差动传感测量釉层热应力

本文介绍一种以差动传感原理测量冷却过程中釉层热应力的方法及装置，并对该装置的测量误差进行了分析。     

Effect of Fe-doping followed by C+SiO2 hybrid layer coating on Li3V2(PO4)3 cathode material for lithium-ion batteries

A novel Li₃V₂(PO₄)₃ composite modified with Fe-doping followed by C+SiO₂ hybrid layer coating (LVFP/C-Si) is successfully synthesized via an ultrasonic-assisted solid-state method, and characterized by XRD, XPS, TEM, galvanostatic charge/discharge measurements, CV and EIS. This LVFP/C-Si electrode shows a significantly improved electrochemical performance. It presents an initial discharge capacity as high as 170.8 mA h g⁻¹ at 1 C, and even delivers an excellent initial capacity of 153.6 mA h g⁻¹ with capacity retention of 82.3% after 100 cycles at 5 C. The results demonstrate that this novel modification with doping followed by hybrid layer coating is an ideal design to obtain both high capacity and long cycle performance for Li₃V₂(PO₄)₃ and other polyanion cathode materials in lithium ion batteries.     

高岭石-氨基硅烷插层复合物的制备与表征

以高岭石-甲醇(K-M)复合物为前驱体,利用置换法于常温下制备了3种高岭石-氨基硅烷插层复合物。用X射线衍射、Fourier变换红外光谱仪、透射电子显微镜、热分析仪等对复合物进行了表征。结果表明:3种高岭石-氨基硅烷插层复合物的层间距均扩大至2nm以上,插层率都大于95%。3种氨基硅烷分子均和K-M前驱体的甲氧基共同存在于高岭石层间,均呈两层倾斜排列,倾斜程度不同。氨基硅烷的插入破坏了高岭石层间的氢键,加剧了高岭石自身结构中硅氧四面体片层与铝氧八面体片层之间的错位,使得复合物片层出现不同程度的卷曲变形。3种高岭石-氨基硅烷插层复合物的热分解过程均分三步进行:表面水的蒸发及层间甲氧基的脱嵌分解、插层剂氨基硅烷分子的脱嵌、高岭石脱羟基。     

碳纤维传动轴胶接胶层应力均匀化分析

碳纤维传动轴胶接联接在传递载荷时,会出现端部胶层应力大、中间应力小的现象,这种现象会使胶接接头的胶层首先从端部破坏,影响联接性能。从应变角度阐述胶接胶层应力曲线规律,说明了影响胶层应力分布的因素有胶层内、外周向变形量和胶层厚度,提出几种胶接胶层应力均匀化方法,并用有限元分析方法进行了验证。结果表明:(1)增加胶层厚度可以使胶层应力均匀化,但均匀化程度不明显,且在工程中会增加胶层缺陷;(2)采用变胶层厚度的鼓形结构胶接能够使胶层应力均匀化明显,最后指出影响鼓形胶接胶层应力均匀化的因素有变厚度胶层长度L、胶层的最大厚度H。     

聚合物电解质膜燃料电池气体扩散层上新型双层微孔层的制备和性能

聚合物电解质膜燃料电池（PEMFC）的微孔层对电池性能有重要影响。首次使用多壁碳纳米管（MWCNTs）在碳纸上先制备1层微孔层,再用碳黑（CB）在其上制备第2层微孔层,形成双层微孔层。从不同尺度上观察了微孔层（MPL）的形貌和结构,测量了气体扩散层（GDL）垂直向电阻,并测试了电池性能。结果表明,双层微孔层的平整程度与单独使用碳黑制备的微孔层相似,比单独使用MWCNTs制备的微孔层更加平整;双层微孔层的GDL垂直向的电阻比单层微孔层的GDL更小;使用双层微孔层制备的膜电极比相同碳载量下的单层微孔层制备的膜电极性能更好。     

