A three‐dimensional model describing stress‐temperature induced solid phase transformations: solution algorithm and boundary value problems

An always increasing knowledge on material properties as well as a progressively more sophisticated production technology make shape memory alloys (SMA) extremely interesting for the industrial world. At the same time, SMA devices are typically characterized by complex multi‐axial stress states as well as non‐homogeneous and non‐isothermal conditions both in space and time. This aspect suggests the finite element method as a useful tool to help and improve application design and realization. With this aim, we focus on a three‐dimensional macroscopic thermo‐mechanical model able to reproduce the most significant SMA features (Int. J. Numer. Methods Eng. 2002; 55 : 1255–1264), proposing a simple modification of such a model. However, the suggested modification allows the development of a time‐discrete solution algorithm, which is more effective and robust than the one previously discussed in the literature. We verify the computational tool ability to simulate realistic mechanical boundary value problems with prescribed temperature dependence, studying three SMA applications: a spring actuator, a self‐expanding stent, a coupling device for vacuum tightness. The effectiveness of the model to solve thermo‐mechanical coupled problems will be discussed in a forthcoming work. Copyright © 2004 John Wiley & Sons, Ltd.     

常减压蒸馏装置换热网络的节能优化

利用夹点技术理论对耗能严重的某炼油厂常减压蒸馏装置进行用能诊断分析;并结合热力学原理得到两种优化换热网络,节能效果显著。     

石油一厂东蒸馏装置的技术改造

介绍抚顺石油化工公司石油一厂东蒸馏装置的改造情况，通过技术改造，使减压蒸馏塔由生产燃料型改造成生产石蜡－润滑油型，满足了该厂对石蜡和润滑油料的质量要求。     

长25-29井卡钻事故的处理

长２５－２９井在完井阶段通井过程中发生粘附卡钻事故，在处理卡钻过程中又发生卡套铣筒、井漏、溢流等事故及复杂情况。通过对井下情况的认真分析，采取先堵漏后循环再解卡的处理方案，顺利地解除了该次卡钻事故，大大地减少了经济损失。     

全液压稠油热力开采过程井下流体的传热

针对稠油黏度高、密度大、驱替效率低,常规方法开采困难等问题,开展了稠油开采装置研究。介绍了全液压稠油开采装置在原油开采过程中的加热功能,分析了采油装置系统井下流体流动及传热过程。结合理论研究方法和热力学计算,建立了井下流体热交换的物理和数学模型,并对模型进行了分析、矫正和求解。以实际油井参数和液压油的流量、温度为输入参数,通过计算机仿真模拟了井下热交换参数之间的关系,从而改进了已获得的热交换理论方程和模型,并得出了原油的产量与液压油的输入量之间的关系,以及保温提采原油所需要的最小液压油输入量。该模型的建立为进一步研究不同井况和不同输入状态下的流体传热提供了理论依据。     

Kinetic Studies on Cocracking of Petroleum Vacuum Residue with Thermoplastics and Biomass (Petrocrop)

Cracking of petroleum vacuum residue (XVR) and its cocracking with plastics (PP or PS), Calotropis procera (CL) as a binary, ternary, and quaternary mixture of these individual plastics, and CL with XVR was carried out in a Perkin-Elmer thermogravimetric analyzer (TGA) for the purpose of comparing the process of the mixture with those of the individual components. Experiments were conducted at a heating rate of 40 K/min, in the temperature range of 30-900°C. Based on the results obtained, three temperature regimes were selected for studying the nonisothermal kinetics of TGA of individual XVR, plastics, and biomass as well as of the cocracking of these with XVR, i.e., below 400°C, between 400-500°C, and above 500°C. The kinetic studies were performed using the Coats and Redfern kinetic modeling equation. The overall activation energies obtained were 25 kJ/mole for petroleum vacuum residue, 99 kJ/mole for polypropylene, 21 kJ/mole for coal, and 35 kJ/mole for the mixture of all these materials. Thus, it has been found that there exists an overall synergy when three materials were coprocessed together. The overall orders and activation energies change during coprocessing of two or three different macromolecules, including mixed vacuum residue as presently observed. The detailed results that were obtained will be reported.     

辽河减压渣油中金属铁的赋存与分布特征

考察了辽河减渣在吸附分离、酸性溶液萃取和沥青质轻度降解过程中金属铁的分布和转移情况。结果表明，辽河减渣中有近90％的铁富集在胶质和沥青质中，部分铁以侧链较短的环烷酸盐或酚盐形式存在，部分铁连接在沥青质分子的侧链上，或是被包裹在沥青质大分子中。     

新疆重质混合原油研制高等级道路沥青

对利用新疆重质混合原油生产的减压渣油作为基质沥青制备高等级道路沥青进行了研究。考察了低硫石蜡基原油（A）和含硫环烷-中间基原油（B）的掺炼比对基质沥青四组分组成的影响，减压渣油软化点与基质沥青四组分组成的关系，以及添加剂对改进沥青性质的作用。由此得出原油（B）的合适掺炼量，减压渣油软化点的控制范围和优化的生产工艺条件，调合出了符合GB／T18150—2000和JTGF40—2004要求的高等级道路沥青。     

真空技术在污水处理中的若干典型应用

介绍了真空技术在污水处理中的几种典型应用，真空结晶法在以分离污水中具有结晶性能的固体溶剂；真空过滤脱水用于初沉池和消化池污泥脱水，真空浮选法通过制造负压条件加速浮选过程；还有真空搅拌、真空脱气等等。这些足以说明真空技术在污水处理乃至环境保护中占有重要的一席之地。