原料,采用固相化学反应法制备了纳米铜锰复合氧化物前驱物,利用均匀设计考察了微波功率与加热时间、热分解温度及时间对产物粒径的影响。研究表明热分解温度对产品粒径的影响最大。最小粒径产物的制备条件是:微波功率540 W,微波加热时间15 min;热分解温度370℃,热分解时间2 h。XRD和TEM分析结果表明,此产品主要物相为Cu1.5Mn1.5O4,结构属立方晶系,空间群为Fd3m,平均粒径16.9-19.0 nm。应用TG-DTG和DSC技术研究了纳米铜锰复合氧化物的热分解过程以及热分解动力学,采用Ozawa积分法和Coats-Redfern积分法得前驱体的热分解机理函数均为G(α)=[-ln(1-α)]^2/3。 相似文献
55.
为解决EMD-IT去噪算法中阈值难以确定的问题,提出一种基于高斯白噪声能量分布的阈值估计方法。将含噪信号进行经验模态分解并估计各固有模态函数(IMF)中噪声的能量;根据模态单元阈值的含义,在各IMF中利用去除掉的模态单元包含的总能量等于噪声能量这一准则估计阈值。合成数据和实际心电信号的去噪仿真实验验证了该方法的有效性,其是自适应的且避免了阈值选择的主观性。 相似文献
56.
To investigate species-specific decomposition rates of litter from native (Quercus faginea) and introduced (Eucalyptus globulus) tree species in Portugal, we monitored changes in the phenolic signature of leaf litter during decomposition as mediated by an aquatic, Proasellus coxalis (Isopoda: Asellota), and two terrestrial, Porcellio dispar and Eluma caelatum (Isopoda: Oniscidea), detritivores. Although the litter of Eucalyptus and Quercus did not differ in overall protein precipitation capacity, we detected differences in terms of contents of particular phenolic compounds and phenol oxidation products. Accordingly, we observed food-specific consumption rates in Proasellus, but not in the terrestrial isopods. Proasellus digested Eucalyptus at significantly higher rates than Quercus, whereas the opposite was the case for Eluma, and Porcellio digested both litter types equally well. Despite slight differences in detail, effects of Proasellus on changes in the signature of litter phenolics were similar for both litter types, whereas terrestrial isopods—Porcellio and Eluma, although they differed from each other—digestively degraded phenolic compounds in Eucalyptus and Quercus litter, respectively, in different ways. Overall, however, degradation of litter phenolics was similarly effective on both litter types. From these data, we conclude that decomposition of Eucalyptus litter does not proceed more slowly than of litter from native Portuguese trees. 相似文献
57.
The effect of pH on the decomposition of peracetic acid in an aqueous solution was studied. It was found that three potential reactions, namely i) the spontaneous decomposition, ii) the hydrolysis and iii) the transition metal catalysed decomposition, are responsible for the consumption of peracetic acid. The spontaneous decomposition reaches its maximum at pH 8.2, while both the hydrolysis and metal ion catalysed decomposition increase as the pH increases. At pH 10.5 and higher, the hydrolysis becomes dominant when the metal ion catalysed decomposition is minimized by the addition of DTMPA. The kinetics of the peracetic acid hydrolysis was developed, which can very well predict the development of peracetic acid and hydrogen peroxide during the decomposition reaction. 相似文献
58.
微波作用下天然气水合物分解的研究及应用 总被引:16,自引:1,他引:16
介绍了微波和天然气水合物的作用的国内外实验研究进展,说明了微波对天然气水合物的分解有很大的促进作用,分析了用微波加热开采天然气水合物资源、解除天然气输送、开采过程中天然气形成水合物而造成的堵塞等应用的可行性,最后展望了微波在天然气工业中的广泛应用前景。 相似文献
59.
针对传统协同过滤推荐算法存在的冷启动、数据稀疏以及相似度度量的准确性问题,基于LDA主题模型对文本隐式主题挖掘的有效性和KL散度在主题分布相似性度量的准确性,提出了结合LDA主题模型的矩阵分解推荐算法。首先,利用改进的LDA算法输出项目-主题分布,并用困惑度作为主题数设置的修正函数;然后分别基于余弦相似度和KL散度计算得到项目相似度矩阵,将得到的相似度矩阵结合原评分训练集输出预评分,再将预评分填充到训练集;最后将训练集输入ALS矩阵分解算法得到推荐结果。通过MovieLens数据集的实验结果表明,该算法在不同隐式参数设定下均能得到比ALS推荐算法以及更小的预测误差,并且最优预测误差小于传统推荐算法。该实验说明了通过集成LDA主题模型的ALS算法效果要优于其他推荐算法。 相似文献
60.
Bo Hyun Ryu Sang Yup Lee Dong Hyun Lee Gui Young Han Tae-Jin Lee Ki June Yoon 《Catalysis Today》2007,123(1-4):303-309
Carbon black has recently been reported to act as an effective catalyst for methane decomposition and to exhibit stable catalytic behavior despite carbon deposition, and thus it can be used for CO2-free production of hydrogen from natural gas. In this work, various carbon blacks with different primary particle size were investigated with respect to methane decomposition under atmospheric pressure from 1123 to 1223 K. Catalytic characteristics, such as activity, activation energy and reaction order, were investigated and compared. It was observed that with decreasing primary particle size (or increasing specific surface area), the specific activity increased and the activation energy decreased. The reaction orders for various pelletized, rubber-reinforcing carbon blacks were 0.6–0.7, about the same regardless of the primary particle size, while they were near 1 for fluffy carbon blacks. Fluffy carbon black showed higher activity and activation energy than the pelletized carbon black of the same primary particle size. Changes of the surface morphology during carbon deposition were observed by TEM. Variations of the number of active sites were discussed in regard of the primary particle size, carbon deposition and binder. The presence of different types of active sites was also suggested. 相似文献