Effects of reaction time and citric acid contents on the morphologies of BaCO3 via PVP-assisted method

BaCO₃ with different morphologies, such as dumbbell-like, pillar-like, peanut-like and ellipsoid-like have been successfully synthesized using citric acid (CA) as chelating ligand via a simple polyvinylpyrrolidone (PVP)-assisted method. The effects of the pH of the starting solutions, reaction time and the molar ratio of CA/Ba²⁺ on the morphologies of BaCO₃ were investigated. X-ray diffraction (XRD), transmission electron microscope (TEM) and the infrared (IR) spectrum of the sample are used to characterize the obtained products.     

The Synthesis of Energetic Compound on 4,4′‐((2,4,6‐trinitro‐1,3‐phenylene)bis(oxy)) bis(1,3‐dinitrobenzene)(ZXC‐5): Thermally Stable Explosive with Outstanding Properties

The novel, thermally stable explosive 4,4′‐((2,4,6‐trinitro‐1,3‐phenylene)bis(oxy))bis(1,3‐dinitrobenzene) (Be referred to as ZXC‐ 5 in our laboratory) has been reported. ZXC‐5 can be synthesized by a simple synthetic method (The total synthesis of ZXC‐ 5 requires only two steps and the total yield of ZXC‐ 5 is more than 89 %) and shows the superior detonation performances (detonation pressure, detonation velocity, sensitivity toward mechanical stimuli, and temperature of decomposition). The structure of ZXC‐5 was characterized by multinuclear (¹H, ¹³C) NMR and mass spectrometry. The structure in the crystalline state was confirmed by low‐temperature single‐crystal X‐ray diffraction. From the calculated standard molar enthalpy of formation and the measured densities, the detonation properties were predicted by using the EXPLO5 V6.01 thermochemical computer code. The sensitivity of ZXC‐ 5 towards impact, electrostatic discharge, and friction were also measured.     

陶瓷造纸刀片的研制

本研究以稀土复合添加剂对９５高铝瓷进行性能和陶瓷造纸刀片。结果表明：稀土复合添加剂可有效地提高致密度、硬度、强度、且降低烧成温度１００℃。     

HIPS复合板材挤出工艺探讨

详细介绍了ＨＩＰＳ复合板的挤出工艺和有关注意事项     

Influence of interfacial reaction layer on reliability of chip-scale package joint from using Sn-37Pb and Sn-8Zn-3Bi solder

The microstructure of Sn-37Pb and Sn-8Zn-3Bi solders and the full strength of these solders with an Au/Ni/Cu pad under isothermal aging conditions were investigated. The full strengths tended to decrease as the aging temperature and time increased, regardless of the properties of the solders. The Sn-8Zn-3Bi had higher full strength than Sn-37Pb. In the Sn-37Pb solder, Ni₃Sn₄ compounds and irregular-shaped Pb-rich phase were embedded in a β-Sn matrix. The Ni₃Sn₄ compounds were observed at the interface between the solder and pad. The microstructure of the as-reflowed Sn-8Zn-3Bi solder mainly consists of the β-Sn matrix scattered with Zn-rich phase. Zinc first reacted with Au and then was transformed to the AuZn compound. With aging, Ni₅Zn₂₁ compounds were formed at the Ni layer. Finally, a Ni₅Zn₂₁ phase, divided into three layers, was formed with column-shaped grains, and the thicknesses of the layers were changed.     

