Equilibrium Studies of the System'(Fe,Co)O'–(Fe,Co)3O4 by Solid-State emf Measurements in the Temperature Range 970 to 1370 K

The equilibrium reaction 3'(Fe, Co)O'( ss ) +1/2O₂ ( g ) ⇄ (Fe, Co)₃O₄( ss ) was studied in the temperature range 970 to 1370 K for seven different total compositions of molar ratios 0.5 < Fe/(Fe + Co) ≤ 1.0. The equilibrium pressures of oxygen were determined by using galvanic cells incorporating calcia stabilized zirconia as solid electrolyte and the Fe/Co ratios in the solid-solution phases by wavelength dispersive spectrometry microprobe analyses. The activities of 'FeO' in the cobaltowüstite phase were then derived from the experimental results obtained.     

应用光度分析法测定铁和渣中的微量镓

用光度分析法测定镓，为适应多种试样的测定，补做了个别条件试验。用该方法测定了铁、渣、浸钒渣等六种不同类型试样中镓的含量，分析其精度精度符合要求。     

Lubricating behavior of iron rhenate and its relation to matching pairs

The iron rhenate was compounded by chemical method, which may be generated during wear process of Fe-Re alloys at elevated temperature. The friction coefficient of iron rhenate has been determined by a pin-on-disc device. The results show that iron rhenate plays role of lubricating at RT-600 °C. The lubricating behavior is related to the matching pairs. The hardness of the materials of matching pairs, compatibility of iron rhenate with materials of matching pairs and surface roughness of disc affect the lubricating behavior of iron rhenate mostly. The principle of matching pairs is proposed. Project supported by the National Natural Science Foundation of China Synopsis of the first author Xiong Dangsheng. associated professor, born in 1960. Current research fields include high-temperature self-lubricating alloys and tribological properties of material.     

创新铁路运输方式实现750m^3高炉富余铁水分流

针对750m^3高炉铁水生产富余状况，制订了富余铁水向铸铁机铸铁的调送方案，通过创新思维、系统挖潜、优化资源配置等措施的实施，保证了750m^3高炉的正常生产，取得了良好效果。     

具有厚大断面的大型球墨铸铁铸件的生产

首先通过电炉—LF精炼炉—VD精炼炉—包内球化的工艺路线获得了足够的优质铁液,然后通过选取合适的分型面、设置合理的浇注系统、设计专用的冷铁、安放足够大的保温冒口和上表面加大加工余量来去除夹渣等措施,成功生产了具有厚大断面的大型球墨铸铁铸件。     

摩擦诱发高铬铸铁相变的透射电镜研究

利用透射电子显微镜研究了高铬铸铁在摩擦过程中的显微组织变化。结果表明：奥氏体基体在摩擦应力的作用下发生相变。摩擦表面形成α‘Ｍ。次表层形成γ与α’Ｍ共存区；γ与．ε共存区；γ位错丛聚区。     

高炉炉缸内铁水环流与内衬侵蚀

从分析中心焦柱在炉缸内的受力出发，计算了１０００￣５５８０ｍ＾３高炉大喷煤前后中心焦柱在炉缸铁水内的沉入深度，分析了炉缸内铁水环流的产生与炉缸内衬侵的关系，分析表明大喷煤有得利抑制铁水环流对缸内补的冲刷，提出了降低铁水环流对炉缸内衬侵蚀的途径。     

铁矿石境外投资风险评估的模糊神经网络模型

论文将模糊理论与神经网络结合,对铁矿石境外投资所涉及的风险因素分别从资产影响、威胁频度两方面进行分析,建立了铁矿石境外投资的风险层次化结构,并构造了各因素所对应评判集的隶属度矩阵;综合运用模糊推理算法与神经网络仿真技术,对铁矿石境外投资的风险进行评估,进而判定铁矿石境外投资风险等级。最后,通过计算铁矿石境外投资的市场风险说明了算法的应用,并将结果与模糊综合评估得到的风险值进行比较,检测了模型的有效性。     

以1,3-二(4-邻羟基苯亚胺次甲基)苯氧基丙烷为载体的铁离子(Ⅲ)电极的研究

以1,3-二(4-邻羟基苯亚胺次甲基)苯氧基丙烷为中性载体制备了PVC膜Fe3+离子选择性电极。该电极对Fe3+呈现出良好的选择性和近Nernst电位响应性能。电极斜率为21mV/dec,线性范围为3.0×10-5～1.0×10-1mol/L,检出限为1.0×10-5mol/L。采用交流阻抗技术研究了电极的响应机理,并将电极作为指示电极初步用于EDTA的电位滴定。     

Magnetic and mössbauer studies on ductile Fe-Cr-Co permanent magnet alloys

Iron-chromium-cobalt alloys possess attractive magnetic properties combined with good formability and hence are identified as technologically important magnetic materials. Alloys with compositions Fe-28·9 Cr-15·6 Co and Fe-28·4 Cr-20·1Co (weight percent) have been studied. Heat-treatment parameters during thermomagnetic treatment viz temperature, time and external magnetic field were optimized with reference to magnetic properties. The fully treated anisotropic alloys develop remanence=11·5–12·0 kilo Gauss, coercivity=600–650 Oersted and energy product=4–4·5 million Gauss Oersted. Electron microscopic and Mössbauer spectroscopic techniques were used to identify the original and transformed phases. During the various stages of the development of the alloy, the changes in mechanical hardness were correlated with magnetic hardness.