光化学反应中的磁场效应 Ⅱ.电子转移光敏化1,2-二苯乙烯的顺反异构化反应

前文报道了外加磁场对吸附在硅胶表面上的芳砜光解反应的影响,本文报道外加磁场影响光化学反应的另一个例子——电子转移光敏化1,2-二苯乙烯的异构化。 近年来电子转移光敏化反应引起了有机光化学家们的极大注意。一些异构化、重排、裂解、氧化反应都可以通过电子转移机理敏化。电子转移光敏化的机理可以用(1)描述。图中A和D分别代表电子的受体和给体。     

普光气田邻井干扰压降研究

根据普光气田现场资料,分析普光气田关井压降恢复时间和稳定生产时间的关系。建立邻井干扰计算模型,评价邻井干扰压降值及邻井干扰,并对邻井干扰规律进行敏感性分析。     

目标追求的入世和出世对框架效应的影响

采用目标追求的入世、出世量表筛选出入世水平高组(70名)和低组(72)大学生,出世水平高组(68名)和低组(71名)大学生,探讨不同入世、出世水平大学生在奖学金申请、选修课和求职应聘三种决策任务领域上的框架效应及其在性别上的特点。结果发现:(1)不同出入世水平大学生在决策任务上的框架效应特点不同,入世水平高分组和低分组、出世水平高分组和低分组在奖学金申请问题上均出现了经典的框架效应;(2)在奖学金申请问题上,男性被试和女性被试的选择出现了明显的经典的框架效应。     

狭义相对论与钟慢效应关系再认识--纪念狭义相对论创立110周年

从爱因斯坦建立狭义相对论的科学方法与狭义相对论理论的逻辑构成入手,综合运用A· P·弗伦奇在国际著名的改革教材“美国麻州理工学院物理学导论丛书”第二卷《狭义相对论》中的研究观点和闵可夫斯基的四维时空理论,阐明狭义相对论与钟慢效应之间的正确关系。     

Interfacial Microstructure and Mechanical Properties of Al/Mg Butt Joints Made by MIG Welding Process with Zn-Cd Alloy as Interlayer

Butt joints between Mg alloy AZ31 B and pure Al 1 060 sheets were produced via metal inert gas welding process with Zn-Cd alloy foil. Crack-free Al/Mg butt joints between AZ31 B Mg alloy and pure Al 1060 sheets were obtained. Intermetallic compound layer 1 and layer 2 had formed in fusion zone/Mg alloy and the average thickness of the layer 1 was about 50 μm. The intermetallic compound layer 1 consisted of Al12Mg17 and Mg2Si phases while layer 2 consisted of Al12Mg17, Mg2Si and Mg Zn2 phases. The crack started from the IMC layer at the bottom of the joint and propagated along the brittle IMC layer, then expanded into weld metal during the SEM in situ tensile test. The highest tensile strength of the dissimilar metal butt joints could reach 46.8 MPa and the effect ofinterfacial IMC layer on mechanical property of the joint was discussed in detail in the present study.     

On the gas dynamics of HVOF thermal sprays

An experimental study of the gas-dynamic aspects of the high-velocity oxyfuel (HVOF) thermal spray process has been performed using commercially available HVOF equipment (Hobart-Tafa JP-5000, Ho-bart-Tafa Technologies, Inc., Concord, NH). Optical diagnostic techniques, including microsecond-expo-sure schlieren and shadowgraph imaging, were applied to visualize the hot supersonic jet produced by this equipment without particle injection. Rapid turbulent mixing of the jet with the surrounding atmos-phere was observed, which is an issue of concern in coating quality due to the possibility of oxidation of sprayed particles. This mixing appears to be a function of the ratio of densities of the hot jet and the cold atmosphere as well as a function of the velocity of the jet, rather than one of combustion-chamber pres-sure or barrel length. The supersonic core of the HVOF jet dissipates rapidly due to the mixing, so that the jet is no longer supersonic when it impinges on the target surface being sprayed. Secondary issues also observed in this study include strong jet-noise radiation from the HVOF plume and the entrainment and induced bulk motion of the surrounding air.     

Effects of laser beam energy and incident angle on the pulse laser welding of stainless steel thin sheet

This paper reports an experimental study of laser spot welding on stainless steel sheets. A pulsed Nd:YAG laser was used to weld the stainless steel specimen in the range of laser energy 0.6–1.2 J and incident angle 30–75° (the angle of the laser beam incident direction to the sheet surface). Metallography was applied to measure the cross-sectional size and shape of the welded spot. From the experimental results, it is found that as the laser energy increases, the penetration depth, bead length, and bead width of the welded spot increase. As the laser incident angle increases, the penetration depth and the bead width increase while the bead length decreases. The results illustrate that the shape and size of the welded spot depend not only on the laser energy, but also on the incident angle of laser beam.     

连续碳分CO2吸收率分析及探讨

本文简述了CO2 气体吸收率的测定原理 ,着重分析了影响连续碳分CO2 气体吸收率的因素 ,提出了提高连续碳分CO2 气体吸收率的途径     

TBC experience in land- based gas turbines

This paper summarizes prior and on-going machine evaluations of thermal barrier coatings (TBC) for power generation, that is large industrial gas turbine applications. Rainbow testing of TBCs on turbine nozzles, shrouds, and buckets are described along with a test of combustor liners. General Electric Power Generation has conducted more than IS machine tests on TBC turbine nozzles with various coatings. TBC performance has been quite good, and additional testing, including TBCs on shrouds and buckets, is continuing. Included is a brief comparison of TBC requirements for power generation and aircraft turbines.