基于MPSK信号的实用高精度的载频盲估计研究

在现代电子信息中,精确的载频估计是接收信息正确解调的基础。基于MPSK调制信号提出一种实用性、高精度的载频盲估计新算法。利用自相关函数的原理,把谱相关的计算量降到了一般的数字电路可以实现的程度,并且在低信噪比的情况下估计结果优良;通过粗估计和精估计两次运算来提高载频的盲估计精度。经过理论分析和MATLAB仿真验证说明本算法的正确性和可行性。     

Magnesium Ion Doping and Micro-Structural Engineering Assist NH4V4O10 as a High-Performance Aqueous Zinc Ion Battery Cathode

Layered ammonium vanadate materials exhibit significant mass-specific capacity and ion transport rate due to their small molecular weight and large ionic radius. However, the strong electrostatic interactions of Zn²⁺ and V–O bonds and the fragile ionic bonding of N-H^…O bonds hinder their development. Therefore, this work reports Mg²⁺ doping NH₄V₄O₁₀ materials accompanied by flower-like morphology to lower the migration energy barrier and inhibit amine dissolution. Owing to the 3D-flower-like morphology and the combined impact of Mg²⁺ and structural water, the binding of Zn^2+…V-O is significantly enhanced and additional ion channels were constructed. Pre-intercalated Mg²⁺ enhances the structural integrity and prevents irreversible deammoniation from obtaining excellent cyclic stability. Density functional theory (DFT) calculations show that MNVO provides a smoother Zn²⁺ diffusion path with a lower migration barrier. Benefited from these advantages, the MNVO cathode exhibits a high specific capacity of 410 mAh g⁻¹ at 0.1 A g⁻¹, satisfactory cyclic stability (90.2 % capacity retention at 10 A g⁻¹ after 5000 cycles), and capable rate ability (118 mAh g⁻¹ at 25 A g⁻¹) within 0.4-1.5 V. Furthermore, the zinc ion storage mechanism in the MNVO cathode is investigated through multiple analyses.     

量子阱红外探测器掺杂阱中能级的计算

量子阱中能级位置的确定是获得量子阱红外探测器其它设计参数的基础。为了提供足够的载流子跃迁,阱层一般为重掺杂层。重掺杂使半导体材料禁带宽度变窄,从而改变量子阱中能级的位置。通过对不同温度、量子阱区不同掺杂浓度条件下的量子阱材料PL 谱进行测量,得出PL 谱峰值波长对应的电子跃迁峰值能量,它与阱中基态能级的位置有关。分别计算了考虑和不考虑禁带变窄效应时的电子跃迁峰值能量,并与实验结果相比较,可以看出考虑禁带变窄效应时与实验结果相吻合,因此掺杂量子阱区能级的计算需要考虑禁带变窄效应,这样可以较为精确的得出阱中能级的位置。     

The design of spin filter junction in zigzag graphene nanoribbons with asymmetric edge hydrogenation

Using the non-equilibrium Green’s function method combined with the density functional theory, we investigate the electronic transport properties of a heterostructure based on zigzag graphene, This heterostructure consists of H2–NZGNR–H and H–NZGNR–H. Results show that a perfect dual spin filtering effect can be realized with the parallel (P) and antiparallel (AP) magnetiesm configuration, and some magnetic domain walls (DW) at the interface between two component ribbons. The magnetic moments, DOS and PDOS, the transmission pathways and LDOS demonstrate that the edge of C–H2 bonds have important effects for magnetic and spin dependent transport properties compared to the edge of C–H bonds. Our results show that the H2–ZGNR–H/H–NZGNR–H heterostructure holds promise for magneto electronics devices which can keep steady properties when change the widths of the two component ribbons.     

Relationship between HOMO energy level and open circuit voltage of polymer solar cells

A series of π-conjugated polymers (PDHF-BT and PDHF-TBT) with 4-(3,4-ethylenedioxythienyl)-2,1,3-benzothiadiazole (BT), 4,7-bis(3,4-ethylenedioxythienyl)-2,1,3-benzothiadiazole (TBT), and 9,9′-dihexylfluorene were synthesized by the Suzuki coupling reaction. The HOMO energy level of PDHF-BT was −5.47 eV, which was lower than that of PDHF-TBT (−5.22 eV), while the LUMO energy level of PDHF-BT (−3.45 eV) was very similar to that of PDHF-TBT (−3.42 eV). These energy levels of PDHF-BT and PDHF-TBT were also supported by a DFT calculation. The power conversion efficiency (PCE) of the polymer solar cell (PSC) with a structure of ITO/PEDOT:PSS/PDHF-BT:PCBM (1:1)/Al was determined as 0.34% and it was larger than that of the device based on PDHF-TBT (0.22%). Correspondingly, the V_oc of the PSC based on PDHF-BT (0.71 V) was much larger than that of the device based on PDHF-TBT (0.40 V). The results support that the V_oc of polymer based PSCs is strongly related to the HOMO energy level of the active polymers.     

浅谈厂用电继电保护配置与整定的重要性

通过一起火电机组的非停事故,来分析其厂用电继电保护配置与整定存在的问题,提高从业人员对继电保护整定或核算工作的重视性.     

基于Mathcad系统对解决统计教学问题中的相关应用

针对Mathcad 系统的特点,阐述了应用Mathcad 系统对解决统计学教学问题中所进行的数据计算,图形绘制和统计决断等这些问题提出思路与方法,不仅可以轻松地解决统计学中繁杂的数值处理和计算问题,而且能够用Mathcad系统绘制准确生动的统计学图表和通过编程让Mathcad系统自动做出科学的统计判断。     

水轮机固定导叶与活动导叶周向相对位置的优化计算

基于无粘－边界层选代的计算模型，以水轮机导水机构的水力损失为目标函数，对固定导叶与活动导叶的周向相对位置进行了优化计算．与有关实验结果的定性比较表明本文的计算结果是合理的．     

管理也是生产力──西北院“八五”国家重点科技攻关管理工作体会

管理也是生产力──西北院“八五”国家重点科技攻关管理工作体会张明瑶，阎力（电力工业部西北勘测设计研究院，西安，７１０００１）Ｂｒｉｅｆｉｎｇｔｈｅｓｔｕｄｙａｃｈｉｅｖｅｍｅｎｔｓｏｆｔｈｅｋｅｙｓｃｉｅｎｔｉｆｉｃａｎｄｔｅｃｈｎｉｃａｌｐｒｏｂｌ...     

三峡船闸岩质高边坡稳定性分析

三峡永久船闸系在花岗岩体系中深挖修建，两侧形成一般高度７０－１２０ｍ、最大高度达１７０ｍ的人工开挖岩质高边坡。边坡稳定是保证通航建筑物的安全与正常运行的基本前提。取船闸区的典型断面为分析对象，考虑自重、地下水渗压力、地震力及预力锚索锚固力等荷载作用，对边坡稳定进行了极限平衡分析。结果表明，边坡具有足够的稳定性。