低温吸附法脱除一氧化碳中甲烷的实验研究

在液氮温度下,采用吸附剂CNA X进行低温脱甲烷动态吸附实验,结果表明CNA X在液氮温度下可以将一氧化碳中0 1%左右的甲烷脱除到10×10-6。     

压力计探测液面法探讨

针对油田地质特征复杂，易结蜡，测试中易出现假液面等情况，为准确快速测得液面资料，提出压力计测试液面法。该方法可作为回声仪测液面方法的有效补充。     

液晶电控效应的实验研究

详细阐述了液晶的电光效应,介绍了利用分光光度计测量液晶透射比的方法。通过改变加在液晶盒上的电压大小及其频率高低,详细测量了液晶的透射比。通过做图分析了液晶的电控双折射效应,得出液晶的透射比随所加电压的大小和频率的高低而变化,以及液晶的阈值电压随频率的增高而减小的规律,这对液晶器件的设计与研究均具有一定的参考价值。     

掺杂铁电纳米粉的液晶的电光特性

铁电纳米粒子悬浮在向列相液晶母体中，增强介电各向异性，而且对施加的电场信号敏感。本文也展示了纳米粒子对所述复合材料可实现的总的相变的作用。这种方法也许可应用于设计新型显示材料。     

电控平行排列液晶光栅的光衍射特性研究

对电控平行液晶光栅的理论进行了分析,并配以结构原理图。通过对平行排列及90°扭曲排列液晶指向矢的计算,得出液晶盒中相应的折射率、相位差与电压之间的关系图,两者经比较证明平行排列更具适用性,并在实验中观测到了平行排列液晶光栅衍射特性与电压的关系。     

棒状液晶分子相变问题的机械旋转模型研究

综述一种关于棒状液晶材料的分子结构与液晶相的相关关系的研究成果。介绍了有关液晶分子的机械旋转模型。该模型将液晶分子视作一种高速旋转的转子,通过分子参数计算,对液晶材料的相变温度和分子结构之间的关系给出了一种全新的解释。最新研究表明,含氟三苯液晶材料的分子结构中存在slim和fat现象,能够对液晶材料的相变进行合理解释。该模型能够通过简单的模型方法对新型液晶材料的分子设计与合成提供有用的信息。     

An analysis of the electrical conductivity in BaSO4-added Ag2SO4 solid electrolyte system

The compositions (1 −x)Ag₂SO₄−(x)BaSO₄, wherex=0·01 to 0·6, were prepared by slow cooling of the melt. The extent of the solid solubility of Ba²⁺ in Ag₂SO₄ was determined by X-ray powder diffraction and scanning electron microscopy. The bulk conductivity of each sample was obtained using a detailed impedance analysis. The partial substitution of Ba²⁺ results in the enhancement of conductivity in compliance with the classical aliovalent doping theory. A simplistic model based on lattice distortion (expansion) due to partial substitution of Ag⁺ by the bigger Ba²⁺ has been considered to explain enhanced conductivity. Beyond solid-solubility limit (5·27 mole%) the BaSO₄-dispersed Ag₂SO₄ conductivity follows the usual trend seen in binary systems. An increase in conductivity in this case is discussed in the light of interfacial reactions and surface defect chemistry. The maximum conductivity in 20 mole% BaSO₄ dispersed Ag₂SO₄ is due to percolation threshold.     

Transport of chromium(VI) through a Cyanex 921‐supported liquid membrane from HCl solutions

The transport of chromium(VI) through a flat‐sheet supported liquid membrane containing Cyanex 921 as a carrier has been investigated. The permeation of the metal is investigated as a function of various experimental variables: hydrodynamic conditions, concentration of chromium(VI) and HCl in the feed phase, carrier concentration and diluent in the membrane and strippant concentration in the stripping phase. The mass transfer coefficient and the thickness of the aqueous boundary layer were calculated from the experimental data. Furthermore, the selectivity of Cyanex 921‐based flat‐sheet supported liquid membrane towards different metal ions and the behaviour of the system against other carriers are presented. Copyright © 2003 Society of Chemical Industry     

Micellar polymerisation of ionic surfactants studied by conductimetry

The micellar polymerisation of ionic surfactants such as allyldodecyl-dimethylammonium bromide and 3-dodecyl-1-vinyl imidazolium iodide has been studied by conductimetry in aqueous solution. The polymerisation was carried out using two different sources of γ rays directed into solutions of surfactant above the critical micellar concentration. Conductimetry is shown to be a very good physicochemical method for analysis of these solutions. The results showed different behaviour for the two surfactants, which has highlighted a change in the structure of their aggregates which led to the assumption of an interaction between the polymers of high mass and different products of the polymerisation (oligomers, products of degradation, monomers etc.). Ultrafiltration experiments coupled with ¹H-NMR and conductivity analysis confirm these assumptions.     

含氚废水水泥固化实验研究

研究用水泥固化处理氚废水,并选择了最佳配方:水与灰的重量比=0.45～0.5,水泥与石膏重量比=5∶1。用IAEA推荐的方法做浸出实验。为了减少水泥固化体中氚的浸出量,实验了几种涂层材料。沥青涂层可将固化体氚的浸出率降低1～2个量级。