5,6-二氨基呋咱并[3,4-b]吡嗪-4,7-二氧化物（DAFPO）的合成、结构及性能

新型高能不敏感含能材料的合成对于武器装备能量水平和安全性的提升有重要意义。以5,6-二氨基呋咱并[3,4-b]吡嗪为原料,经氧化反应首次合成了5,6-二氨基呋咱并[3,4-b]吡嗪-4,7-二氧化物(DAFPO),用核磁共振(氢谱、碳谱、氮谱)、红外光谱和元素分析对其进行了表征。以乙酸乙酿为溶剂使用缓慢蒸发法获得了DAFPO-2H_2O的单晶,利用X-射线单晶衍射和Hirshfeld表面分析完成了结构解析和分子间相互作用研究。结果表明,DAFPO·2H_2O属正交晶系,Pna2_1空间群,296 K下晶体密度1.806 g·cm~(-3),分子间存在较强的O…H和N…H氢键作用。使用差示扫描量热法(DSC)和热失重法(TG/DTG)进行热分析,结果显示其热分解峰温为131.8℃。基于原子化反应利用Gaussian 09计算DAFPO的固相生成热为753.5 kJ·mol~(-1),由气体膨胀置换法测得其密度1.86 g·cm~(-3),使用EXPLO5预测其理论爆速和理论爆压分别为8836 m·s~(-1)和36.0 GPa,采用BAM标准方法测得其撞击感度大于40 J,摩擦感度大于360 N。性能研究结果表明,DAFPO是一种兼具较高能量水平和优良安全性能的新型不敏感含能材料。     

3D网状静电纺NC/GAP/nano-TATB纤维的表征及热化学性能（英）

采用静电纺丝法制备了具有三维网络结构的硝化纤维素/聚叠氮缩水甘油醚/三氨基三硝基苯(NC/GAP/nano-TATB)复合纤维。采用差示扫描量热法(DSC)和热红外法(TG-IR)对复合纤维的低温热化学性能进行了研究。结果显示,每条曲线上只有一个放热峰,,NC、GAP和nano-TATB同时分解,而非单独分解。NC/GAP/nano-TATB(208.1 kJ·mol^-1)的活化能(E_a)低于nano-TATB (228.9 kJ·mol^-1),NC/GAP/nano-TATB (1.70 s^-1)的速率常数(k)高于nano-TATB(0.92 s^-1)。复合纤维比纳米TATB更容易被活化,分解速度更快。NC/GAP/nano-TATB热分解的主要产物为CO₂、N₂O、NO、CO、NO₂、H₂O,同时检测到─CH─、─CH₂O、─C─O─C─片段。对比了复合纤维和NC/GAP和nano-TATB的能量和敏感性。NC/GAP/nano-TATB的燃烧室温度(T_c)高达1583℃,纳米TATB的加入有利于降低冲击敏感度。     

以“耦合、融合、结合”为特征的复合应用型人才培养模式研究——以工程造价专业为例

文章结合工程造价专业教学和应用实践,剖析了目前工程造价专业人才培养模式中存在的问题,借鉴国外工程造价专业人才培养成果,从耦合行业需求,整合相关知识、融入职业标准,工学结合、做学结合、课证结合三方面,对以"耦合、融合、结合"为特征的工程造价复合应用型人才培养模式进行系统研究,旨在为复合应用型工程造价专业人才的培养提供借鉴。     

复合行星轮系均载特性仿真研究

针对复合行星轮系均载特性的问题,以Ravigneaux式复合行星轮系统的典型结构为研究对象,基于ADAMS建立了系统的虚拟样机模型,通过对齿轮动态啮合力进行仿真分析,计算出了各啮合副的均载系数,分析了齿轮偏心误差、负载以及输入转速对于系统均载性能的影响。研究结果表明:增加偏心误差、提高转速会降低系统的均载性能;当行星轮偏心误差呈辐射状对称时,系统的均载性能会得到极大提高;太阳轮s1偏心误差对于系统均载性能的影响较s2偏心误差的影响更为明显;增加负载能提高系统的均载性能。     

基于改进谐波小波包分解的滚动轴承复合故障特征分离方法

为解决滚动轴承单通道振动信号中复合故障特征难以分离的问题,提出了基于改进谐波小波包分解的轴承复合故障特征分离方法。首先,改进了二进谐波小波包分解方法,提出了连续谐波小波包分解方法,克服了信号分解后子带个数和带宽范围受二进制划分的缺陷;然后,采用谐波窗分解提取信号中频率成分集中的频段,根据轴承各单点故障特征频率确定分解层数,进行连续谐波小波包分解,利用能量算子包络解调得到子带信号中各个单点故障的权重因子;最后,重构轴承各单点故障信号,实现复合故障的特征分离和提取。对仿真信号和实测轴承内、外圈复合故障信号分析的结果表明,该方法能将轴承单通道复合故障信号分解到不同的通道中,实现了复合故障特征的分离,具有一定的工程实用价值。