单轴-平面W型复合锶铁氧体的制备及其吸波特性研究

用草酸盐共沉淀和微量掺杂法研制六角晶系W型Ni,Zn,Co,Al多元复合锶铁氧体，通过调节Ni2W同Co2W的摩尔比例，可使该种铁氧体易磁化方向从C单轴型向垂于C轴的平面型转化，控制置换锶铁氧体中部分Fe3 的微量掺杂Al3 ，可以调整4πMs值，提高磁晶各向异性场，测试分析了5种不同含Co量的W型复合锶铁氧体粉料涂层的吸波特性，发现其自然共振吸收峰随Co含量增加向低频方向偏移，最高吸收峰可达32．8dB，是适用于电子隐形技术的高品位的微波吸收剂。     

氧化还原功能纤维的研究 Ⅷ．含正丙胺基吸附剂与Au~（3＋）的氧化还原反应机理

通过元素分析、红外光谱分析、光电子能谱分析以及扫描电子显微镜分析等手段，证实含正丙胺基吸附剂与Ａｕ３＋的氧化还原反应过程中，氮原子邻近的羟基碳或Ｃ－Ｈ键被氧化，而氮原子并未参与氧化还原反应；吸附态Ａｕ（３＋）最终部分被还原成单质金；在非水介质中吸附在吸附剂上的金聚集成颗粒状。     

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本文介绍了采用复合吸收剂净化天然气的试验结果,在现有三甘醇等脱水剂中添加单乙醇胺,在脱水的同时脱除H_2S,在保证净化气露点低于-21℃的条件下,使净化气中H_2S含量亦低于5mg/m～3。     

Effect of bismuth replacement at barium site in Y-Ba-Cu-O system

X-ray diffraction, electron paramagnetic resonance, microwave absorption and resistivity measurements were carried out on YBa_2−x Bi _x Cu₃O₇ (0≤x≤0·5) superconductors in order to study the effect of bismuth on the structural and superconducting properties. A decrease in sintering temperature increased the amount of impurity phase. Transition from an orthorhombic (superconducting) phase to tetragonal structure produced no significant change in EPR zero-field signal at liquid nitrogen temperature (LNT). The non-resonance signal height decreased on higher concentration of bismuth. Sintered YBa_2−x Bi _x Cu₃O₇ superconductor had a strong EPR zero-field signal at LNT. We have evaluated particle size from XRD and EPR studies. The average particle size was about 0·4μm.     

油酸乙二醇单酯在基础油与水界面上形成吸附膜的研究

以油酸和乙二醇为原料，在酸性催化剂作用下，用硼酸间接酯化法合成了润滑油油性油酸乙二醇单酯，用界面张力仪测定了单酯含量的矿物油的界面张力。用量小二乘法求得油中油酸乙二醇单脂的浓度与油对水界面张力关系的回归方程。依据所求的回归方程和Ｇｉｂｂｓ公式计算出油酸乙二醇单脂在油与水界面上形成吸附膜时的最低浓度。     

Al,Ga取代Bi：DyIG薄膜的磁和磁光特性的研究

本文报道用热分解法在玻璃衬底上制备了Ａｌ和Ｇａ取代的Ｂｉ：ＤＹＩＧ薄膜，对其磁和磁光特性做了详细研究．Ａｌ和Ｇａ取代的薄膜均可获得好的矩形比和高的矫顽力．对于Ｂｉ１．２Ｄｙ１．８Ｆｅ５－ｘＭＸＯ１２（Ｍ＝Ａ１，ＧＺ）薄膜，Ａ１和Ｇ２的最佳替代成份分别为１．０和Ｇ．７；最佳晶化温度分别为７００ｏ℃和６７５℃．在波长５１０ｎｍ附近，法拉第旋转角可达８°／ｕｍ左右．光学吸收和品质因子的研究结果表明，Ａｌ和Ｇａ取代能够影响光学吸收和品质因子，其中Ｇａ取代对光学吸收和品质因子的影响较大．     

Synthesis and characterisation of carboxylic acid and diphenylphosphine derivatives in the 1,3-diyne series: Spectral properties of polydiacetylene carboxylates

Symmetrically substituted 1,3-diynes containing hydroxyalkyl ( 1a-d ), bromoalkyl ( 1e-h ) (diphenylphosphinyl) ( 1i-k ) and carboxyalkyl ( 2a-d ) substituents have been prepared and characterised; the phosphine derivative ( 1k ) has been converted with alkyl iodides ( RI ; R = Me, Et) into bis(phosphonium) salts ( 1l and m ). During preparation of the diynedioic acid. ( 2a ), the non-centrosymmetrical diyne, HO₂CCH₂C?C—C?C(CH₂)₂OH ( 3 ), was also isolated. ⁶⁰Co γ-Irradiation of diacetylene monomers ( 2a – d ) and 10,12-tricosadiyn-1-oic acid gave the corresponding polydiacetylene derivatives ( 4a – d and 5 ), respectively. Rubidium salts of ( 4c ) and ( 4d ), a barium salt of ( 4c ), and a potassium salt of ( 5 ) were prepared and isolated; soluble potassium salts of the carboxylic acid polymers ( 4 ) were generated in aqueous solution. The effects of changes in pH on the UV/visible absorption spectra of aqueous solutions of selected carboxylic acid polydiacetylenes have been recorded, and are discussed.     

Ammonia-water absorption machines for refrigeration: theoretical and real performances

In principle, absorption chillers of the ammonia-water type could work at temperatures well below the usual air-conditioning temperatures, arriving at the range 250–260 K, which can be useful for refrigeration applications. This possibility is studied for an air-cooled machine, comparing the results with the experimental data supplied by a manufacturer that recently commercialized such a refrigerator. The prediction is fair, and the study allows an insight into the internal parameters and into the possible behaviour for more severe conditions than those studied.     

X-ray microtomography: Application to microstructure analysis of a cementitious material during leaching process

Leaching of cementitious materials leads to an increase in porosity, which has important consequences on transport and mechanical properties. The present study outlines the characterization of microstructural evolution in a mortar subjected to a chemical attack, by means of a powerful non-intrusive experimental method, namely synchrotron X-ray computed microtomography. This innovative method is used to measure the variation of porosity in a leached mortar. Having described the effects of leaching in mortar (influences on microstructure and on mechanical properties), we present the accelerated leaching process and the microtomographic analysis that have been used to monitor it. We then investigate the capacity of this method to quantify the evolution of porosity during the leaching process. The method is validated by comparison of the results obtained with data available in the literature.