刚性卵形弹丸对半无限厚铝合金靶的穿深方程

基于圆柱形空腔膨胀模型,将靶板变形所做的塑性功等效为刚性弹在整个侵彻过程所消耗的动能,对用于计算刚性卵形弹侵彻半无限厚铝合金靶板的侵深公式进行了推导.利用MTS万能试验机对2A12T4、6061T6、7075T6共3种铝合金材料进行了室温下的静态力学性能实验,得到了它们的真实应力-应变曲线,并将各参数代入侵深方程进行计...     

铝材防锈油的研制

铝材防锈油是以精制矿物油为基础油,加入成膜剂、多种防锈剂和抗氧剂研制而成.实际使用证明,该油的防锈效果好,防锈期在1年以上.     

先驱体法制备氮化硼纤维的研究

以三聚氰胺和硼酸为原料,用有机化学法合成先驱体,制备氮化硼纤维。采用中和滴定法、红外吸收光谱、X射线衍射及扫描电镜进行氮化硼纤维的氮含量的测定及结构分析。结果表明:合成的先驱体是结晶体,晶体发育良好;制得的氮化硼纤维具有B-N键、B-N六元环的特征吸收;随着氮化处理温度的提高, 氮化硼纤维的氮含量增加;用扫描电镜观察1 700℃制得的氮化硼纤维的直径为2-5μm,长径比为20- 100,氮含量为53．46％。     

化学共沉淀法制备氢氧化铝镁溶胶的研究

对铝镁氢氧化物溶胶制备的反应条件进行了研究,结果表明：溶胶的最佳pH值范围为9．0—9．2。溶胶中铝镁摩尔比随混合溶液中铝镁摩尔比的增加而增加,但总是低于混合溶液中的配比;随着混合溶液中铝镁摩尔比的增加溶胶的固体含量降低,产率下降。     

强烈塑性变形超塑材料研究进展

强烈塑性变形可以用于制备超细晶金属材料,超细晶金属材料一个典型的特性是具有高应变率和/或低温超塑性。介绍利用强烈塑性变形研制超塑铝、镁合金的研究近况,并对强烈塑性变形超塑材料的研究进行展望。     

SiCp/ZL109复合材料摩擦磨损性能研究

以探讨SiCp增强颗粒对SiCp/Al复合材料摩擦磨损机理的影响为目的,采用搅拌铸造法制备SiCp/ZL109复合材料并进行摩擦磨损性能测试。通过SEM微观形貌观察及能谱分析等手段研究材料摩擦性能及机制,结果表明:添加SiCp增强颗粒能够有效地改善基体材料硬度和耐磨性,提高基体材料的摩擦因数;复合材料的磨损机制为粘着磨损、氧化磨损和磨料磨损的混合型磨损;SiCp在材料的磨损过程中起双重作用,在破碎前保护基体,减少基材粘着磨损;破碎后产生硬质点,对基体造成磨料磨损。     

Multicomponent bulk metal nitride (Nb1/3Ta1/3Ti1/3)N1−δ synthesis via reaction flash sintering and characterizations

In this research, near fully dense single phase bulk multicomponent transition metal nitride (Nb_1/3Ta_1/3Ti_1/3)N_1−δ has been successfully synthesized from mixed commercial powders of NbN, TaN and TiN via reaction flash sintering technique. This was performed with an applied pressure of ~ 35 MPa at 25°C under a constant DC electric field (~24-32 V/cm). The flash event, which is the abrupt increase in current (up to ~ 25.2 A/mm²) and temperature, occurred without preheating. The threshold power dissipation on the sample right before the flash is ~ 0.7 W/mm³. The formation of single phase (Nb_1/3Ta_1/3Ti_1/3)N_1−δ random solid solution and its compositional uniformity were confirmed by XRD and EDS, respectively. The effects of ball milling duration and limiting current density on phase formation were studied. Simulation based on Joule heating provides an estimate of the ultimate sample temperature of ~ 1850°C. Vickers hardness of the obtained (Nb_1/3Ta_1/3Ti_1/3)N_1−δ is 17.6 ± 0.6 GPa, which is comparable to similarly flash sintered ingredient binary nitrides of TaN and NbN. TGA in air shows that the oxidation resistance of (Nb_1/3Ta_1/3Ti_1/3)N_1−δ is better than that of TaN and NbN but inferior to TiN. The study demonstrates that reaction flash sintering can be a highly efficient technique for synthesizing bulk multicomponent ceramics for both material fundamental investigations and application development.     

Improved thermal conductivity of β-Si3N4 ceramics by lowering SiO2/Y2O3 ratio using YH2 as sintering additive

A two-step sintering process was conducted to produce β-Si₃N₄ ceramics with high thermal conductivity. During the first step, native SiO₂ was eliminated, and Y₂O₃ was in situ generated by a metal hydride reduction process, resulting in a high Y₂O₃/SiO₂ ratio. The substitution YH₂ for Y₂O₃ endow Si₃N₄ ceramics with an increase of 29% in thermal conductivity from 95.3 to 123 W m⁻¹ K⁻¹ after sintered at 1900°C for 12 hours despite an inferior sinterability. This was primarily attributed to the purified enlarged grains, devitrified grain boundary phase, and reduced lattice oxygen content in the YH₂-MgO-doped material.     

Broadband deep-red-to-near-infrared emission from Mn2+ in strong crystal-field of nitride MgAlSiN3

Broadband near-infrared (NIR) phosphors have received increasing attention for fabricating phosphor-converted light-emitting diodes (pc-LEDs) as NIR light source. Most of the reported broadband NIR phosphors originate from Cr³⁺ in weak crystal field environments. Herein, we report a luminescent material, MgAlSiN₃:Mn²⁺ with CaAlSiN₃-type structure, demonstrating that broadband deep-red-to-NIR emission can be achieved via doping Mn²⁺ into crystallographic sites with strong crystal field in inorganic solids. This phosphor is synthesized via easy-handle solid-state reaction, and the optimized sample, (Mg_0.93Mn_0.07) AlSiN₃ shows an emission band with peak at ~754 nm, FWHM of 150 nm, and internal quantum efficiency of 70.1%. The photoluminescence intensity can further be enhanced by co-doping Eu²⁺ as sensitizer. This work provides a new strategy for discovering new broadband NIR phosphors using Mn²⁺ in strong crystal field as luminescence center.     

Boron nitride-reinforced polysilazane-derived ceramic composites via direct-ink writing

In this study we investigate the use of hexagonal boron nitride (hBN) as a rheology modifier in polysilazane resin to enable direct-ink writing (DIW) of polysilazane-derived boron nitride-reinforced ceramic composites. hBN is shown to effectively modify the flow properties of the resin by imparting strong shear thinning and yield stress behavior, and to reduce the mass loss and shrinkage associated with the polymer-to-ceramic conversion process, when compared with unfilled polysilazane resin. DIW inks are formulated with 40 vol.% hBN and used print flexural specimens and complex structures with high resolution. Mechanical properties of the resulting polymer-derived ceramic composites were evaluated by 3-pt. flexure and Vickers microhardness. The printed composites exhibit flexural strength of 56.4 MPa and microhardness of 111.4 HV2.