A new dynamic hydrogen reference electrode for applications in thin-film sensor systems

The realization and applicability of a new dynamic hydrogen reference electrode (DHRE) within an electrochemical microcell for sensor applications is reported. The electrodes are fabricated in thin-film technology and fixed within a flow-through device. An experimental setup for accurate electrochemical potential measurements is described. Smooth platinum, platinized platinum and pHEMA coated electrodes are investigated with regard to their initialization behavior, stability, reproducibility and interference with electrolytes. It is found that platinized platinum DHREs show excellent stability and reproducibility. For uncoated electrodes, the electrochemical potential is established within seconds. The potential is independent of the pH value within the range of pH 4–10. Interference with sulfate and phosphate is observed. Thus, the platinized platinum DHRE is well suited for bioanalytical sensor applications, where the pH value is buffered and the concentrations of the disturbing anions are constant or very low.     

基于信息融合技术的瓦斯传感器故障诊断研究

文章提出了将基于RBF网络的信息融合技术应用于瓦斯传感器故障诊断的思想。该思想的核心是通过对影响测点瓦斯浓度的各种相关信息融合,利用高精度RBF网络逼近器的输出与瓦斯传感器实际的输出之差与设定的阈值比较,实现瓦斯传感器故障的监测诊断。试验表明该技术能对瓦斯传感器进行有效的状态监测和故障诊断。     

自然主义——新艺术者的梦幻出口——浅析自然主义在设计史上盛极而衰的原因

自然主义对许多艺术门类都产生过深刻影响,在设计领域中,以自然主义为主要特点的新艺术运动曾在一个重大的设计变革时期——工业革命后风靡各国,然而却又在短短十多年后沉寂下来,本文主要分析自然主义为什么会在设计史的重要阶段产生如此特别的表现。     

煤气混合流量配比及热值串级模糊控制系统

文中将模糊控制技术运用到煤气混合串级调节系统中,介绍了系统的构成、原理及控制算法,有效地实现了混合煤气热值的检测和控制。     

Ion-cyclotron resonance study of elementary stages of the catalytic oxidation of CO by N2O in the presence of VIA-group metal ions

Gas phase reactions of Mo⁺ and W⁺ ions with the molecules of various oxidants (NO, O₂, N₂O, CH₂O, C₂H₄O) were studied using ion cyclotron resonance. In oxidation with N₂O the mono-, di- and trioxide metal cations are formed consecutively. The trioxide MO₃ ⁺ ions of both metals react with CO to form CO₂ and MO₂ ⁺ ions. In this way, catalytic reaction N₂O + CO N₂ + CO₂ occurs in the gas phase with MoO₃ ⁺ /MoO₂ ⁺ and WO₃ ⁺/WO₂ ⁺ couples as catalysts. The rate constants have been measured for both stages of the catalytic cycle as well as for the stages of the catalyst preparation. Metal-oxygen bond energies were estimated for MoO_x ⁺ and WO_x ⁺ species with various x. The mechanism of CO oxidation with MoO_x ⁺ and WO_x ⁺ cations as catalysts in the gas phase is discussed in comparison with that for the oxidation over classical solid oxide catalysts.     

PE,PP专家系统

简述了专家系统的发展及在塑料加工中的应用特点,介绍了成功地开发PE、PP专家系统的方法、技术及实现功能,并提出了采用压缩库大大节约存贮空间的新途径。     

凝析气藏相态参数实验研究

油气藏流体主要有烃类成分组成,在油藏及地面条件下,这种烃类混合物的物理性质取决于其化学成分及给定的温度和压力。对于烃类的相态特征及流体组分研究在油气田开发中具有重要的意义,尤其是凝析气藏田。对海榆和10井的研究,归纳总结其流体PVT性质,为其开发提供科学依据。     

基于模糊控制的微型燃机燃料压力控制

针对微型燃气轮机在控制时由于压力不恒定而导致的运行效率低的问题,将模糊PID控制思想运用到控制系统。在传统的PID控制下加入模糊控制,使其PID参数具有在线自整定功能。仿真结果表明,该方法能够很好地提高压力控制效果。     

甲烷部分氧化制合成气的研究进展

综述了近年来甲烷部分氧化制合成气的催化剂，反应机理及活性中心的研究进展及反应中存在的主要问题。