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61.
62.
Zucong Cai 《Nutrient Cycling in Agroecosystems》2002,63(2-3):267-274
Coupled nitrification and denitrification is considered as one of the main pathways of nitrogen losses in paddy soils. The effect of NO3
– on NH4
+ transformation was investigated by using the 15N technique. The paddy soils were collected from Wuxi (soil pH 5.84) and Yingtan (soil pH 5.02), China. The soils were added with either urea (18.57 mol urea-N enriched with 60 atom% 15N excess) plus 2.14 mol KNO3-N (natural abundance) per gram soil (U+NO3) or urea alone (U). The KNO3 was added 6 days after urea addition. The incubation was carried out under flooded condition in either air or N2 gas headspace at 25°C. The results showed that in air headspace, 15NH4
+ oxidization was so fast that about 10% and 8% of added 15N in the treatment U could be oxidized during the incubation period of 73 hours after KNO3 addition in Wuxi and Yingtan soil, respectively. The addition of KNO3 significantly inhibited 15NH4
+ oxidation (p<0.01) in air headspace, while it stimulated 15NH4
+ oxidation in N2 gas headspace, although the oxidation was depressed by the N2 gas headspace itself. Therefore, the accumulation of NO3
– would inhibit further nitrification of NH4
+ at micro-aerobic sites in paddy soils, especially in paddy soils with a low denitrification rate. On the other hand, NO3
– would lead to oxidation of NH4
+in anaerobic bulk soils. 相似文献
63.
用固态配料和硝酸盐共沉淀配料制备了各组份为(Bi_(1.85)Pb_(0.40))Sr_(1.95)Ca_(2.05)Cu_(8.10)的超导材料,研究了两种不同制备工艺对Bi系超导相形成过程、超导电磁性能和显微结构的影响.实验发现,由共沉淀制备的样品T_(c(zero))稳定性好,T_(c(zero))均在107.5K以上.SEM观察表明:共沉淀法制备的样品中超导相颗粒比固态配料制备的要细小、均匀,颗粒间连结紧密,与T_(c(zero))结果相符.但XRD相分析结果显示:固态配料样品中高温相含量高于共沉淀配料,共沉淀配料制备作品中高、低温相同时存在,但其交流磁化率—温度曲线上仅在120K附近出现相应于高温相的抗磁信号.研究认为,这是由于共沉淀配料烧成时,高温相容易在部分液相参与下,在低温相表面通过反应成核生长,导致在形成的高温相内部包裹有残余低温相的“内芯”.依此包裹模型可自洽地解释X射线相分析与电、磁性能测定结果间的矛盾,讨论了Bi系高温相的形成机理,为选择合理的制备工艺提供了依据. 相似文献
64.
Biodiesel was produced by transesterification of soybean oil with methanol using ZnO loaded with KF as a solid base catalyst.
It was found that the catalyst with 15 wt.% KF loading and calcined at 873 K showed the optimum activity. XRD, IR and Hammett
indicator method were employed for the catalyst characterization. The results showed the activity of the catalysts was correlated
with their basicity. The influence of various reaction variables on the conversion was also discussed. 相似文献
65.
Lipase-catalyzed alcoholysis of soy phospholipids was investigated to simultaneously make lysophospholipids and fatty acid
esters of individual alcohols. Alcoholysis was carried out by stirring a mixture of soy phospholipids and individual alcohols
in equimolar proportions with 10% (by weight of reactants) Mucor miehei lipase at 55°C for 24 h. The products were isolated by column chromatography after removal of the lipase. Lysophospholipids
(in 69–78% molar yield) were obtained from soy phospholipids, and the yield of esters of various alcohols also conformed nearly
with theoretical yields. 相似文献
66.
67.
68.
Yinzhong Guo Vijay M. Mannari Pulin Patel John L. Massingill 《Journal of Coatings Technology and Research》2006,3(4):327-331
A series of soybean oil phosphate ester polyols (SOPEP) was prepared by reaction of fully epoxidized soybean oil with phosphoric
acid and simultanoeous hydrolysis in the presence of a polar solvent. The polyols were characterized by determination of acid
value, oxirane number, hydroxyl value, molecular weight (GPC), and FTIR spectra. These polyols with varying amounts of acid
phosphate groups could be self-emulsified to form aqueous dispersions after neutralization with organic base. These aqueous
dispersion showed varying degrees of stability and their appearance ranged from opaque dispersions to translucent to clear
solutions. Waterborne coating compositions were prepared using these aqueous dispersions as principal components and their
thermally cured film properties were studied. it was found that by careful selection and formulation, SOPEPs can be successfully
used for low-VOC waterborne coating formulations. SOPEPs with 3.5% phosphate ester content showed visibly superior corrosion
resistance properties. 相似文献
69.
营养条件对产烃葡萄藻生长的影响 总被引:15,自引:0,他引:15
在摇瓶培养中考察了无机碳源、氮源、磷源和NaF等营养成份对产烃葡萄藻(Botry℃℃cus braunii)生长的影响. 结果表明:与仅利用空气中的CO2作为碳源相比,以NaHCO3或CO2加富空气补碳,比生长速率从0.0535 d-1分别增大至0.0589和0.0949 d-1,代时从5.6 d分别缩短至5.1和3.2 d,最大放氧速率分别提高了2.3和5倍;在一定范围内增大KNO3起始浓度能提高葡萄藻的生长速率,延长对数生长期;磷源对葡萄藻生长的影响十分显著,在0~160 mg/L范围内,增大K2HPO4浓度,葡萄藻生长明显加快;适量NaF能促进葡萄藻的光合作用和呼吸作用,从而加快葡萄藻的生长,其最适浓度为0.84 mg/L. 相似文献
70.
D. L. Purcell B. T. McClure J. McDonald Hemendra N. Basu 《Journal of the American Oil Chemists' Society》1996,73(3):381-388
An evaluation of the exhaust emissions from a compression ignition engine for fuels composed of 100 and 30% methyl esters
of soy oil (SME) is described. These fuels were compared with a low-sulfur, petroleum #2 diesel fuel in a Caterpillar 3304,
prechamber, 75 kW diesel engine, operated over heavy- and light-duty transient test cycles developed by the United States
Bureau of Mines. More than 60 h of testing was performed on each fuel. The objective was to determine the influence of the
fuels upon diesel particulate matter (DPM) and gaseous emissions. The effect of a modern diesel oxidation catalyst (DOC) also
was determined in an effort to minimize emissions. Neat SME produced a higher volatile fraction of the DPM, but much less
carbon soot fraction, leading to overall DPM reductions of 23 to 30% for the light- and heavy-duty transients. The DOC further
reduced the volatile fraction and the total DPM. The SME fuel reduced gaseous emissions of CO by 23% and hydrocarbons by over
30% without increasing NOx. The DOC further reduced CO and hydrocarbon levels. Mutagenicity of the SME exhaust was low. Results indicate that SME fuel,
used with a proper DOC, may be a feasible emission reduction technology for underground mines.
References to specific products do not imply endorsement by the U.S. Bureau of Mines, a now defunct agency. 相似文献