薄板弯曲时树脂基碳纤维智能层的力阻响应

将智能层附于足够大的矩形薄板表面,通过不同的弯曲试验构造出多种表面应变状态,基于三种工况下的试验结果,建立智能层电阻变化与平面二维应变状态之间的映射关系,该关系表明纵向应变对智能层的电阻变化的影响占主导地位。在此基础上对其它工况下智能层的电阻变化率进行了预测,其结果与实验结果具有较好的一致性。     

From Laboratory Experiments to Design of a Conveyor-Belt Dryer via Mathematical Modeling

Abstract

A conveyor-belt dryer for picrite has been modeled mathematically in this work. The necessary parameters for the system of equations were obtained from regression analysis of thin-layer drying data. The convective drying experiments were carried out at temperatures of 40, 60, 80, and 100°C and air velocities of 0.5 and 1.5 m/sec. To analyze the drying behavior, the drying curves were fitted to different semi-theoretical drying kinetics models such as those of Lewis, Page, Henderson and Pabis, Wang and Singh, and the decay models. The decay function (for second order reactions) gives better results and describes the thin layer drying curves quite well. The effective diffusivity was also determined from the integrated Fick's second law equation and correlated with temperature using an Arrhenius-type model. External heat and mass transfer coefficients were refitted to the empirical correlation using dimensionless numbers (J _h , J _D  = m · Re ⁿ ) and their new coefficients were optimized as a function of temperature. The internal mass transfer coefficient was also correlated as a function of moisture content, air temperature, and velocity.     

ESTIMATION OF THE EFFECT OF PRODUCT SHRINKAGE ON THE DRYING TIMES,HEAT INPUT AND CONDENSER LOAD OF THE PRIMARY AND SECONDARY DRYING STAGES OF THE LYOPHILIZATION PROCESS IN VIALS

ABSTRACT

The effects of cake shrinkage on the drying times and energy requirements of the primary and secondary drying stages of the freeze drying process involving the drying of a material in a vial, are estimated through the construction and solution of an extended unsteady state and spatially multidimensional model that accounts for the changes introduced by cake shrinkage on the internal and external mass and heat transfer mechanisms of the freeze drying     

微型离心泵泵叶三层式滑块机构三板模具设计

针对微型离心泵泵叶塑件成型模具设计困难的问题,设计了一种改进型三板点浇口模以用于该泵叶塑件的成型。塑件的浇注成型应用3个点浇口来进行平衡注塑,以控制塑件成型变形。模腔布局为1模1腔。针对塑件叶槽区域脱模困难问题,设计了一种3层3次复合抽芯脱模用于难脱模叶槽部位特征的脱模,机构中,将叶槽部位特征的成型块分割成2层成型件后,机构的第一次抽芯动作由弹簧驱动上层滑块实施上层成型块的抽芯;机构的第二次抽芯由斜导柱驱动实施下层成型块的抽芯;最后,由弯销驱动基座滑块带动2个侧抽芯滑块向外抽芯,以让出塑件完全顶出脱模的运动空间。第二次抽芯、第三次抽芯的驱动动力分别由模架模板的第三次开模、第四次开模打开来进行驱动。塑件的最终脱模由油缸驱动顶针板及顶杆顶出而实现塑件的完全脱模。基于塑件、流道脱模及抽芯机构的动作需要,将典型三板点浇口模架改进为四板4次开模点浇口,从而能使塑件、流道废料及驱动滑块机构分次按序来实施抽芯脱模。模具脱模机构动作设置合理,机构结构设计巧妙,模具整体工作可靠,有较好的设计参考价值。     

Development of a Failure Model for the Adhesively Bonded Tubular Single Lap Joint

The accurate calculation of the stresses and torque capacities of adhesively bonded joints is not possible without understanding the failure phenomena of the adhesive joints and the nonlinear behavior of the adhesive.

In this paper, an adhesive failure model of the adhesively bonded tubular single lap joint with steel-steel adherends was proposed to predict the torque capacity accurately.

The model incorporated the nonlinear behavior of the adhesive and the different failure modes in which the adhesive failure mode changed from bulk shear failure, via transient failure, to interfacial failure between the adhesive and the adherend, according to the magnitudes of the residual thermally-induced stresses from fabrication.