化工容器设计规范述评

分析了压力容器设计标准ＧＢ１５０－８９［１］和ＪＢ４７３２－９５［２］在设计思想和设计方法上的主要区别及按两种标准制造的容器的经济性，提出了选取ＪＢ４７３２－９５作为所遵循的设计规范的一些参考性意见。     

自控系统在加氢反应工艺中的应用

通过对化工生产中加氢反应的危险性简要介绍,并以某药厂对加氢反应工艺自控系统改造时从自控方案选择到自控参量、主要自控设施确定及安装、校验和系统调试等主要过程实施为例,说明此种危险可行性,为药厂类加氢工艺自控系统的技术改造提供相应的参考。     

颗粒流体两相流基本方程中压差力和曳力系数的计算

本文总结了颗粒流体两相流基本方程的压差力表达方式和推导颗粒流体系统曳力系数计算公式的力平衡原理，提出了一种分析压差力的简单方法，阐明了各种压差力表达方式间的关系及对应的两相流基本方程的曳力系数的计算方法     

气—液鼓泡塔中流动域和气含率的分布

利用压力传感器测定了气、液两相鼓泡塔内不同轴、径向位置上压强的脉动信号,分析了压强的脉动特征,计算了各种操作条件下塔内不同轴向位置截面上的平均气含率,发现在不同操作条件下,塔内可能出现不同的流动域分布,即全塔均匀鼓泡域、全塔过渡域、全塔湍动鼓泡域以及均匀鼓泡域,过渡域和湍动鼓泡域中的相邻2种或3种流域同时出现在塔内不同高度上。提出了不同轴向位置流域转变的判据。并发现,同一截面的不同径向位置基本处于同一流域内。同时研究了鼓泡塔内气含率在轴向上的分布规律,给出了不同流动域内气含率的关系式。     

重碱加压过滤的研究探索

在化工领域偿试使用加压过滤技术处理重碱，使重碱水份由真空过滤的１８～２０％降为加压过滤的１２％，可使生产厂家降低能耗；节约返碱     

焦炉加热吸力控制模型及应用

依据焦炉正常生产条件下的系统压力分布,利用焦炉内气流流动方程,建立了燃烧系统参数与各压力控制点的模型。通过计算机仿真与实际结果比较,该模型能够较好的反映焦炉内气体流动规律,对吸力控制具有较好的理论指导意义。     

新型高压密封装置的优化设计

以最低制造成本为优化目标，建立了新型高压密封装置优化设计的数学模型，并给出设计实例。结果表明，采用优化设计可降低制造成本１４．７％。     

焦炉集气管压力专家协调控制

针对压力对象相互耦合的实际特点，提出了基于专家系统的集成管压力协调控制方法，使系统在PID控制的基础上，按实际运行状况智能选择控制策略。     

Correlation of vapor-liquid equilibria for binary mixtures with free energy-based equation of state mixing rules: Carbon dioxide with alcohols, hydrocarbons, and several other compounds

The correlation of vapor-liquid equilibrium data for high-pressure carbon dioxide systems is of interest in a number of industrial applications, including supercritical extraction. Here, we consider the correlation of data for 12 binary systems of carbon dioxide separately with alcohols, with hydrocarbons, and with acetone, benzene, and water. The Wong-Sandler (W-S) and modified Huron — Vidal first order (MHV1) free energy-based equation of state mixing rules (the W-S and MHV1 models) were used in the calculations. Both combined equation of state+free energy models generally resulted in good correlations of the experimental data over wide ranges of temperature and pressure with temperature — independent parameters. However, for the carbon dioxide+water system, the W-S model produced an 11% average absolute deviation in pressure, while no parameter that resulted in an AAD in pressure of less than 20% could be found for the MHV1 model.     

Granulation of a hardmetal powder for spark plasma sintering

A fluidized bed granulation method, pressure swing granulation (PSG), was applied to granulation of a hardmetal powder without pressing lubricants for making the upstream process of spark plasma sintering (SPS) more efficient.

The properties of the granules were examined and compared with those of spray dried granules and extruded ones under the present system using a sieve.

Spherical granules between 0.15 and 0.84 mm in diameter difficult to obtain by the spray drying were obtained with high yield. The flowability of the granules was far better than that of spray dried granules and similar to that of extruded ones. Iron contamination and oxidization during pressure swing granulation were tolerable to the real production.