In situ13C NMR study of tert-butanol interaction with moderately concentrated sulfuric acid

An in situ NMR study of tert-butanol dehydration in 95 and 85% sulfuric acid did not indicate the formation of tert-butyl cations as active reaction intermediates. Instead, only NMR lines from oxonium ions under the condition of fast exchange with water and the acid were observed. It is most likely that, in the concentrated acid, the active intermediates of this reaction are represented by tert-butyl sulfuric ester which probably is a precursor of invisible tert-butyl carbenium ions representing short-lived excited or transition states.     

Environmentally friendly, heterogeneous acid and base catalysis for the methylation of catechol: Chances for the control of chemo-selectivity

The properties of catalysts with (i) Brønsted-type acidity (H-mordenite and Al/P mixed oxide), (ii) Lewis-type acidity (Al trifluoride) or (iii) basic characteristics (Mg/Fe mixed oxide) were investigated in the gas-phase methylation of catechol. When methanol was used as the methylating agent, H-mordenite and AlF₃ gave high selectivities to guaiacol (the product of O-methylation) under mild reaction conditions, that is at very low catechol conversions. An increase in temperature led to the transformation of guaiacol to phenol and cresols, and to considerable catalyst deactivation. The basic catalyst Mg/Fe/O also favored an extensive degradation of guaiacol to phenol. On the mildly acidic catalyst Al/P mixed oxide a stable catalytic performance and a high selectivity to guaiacol at 40% catechol conversion were obtained. When methylformate, a more reactive methylating agent, was used with AlF₃ and Mg/Fe mixed oxide as catalysts, higher catechol conversions and slower deactivation rates could be achieved under mild reaction conditions, with a low extent of guaiacol degradation. However, methylformate rapidly decomposed when temperatures above 350 °C were used. Finally, tests were made by reacting catechol and diethoxymethane with acid catalysts, with the aim of synthesizing methylenedioxybenzene. The latter product was obtained with high selectivity, but with very low yield, due to both catalyst deactivation and decomposition of diethoxymethane.     

佛尔哈德法测定氯化除汞上清液中的氯量

控制pH4-6，用锌粉还原氯化除汞上清液中的汞（Ⅱ）离子，取置换后液加入过量的硝酸银标准溶液，以硫酸铁铵溶液作指示剂，用硫氰酸钾标准滴定溶液滴定来测定氯量。该方法的检出限：0．25mg／100mL，回收率：98％-101％。     

Analysis of color symbology from the perspective of cultural semiotics focused on Korean costume colors according to the cultural changes

The purpose of this study was to analyze the symbolization of colors as cultural codes, based on costume colors. In order to study the significance of colors in cultural changes, we carried out a quantitative analysis and interpreted it from the perspective of cultural semiotics. The range of this study was focused on Korean costume colors, over diverse diachronic stages of Korean culture. For this study 1535 color samples were collected, measured with a spectrophotometer, and analyzed quantitatively according their diachronic stages of origin. As a result, red, blue, and yellow were found to be the most frequently used colors during the Chosun Dynasty, a period based on Confucianism. These colors acted as cultural codes with cultural significance. During the Modern times pink, light blue, and black increased in frequency and represented the reception of western culture, the changing sex role of women in society, and utilitarianism. In these days, neutral colors and grayish tones of all colors are the most significant colors of high frequency. The use of such colors is closely related to industrialization, mechanization, functionalism, and the changes of women's sex roles in the societies. They are used as cultural codes, especially to emphasize a rational and masculine image rather than a feminine image. © 2006 Wiley Periodicals, Inc. Col Res Appl, 32, 71–79, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20290     

A new approach to the decomposition of Boolean functions by the method of <Emphasis Type="Italic">q</Emphasis>-partitions. III. Joint decomposition of a function system

The paper considers the set-theoretical approach to the joint decomposition of systems of Boolean functions of variables specified in different representation forms. The approach is based on the method of q-partitions of conjuncterms and concept of decomposition clones. Theorems on joint decomposition of a system of full and partial functions are formulated. The approach is illustrated by examples. Parts I and II of this article are published in No. 5 (2001) and No. 1 (2002). __________ Translated from Kibernetika i Sistemnyi Analiz, No. 2, pp. 39–58, March–April 2007.     

紫杉醇母核全合成的初步思想实验

紫杉醇的全合成困难，许多工作还只能停留在实验室的模型化合物上。作者以思想实验方法提出了：先以Ｄ－Ａ反应形成Ａ环和Ｃ环，然后用两步形成Ｂ环，最后形成Ｄ环，以此完成紫杉醇母核的全合成。     

Trifluoromethanesulphonic acid catalysed transalkylation between tetrabromobisphenol-a and toluene for the production of 2,6-dibromophenol

The preparation of 2,6-dibromophenol is described. This compound, useful as raw material for brominated poly(phenyleneoxide) and pyrogallol or derived pharmaceuticals/pesticides, was prepared in 80% (isolated) yield by a transalkylation reaction between tetrabromobisphenol-A and toluene. The catalyst, trifluoromethanesulphonic acid, can be simply recovered and recycled. Perfluorinated resin sulphonic acid (NAFION-H®, DuPont) did not effectively catalyse this transalkylation.     

房地产开发企业会计核算问题探讨

本文就房地产开发企业会计核算的现状及特点进行了分析,并提出了完善房地产开发企业会计核算规范的对策。     

适用于LED显示屏或照明工程的异步控制卡DS2000-M1

DS2000-M1是高性能、开放式的LED控制系统,本文从软硬件两方面简述其设计原理。