Surface segregation studied by low-energy ion scattering: experiment and numerical simulation

The changes in surface composition of metallic alloys caused by segregation can be very efficiently studied by low-energy ion scattering (LEIS) due to the specific surface sensitivity of this technique. Investigations of single-crystal surfaces of ordered alloys are of particular interest because they provide the possibility to investigate the interplay between segregation effects and the order-disorder phase transition when passing through the transition temperature. Exemplifying these effects for bimetallic alloys we consider in particular the CuAu-system.For the quantitative interpretation of energy and angle resolved LEIS intensity distributions we compare experimental results with those from numerical simulations using the MARLOWE code which we extended with a detailed trajectory analysis. This allows us to apply various discrimination criteria, such as number of collisions, distance of closest approach, identification of the scattering crystal layer, total path length, etc. On this basis structural effects, ion survival probabilities and the influence of thermal vibrations can be studied.We demonstrate this potential by using CuAu(1 0 0) as a special example. The scattering potential parameters were calibrated with elemental single crystals of known structures and the anisotropic Debye temperatures taken from the literature showed good agreement, neutralization was of minor importance in this case. Our procedure could be successfully used for the quantitative analysis of the composition of the first and second layer as a function of temperature. These results are in good agreement with theoretical predictions.     

铸铁热分析用试样新型激冷剂的实验研究

从冷却曲线上相变段倾角最小原则出发，研究了新型激冷剂的配比与热分析法检测铸铁成分精度的关系，实验结果表明，能使相变段倾角最小的成分配比，也能提高对铸铁成分的热分析和检测精度。     

Instron texture profile of buffalo milk cheddar cheese as influenced by composition and ripening changes

Buffalo milk Cheddar cheese samples of different ages were analysed for compositional attributes (CA), ripening indices (RI) and Instron Textural Profile (ITP). All samples were compositionally alike, except for pH and salt-in-moisture (SM) contents. RI showed significant variations. CA and RI showed highly significant correlations within themselves and with each other, except for moisture with pH, SM with moisture, MNFS, Fat and FDM and Fat with MNFS. The ITPs of cheeses showed significant variations and had highly significant intercorrelations indicating their interdependence. CA (except moisture and MNFS) and RI showed a highly significant correlationship with ITPs. Moisture content showed a highly significant correlationship with all ITPs, except cohesiveness and springiness, where it was significant. MNFS content showed significant correlations only with hardness and brittleness. Stepwise regression analysis revealed that MI was the most predominant factor influencing cheese texture, followed by pH, SM, FDM and TVFA. Knowing Ca and RI, the textural properties of cheeses can be forecast through mathematical equations. Similarly the age of cheese can also be predicted if RI and/or textural properties are known.     

煤矿许用毫秒延期电雷管研究

文中对影响煤矿许用毫秒延期电雷管沼气安全性与延期时间精度的因素进行了研究。应用正交设计研制了新的延期药配方，确定了合理的雷管结构及装配工艺参数，产品性能达到ＧＢ８０３１《工业电雷管》的规定。     

唐山建龙900mm冷轧机组的工艺与设备

较系统地介绍了我国第1条国产化的中宽带钢冷连轧生产线，即唐山建龙钢铁控股有限公司900mm冷连轧生产线的工艺流程、主要设备组成及技术特点。重点介绍了900mm 4机架六辊轧机的技术参数、性能特点及自动控制系统。该生产线投产以来，取得了较好效果。     

化学成分和固溶温度对1Cr17Mn9Ni4N不锈钢组织和性能的影响

为提高1Crl7Mn9Ni4N钢固溶处理后的力学性能(特别是钢的强度)，研究了化学成分及固溶处理温度对其组织和性能的影响。结果表明，1000—1125℃固溶处理后，该钢的组织为单相奥氏体。在标准成分范围内，随着镍、锰含量的增加，该钢的强度降低，塑性有所改善。氮明显提高该钢的强度。根据试验结果，每增加0．01％的氮钢的室温强度可提高大约5MPa，且塑性基本上不受影响。当合金成分(质量分数，％)控制在C0．08—0．12、Crl6．5—17．5、Ni3．5—4．2、Mn8．0—9．0、N0．22—0．28时，1Crl7Mn9Ni4N钢经1050—1100℃固溶处理后强度较高、塑性好，室温强度σ0．2和σb可分别达到400MPa和800MPa。     

唐钢ER70S-6焊丝钢的生产工艺研究及质量分析

介绍了唐钢ER70S-6焊丝钢的特点，对盘条质量进行了分析。对该钢化学成分、冶炼和轧制工艺进行了优化研究，使其综合性能明显改善。     

钨系延期药预点火反应机理研究

通过程控升温模拟点火条件，根据ＤＳＣ图谱分析，找出主要反应区的温度范围。研究结果表明，钨系延期药预点火反应是一个真正的固－固反应。     

Temperature and pressure effects on supercritical CO2 extraction of tomato seed oil

Tomato seed oil was extracted with supercritical carbon dioxide in a semibatch-flow extractor within the temperature range 313–343 K and the pressure range 10.8–24.5MPa. The extraction rates increased with pressure, but decreased with temperature increase because of the variation in solvent density and resultant differences in oil solubility. The fatty acid composition of the extracted oil was similar to that of soybean oil.     

焦化防砂室内实验研究

油井防砂工艺技术的研究与发展对疏松砂岩油藏的正常开采至关重要.焦化防砂是通过向地层内注入热空气使原油在高温下发生氧化裂解生成焦炭从而将地层砂固结的一种防砂新技术.为了对该项技术进行全面系统的理论分析与评价,设计并制作了一套焦化防砂实验装置,利用该装置进行了焦化防砂室内实验研究.焦化效果以岩样的抗压强度进行评价,实验结果表明,影响焦化后岩样抗压强度的主要因素为空气最高温度、处理时间和空气流量.此外,对焦化处理后的岩样所作的岩样组成分析揭示出,稠油胶结机理为氧化作用使部分油分和胶质变成沥青质,沥青质受到高度的缩合作用而成为高分子量的甲苯不溶物.由于新生胶质的氧化比原生胶质的氧化困难得多,因此适合焦化防砂的油层,其原油必须含有一定量的原生胶质和沥青质.