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111.
关于贝氏体形核和台阶机制的讨论--与徐祖耀院士等商榷   总被引:8,自引:6,他引:8  
一些合金固溶化(或淬水)后在预贝氏体(孕育)期内等温淬火(或时效),既保持高温时形成的晶体缺陷,又产生新的晶体缺陷。母相中由于溶质原子扩散而在缺陷处发生偏聚,则形成贫/富溶质微区,即类拐点(spinoclal—like)分解。当贫溶质微区成分作为Ms,其温度等于或高于等温淬火(或时效)温度时,贝氏体将以马氏体样切变形核,故贝氏体是在溶质原子扩散控制下切变形核。在TEM温台试验中未发现台阶生长机制,界面上巨型台阶是贝氏体增宽(厚)速度差异所致。  相似文献   
112.
The thermal behavior of Tb2(BA)6(PHEN)2 (BA: benzoate, and PHEN: 1,10-phenanthroline) in a static air atmospbere was investigated by TG-DTG, SEM and IR techniques. By the kinetic method of processing thermal analysis data put forward by Malek et al., it is defined that the kinetic model for the first-step thermal decomposition is SB(m, n). The activation energy E for this step reaction is 99.07 kJ/mol, the entropy of activation ΔS^≠ is -84.72 J/mol, the enthalpy of activation ΔH^≠ is 94.26 kJ/mol, the free energy of activation ΔG^≠ is 144.77 kJ/mol and the pre-exponential factor lnA is 20.93.The lifetime equation at mass-loss of 10% was deduced as lnτ = -29.0312 19760.83/T by isothermal thermogravimetric analysis.  相似文献   
113.
甲基偶氮四唑热稳定性和热分解机理的量子化学研究   总被引:2,自引:0,他引:2  
采用量子化学方法全优化计算了1—甲基—5—偶氮四唑(1—MAT)和2—甲基—5—偶氮四唑(2—MAT)热分解反应位能曲线,探讨了热稳定性和分解机理。热分解活化能计算值分别为245.9,183.2k/mo1,静态分子结构和动态分解性质都显示出1—MAT比2—MAT有更好的热稳定性。裂解优先以开环方式发生。  相似文献   
114.
The decomposition kinetics of poly(vinyl butyral) binder from barium titanate multilayer ceramic capacitors with platinum metal electrodes were analyzed by thermogravimetric analysis as a function of the heating rate. The activation energy and pre-exponential factor for the decomposition kinetics were determined from two types of integral equations, from the Redhead method, and from the variation in heating rate method. The accuracy of the kinetic parameters determined from these methods was then evaluated for describing the observed rate of binder decomposition. Although the individual models yielded very different kinetic parameters, all were capable of describing the experimental data within ±15% accuracy. The kinetic parameters were then used in a coupled transport and kinetic model for describing the buildup of pressure within the ceramic green body as a function of the heating cycle. A methodology based on calculus of variations was also developed to predict the minimum duration for the binder burnout cycle.  相似文献   
115.
Decomposition of SRC-II middle distillate under surface vaporizing conditions was studied as a function of temperature (heating rate), vapour phase residence time and oxygen level. The stressed and unstressed fuel was analysed by capillary gas chromatography. Decomposition was found to be greatest at low temperature. Boiling mode did not appear to affect the extent of decomposition. Decomposition was weakly related to chemical class and strongly related to component volatility. The effect of gas phase residence time and oxygen level were negligible at the conditions studied. It is concluded that decomposition occurs primarily within the liquid and at the vaporizer surface.  相似文献   
116.
The Mössbauer effect has been used to study the transformations of FeS2 in four different coals: IL No. 6, Ky 914, Blacksville No. 2, and Powhatan No. 5. The transformations of FeS2 in the coals were studied in an inert atmosphere. It was observed that the pyrrhotites formed from FeS2 have a considerable reduction in the isomer shift at 440 °C as compared to the values obtained in the absence of coal. This effect is associated with the interaction of the pyrrhotites with the coal constituents at high temperatures. There is also a significant line-broadening at 440 °C. This broadening is due either to vacancy motion in the iron sulphides and/or to motional broadening due to particle motion in the coal-derived liquids. The percentage conversion of pyrite to pyrrhotite depends markedly on time as well as type of coal. The weathering of the coal has a detrimental effect on the rate of conversion of pyrite to pyrrhotite. The ferrous sulphate layers covering the pyrite particles hinder the removal of sulphur from that surface. The major factor affecting the FeS ratio is the total amount of sulphur available for H2S formation. Partial H2S pressure is the crucial quantity controlling the stoichiometry of the pyrrhotites. Hence, a high percentage of H2S in the reactor at high temperature will assure the formation of pyrrhotites with a high number of metal vacancies.  相似文献   
117.
在空气中杀菌灯产生臭氧及其催化分解的研究   总被引:5,自引:0,他引:5  
用流动型反应装置,对8W杀菌灯(主波长λ=253.7nm)辐照空气时产生的臭氧进行了研究.发现在一定条件下当空气与杀菌灯接触大约7s时,就有超出0.33μg/L的臭氧产生.随着空气流速的减小,产生的臭氧的量随之变大.采用臭氧分解催化剂对臭氧的消除进行了研究,当体积空速小于1.1×105h-1时,臭氧可以降解到安全范围.  相似文献   
118.
Stakheev  A. Yu.  Gabrielsson  P.  Gekas  I.  Teleguina  N. S.  Bragina  G. O.  Tolkachev  N. N.  Baeva  G. N. 《Topics in Catalysis》2007,42(1-4):143-147
Pt/Al2O3 and Pt/BaO/Al2O3 catalysts (1 wt% Pt, 10 wt%BaO) were sulfated under conditions simulating a real NSR catalyst operation. Comparative TPR and XPS studies of sulfur removal from Pt/Al2O3 and Pt/BaO/Al2O3 catalysts indicate that the sulfur removal from Al2O3 surface precedes reductive decomposition of BaSO4 (250–400 °C). Barium sulfate decomposition started with further increase in desulfation temperature at the point of surface atomic ratio Ba:S = 1 (~450o). Simultaneously, an intensive formation of sulfide species on the catalyst surface was observed. Thermodynamic analysis of the desulfation process allows us to hypothesize that barium sulfide formation may hinder sulfur removal under reducing conditions.  相似文献   
119.
David Merrick 《Fuel》1983,62(5):567-570
A mathematical model to predict the strength of a coke manufactured from a blend of coals is proposed. The model operates in terms of ‘bond strengths’ between the constituents. The magnitudes of these bond strengths may be determined from the strengths of cokes manufactured from the individual constituents and from a limited number of binary blends. The model has been applied to predictions of the M10 index of coke strength for binary and ternary blends, and the predictions are in reasonable agreement with the experimental data. In particular, the model is able to account for the behaviour of incompatible coals and bridging coals in blends.  相似文献   
120.
谭淑珍  张罡  沈晃宏 《化工进展》2002,21(12):949-951
介绍了制取硫酸钾的一种新工艺--复分解四步循环法,即氯化钾与硫酸铵反应生成硫酸钾铵与氯化铵钾,硫酸钾铵再与氯化钾溶液反应生成硫酸钾,氯化铵钾再与硫酸铵溶液反应生成氯化铵。整个工艺全封闭循环生产,产品硫酸钾K2O质量分数≥50%,钾收率达92%。  相似文献   
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