A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

大坝水平位移监控指标拟定的混合法

用混合法拟定了大坝水平位移的监控指标，即通过结构分析和建立数值 模型，计算大坝水平位移的水压分量和给定概率水平下的温度分量极值，进而拟定水平位移 监控指标，并给出了实例。     

罗茨真空泵的溢流阀与旁通阀的组合

在简要地介绍了罗茨泵功能的基础上，通过溢流阀的改进设计，使溢流阀成为既能旁通又能溢流的组合阀，罗茨泵的功能将更加完备。     

山区水库溢洪道和放水洞工程布置优化组合及型式选择

山区河流上修水库与平原水库不同的是，地形复杂、地质条件各异。要充分利用坝址处的地物地貌及地质条件，如何趋利避害，合理布置水库的土坝走向，放水洞与溢洪道的位置及型式，以取得安全、经济、美观三者协调统一。     

变权组合预测模型在大坝安全监测中的应用

简要介绍了组合预测模型的基本原理，该模型改进了单一模型考虑因素的片面性，但常规的组合预测模型的权系数是固定的。考虑到各种模型的预测精度的变化，以及大坝安全监测数据存在的突变、时效等因素，固定权系数的组合预测模型有待进一步改进。文中提出了变权系数组合预测模型，并将其用于实际的大坝安全监测工程。结果表明，变权组合预测模型的预报精度高于其他模型。是一种值得推广的方法。     

注入剖面五参数组合测井仪的改进

文章介绍了注入剖面五参数组合测井仪及对该仪器的改进与完善，特别是对流量计的结构进行了改进。流量计下端采用水阻尼和机械弹簧两种保护措施，有效地保护了涡轮；过芯加重改成通用加重下挂到涡轮流量计上，有效地减少了涡轮粘污，提高了组合测井仪的测井成功率。改进后测井成功率从60％提高到90％。同时。对数据处理与传输电路也进行了改进，新开发研制了PPM码数据传输体系，使组合仪耐温指标提高到175℃。     

长庆油田陕北区原油破乳剂的筛选和复配

实验考察了8种市售水溶性破乳荆对长庆油田陕北区有代表性的宝塔区、安塞和子长原油(均为低硫中间基-石蜡基原油)的脱水效果(加量100mg／L，脱水温度55℃，时间3h)。目前长庆采油一厂使用的YT-100和延炼集团使用的GT-940对这3种原油的脱水效果均较好，但对子长原油的脱水率不高，分别为69．7％和58．9％。在由所选性能较好的破乳刺组成的4种二元复配物中，GT-940 HQ96-1对3种原油的脱水效果均高于单剂，最佳配比分别为4：1，4：1，3：2；其余3种复配物则对原油有选择性，其中GT-940 YT-100相近(97．5％)；YT-100 HQ96-1仅能改善子长原油的脱水效果，配比为4：1时脱水率最高(76．4％)；SP-169 HQ96-1仅能改善宝塔区原油的脱水效果．配比3：2和2：3时脱水率最高(92．9％)。表5参6。     

A fast evolutionary pursuit algorithm based on linearly combining vectors

In this paper, we propose a fast Evolutionary pursuit algorithm. It searches for optimal discriminant vectors through linearly combining standard bases. Experiments on the Yale and ORL databases verify its effectiveness and enhanced efficiency.     

Familiarity and plausibility in conceptual combination: Reply to Gagné and Spalding (2006).

E. J. Wisniewski and G. L. Murphy (see record 2004-22496-015) suggested that the apparent effects of relation frequency in C. L. Gagné and E. J. Shoben's (1997; see record 1997-02349-004) conceptual combination experiments could be explained by differences between the familiarity and plausibility of their stimuli (noun-noun phrases). However, C. L. Gagné and T. L. Spalding (see record 2006-20573-017) argued that Wisniewski and Murphy's measures of plausibility and frequency are both sensitive to relation frequency. They also suggested that the stimuli were mostly novel, such that differences in familiarity could not explain Gagné and Shoben's findings. The current authors focus on the theoretical rationale for the plausibility and familiarity variables, arguing that the original interpretation of their findings is correct. (PsycINFO Database Record (c) 2010 APA, all rights reserved)