Coinage Metals in the Nanometer Length Scale

Cetylpyridinium chloride (CPC)-stabilized gold organosol in toluene has been prepared by using a two-phase (water-toluene) extraction of AuCl₄^- followed by its reduction with sodium borohydride in the presence of the surfactant, CPC. The surfactant-stabilized gold nanoparticles were exploited to examine their optical properties when exposed to various solvent systems by measuring the changes in the localized surface plasmon resonance (LSPR) spectrum.     

Photoinduced phenomena in nanostructured porous silicon

In this work we study the evolution of porous silicon photoluminescence under illumination. Samples were obtained by electrochemical etching of crystalline silicon wafers of different types. For the p-type samples the evolution of the spectra is explained in terms of photoinduced oxidation of nanostructures, which in turns leads to a discrete change in the photoluminescence spectra, as we reported in previous works. For the n-type material, a progressive decrease of the luminescence intensity is observed, which is attributed to the photoinduced generation of dangling bond related defect states at the surface layer surrounding the nanostructures. This model explains qualitatively well the kinetics of the evolution of the measured photoluminescence. Preliminary results of electronic paramagnetic resonance spectroscopy agree with this model.     

应用模态级数方法分析电力系统模态谐振

本文推出了一种分析电力系统模态谐振的方法———模态级数(modalseries)方法。用该方法求取2阶解析解不用解高维非线性代数方程,而且把谐振情况和非谐振情况的公式融为一体,推导容易,计算简单。在2阶解析解的基础上推导出了系统谐振时非线性相关因子的表达式。用该方法分析了简单电力系统中出现的模态谐振情况,获得了良好的效果,由此验证了本文所提出方法及谐振时2阶非线性相关因子的正确性。     

同型多机电力系统间扭振相互作用的等效简化研究

提出了一种用于分析并列运行的同型多机系统次同步谐振(SSR)稳定性的等效简化方法。该方法基于相似矩阵具有相同特征值的原理，通过构造合适的变换矩阵，将同型N机系统的系统矩阵变换为具有N个子块的分块对角阵，其中N-1个子块完全相同，从而使N机系统的SSR问题可以简化为具有两类结构的N台单机系统来研究，并给出了这两类单机系统的建模方法。采用该等效法可以有效地降低系统维数，且保留了全部的系统特征值信息。理论推导和算例结果都显示了该等效法的正确性和实用性。     

大气压直流双阳极等离子弧脉动特性研究

等离子弧的脉动特性是表征等离子体物理状态和过程的重要参数之一,等离子体射流的非稳定性和阳极斑点在电极上的运动是引起等离子弧脉动的主要原因,是等离子体技术的实际应用和进一步发展的关键。该文介绍了一种大气压直流双阳极等离子发生器,通过对等离子弧电信号进行时域和频域分析,研究了载气成分、载气流量和弧电流等参数的变化对等离子弧脉动特性的影响,结果表明在文中的实验条件下等离子弧的伏安特性呈上升趋势,纯氩气作为载气时等离子弧的脉动特性主要和电源的交流分量有关,氩氮混合气体作为载气时等离子弧的脉动特性除了和电源的交流分量有关,还和弧室内存在的赫姆霍茨共振有关,其共振频率独立于气体流量和弧电流的变化。     

不同控制策略下并联混合型滤波器对系统谐振抑制特性的研究

并联混合型滤波器作为一种谐波抑制和无功补偿装置，结合了无源滤波器成本低、结构简单和有源滤波器控制灵活、可动态补偿等优点，成为近年来研究与应用的热点。并联混合型滤波器中，根据有源滤波器电流检测点的不同，其控制方法也不尽相同。本文分析了有源滤波器在不同电流检测点情况下系统的电路模型，在此基础上分析了不同控制方法下，有源滤波器对抑制电网和无源滤波器之间谐振的作用，并通过仿真进行了验证。     

Preparation of a sensor substrate using functionalized mesoporous silica on a gold film for surface plasmon resonance (SPR) spectroscopy

The use of surface plasmon resonance (SPR) spectroscopy has been applied to a wide variety of fields such as biosensors and surface analysis instruments. In general, a SPR substrate is prepared using self-assembled monolayer (SAM) method of organic molecules as receptor for the target on a layer of gold or silver. However, mesoporous inorganic materials such as SBA-15 have benefits as sensor substrate for SPR. Mesoporous silica has a large surface area which receptor molecule can be attached and has a rigid body which has an excellent stability in the extreme condition compared to organic sensing layer. We prepared an organic modified mesoporous silica and successfully immobilized it on a gold surface, in an attempt to use as a substrate for SPR spectroscopy. For the comparison of sensitivity of prepared substrate, Pt²⁺ detection was selected as a model system. Substrate prepared in this study exhibited the capability of selective sensing for Pt²⁺ ions.     

调频串联谐振装置在XLPE绝缘电缆试验中的应用

介绍一种调频串联谐振装置的原理及工作过程,并在高压交联聚乙烯(XLPE)绝缘电缆交流耐压试验中应用.     

创新型的基于软开关的X射线电源系统

自动X射线检测(AXI)已经成为检测和评估复杂微机电系统(MEMS)和微光电子机械系统(MOEMS)的基本方法,在医疗、考古等领域也有了广泛应用,而稳定可靠高效的直流高压电源是AXI的核心组件。一般的高压直流电源为定值输出,它们在X射线管这样的宽负载变化范围下的稳态和暂态响应不能满足AXI的要求。基于AXI的需要,本文介绍了一种最新研制的可调高压电源,创新型的主电路拓扑结构由PFC(功率因数校正)模块、Buck模块、逆变电路、高频变压器和倍压电路组成。电源利用变压器的寄生参数谐振工作,利用软形状技术实现了ZCS低损耗。PFC模块能使此电源系统适用于国内外市场并且可减小对电网的谐波污染。电源的控制电路采用基于DSP的PI调解器,并基于RS232实现与PC的通信,从而实现本地控制和远程管理。     

基于IR2104的金属卤化物灯调频驱动电子镇流器的研制

简述了金属卤化物高强度气体放电灯的特点,提出了一种基于IR2104半桥控制芯片的高性能电子镇流器的设计方案,通过改变电子镇流器的驱动频率-频率调制技术,有效地解决了金属卤化物灯的声谐振的现象,最后给出了70W金卤灯的原理图和实验结果。