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11.
Xiang‐Dan Li Zhen‐Xin Zhong Sang‐Hoon Han Seung Hee Lee Myong‐Hoon Lee 《Polymer International》2005,54(2):406-411
From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry 相似文献
12.
Vatroslav Bubalo Vjekoslav Jerolimov Ivo Bau
i Mladen Andreis Zorica Veksli 《Polymer International》2005,54(5):848-853
The electron‐spin‐resonance (ESR) spin‐probe method, was used to study the heterogeneity of denture resins based on poly(methyl methacrylate). Results for three resins processed by microwave energy, conventional curing and cold curing (depending on the curing procedure and exposed to ageing in various environmental conditions) were compared. All three cured resins were stored over the same time (1200 h) in distilled water at ambient temperature and in artificial saliva at 348 K. The temperature‐dependent ESR spectra of a spin probe dispersed in the denture resins are analyzed in terms of line‐shapes and line‐widths. The appearance of two spectral components was taken as an indication of resin heterogeneity. The results reveal that the cold‐cured resin has a lower local density in comparison with microwave and conventionally cured resin. The amount of residual monomer also contributes to the local motion of polymer segments. The change of denture resins exposed to ageing is influenced both by the structure of the original resin and the ageing conditions. Restricted motion of a spin probe incorporated into the acrylic resins exposed to accelerated ageing suggests additional crosslinking of polymer chains. The differences are observed for all the investigated resins, but the highest change is observed with the cold‐cured resin. The ESR results are accompanied by Tg and Tm measurements. Copyright © 2005 Society of Chemical Industry 相似文献
13.
增塑对UV固化型高分子固体电解质性能的影响 总被引:1,自引:0,他引:1
将合成的大分子量的聚乙二醇丙烯酸酯(PEGDA)齐聚物与光引发刑、LiClO4组成光敏体系,与一定比例的碳酸乙烯酯(EC)、碳酸丙烯酯(PC)或其混合物进行混合,经紫外光辐照制得了一种新型的高分子固体电解质膜,考察了增塑刑种类和用量对光固化速率、电导率和机械性能的影响。结果表明,增塑是提高UV固化型高分子固体电解质导电性能的有效方法,在机械性能满足使用要求的条件下,增塑的UV固化型固体电解质的电导率可以高达10^-4S/cm左右。 相似文献
14.
15.
Finite element analyses (FEA) of thermosets are often performed on the basis of rheological data for fully cured resin. For the FEA of thermosets during curing, a material model is established and a technique is demonstrated, which allows the rheological data of the linear viscoelastic material to be derived. As the moduli are sensitive to conversion, all measured properties are related to temperature and conversion. Therefore the basis for the rheological data has to be a suitable reaction kinetic. Based on the kinetics shear and compression properties are measured independently and modeled mathematically with the focus to gain a formulation, which is suitable for FEA. The considered time constants are in the range between one second and one month as these times are relevant for the investigated relaxation times. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1868–1872, 2003 相似文献
16.
桐油改性酚醛树脂的结构及固化过程的研究 总被引:8,自引:0,他引:8
通过桐油与苯酚在酸性催化剂存在下反应,然后再在碱性催化剂存在与甲醛反应制得了一种热固性桐油改性酚醛树脂。利用红外光谱,差示扫描量热法分析技术对改性树脂的结构及固化反应过程进行了研究。 相似文献
17.
LuZhengerc 《低温建筑技术》1998,(1):28-29
介绍了应用在预应力砼T型梁的C50级砼的冬季施工配制措施,并给出了-10℃条件下的砼有效配合比及冬季45℃±5℃蒸汽养生法措施。 相似文献
18.
优化SMC模压工艺控制制品收缩率和表面粗糙度 总被引:1,自引:0,他引:1
优化SMC模压工艺参数:模压压力分为二阶段,选定最佳压力释放时机和压力;适宜降低模压温度。可显著降低SMC制品的固化收缩率,提高其表观质量、试验表明,同时采用的线收缩率和表面粗糙度两种检测和村定方法具有很好的同一性。 相似文献
19.
双马来酰亚胺树脂体系的固化反应研究 总被引:2,自引:0,他引:2
利用DSC及原位FTIR技术研究了双马来酰亚妥树脂体系的固化反应,获得了在固化反应过程中各组分的转化率与时间的关系,结合热分析数据,确立了最佳固化工艺。 相似文献
20.
This paper concerns a study of the combined effects of curing conditions and environmental exposure on the ultimate properties of two commercial woven carbon/epoxy laminates. Curing parameters (heating rate and applied pressure) were varied so as to obtain six different conditions for each material. Moisture saturation was also achieved by exposing some of the cured samples to environmental conditions of 70°C and 95% relative humidity. Four different tests (tensile, impact, Mode I and Mode II interlaminar fracture resistance) were therefore performed, and the results obtained on the different materials before and after moisture saturation compared. Neither curing pressure nor heating rate nor moisture absorption were observed to have any practical effect on tensile and impact properties. On the contrary, one noticeable effect was the interlaminar fracture resistance of the laminates. The results are discussed and interpreted in terms of damage formation and stress intensification mechanisms. 相似文献