High molecular weight polypropylene nanospheres: Synthesis and characterization

The high molecular weight (MW) polypropylene with average particle size of 60 nm was synthesized by controlled growth mechanism using Ziegler–Natta catalyst. The atomic force microscopy (AFM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) studies showed that PP nanoparticles were spherical in shape. Structure and crystallinity were concomitantly studied through Fourier transform infrared spectroscopy and X‐ray diffraction, respectively. It shows nanospherical PP particles with more crystallinity (～ 75%) compared with macrosized PP (～ 59%). In addition, differential scanning calorimetry studies revealed the finite particle size effect on T_g and the scale dependence T_g followed a first order exponential trend. As particle size goes down to nano‐ scale from macrosize, continuous elevation of T_g's were observed from ?25 to ?11°C. This phenomenon was directed to configuration entropy of single spherical nanoparticles of PP. The mechanical properties and surface roughness were also evaluated through AFM. At last, the properties of nanosized PP were compared with micron and macrosized particles. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

超高分子质量聚乙烯纤维黏结强度增强方法研究

为提高超高分子质量聚乙烯(UHMWPE)纤维复合材料中纤维与树脂基体之间的界面黏结强度,提出通过不同质量分数的硅烷偶联剂KH-570处理纳米SiO_2对UHMWPE纤维进行表面改性。对改性处理后的纤维与乙烯基酯树脂进行黏结强度试验,发现硅烷偶联剂处理纳米SiO_2能有效提高纤维的界面黏结强度,同时使纤维保持一定的断裂强度。     

阻垢缓蚀剂对不锈钢管缓蚀效果的评定方法

用点蚀电位法和失重法评价了七种阻垢缓蚀剂在不同冷却水样中对不锈钢的缓蚀效果。用腐蚀失重法评价阻垢缓蚀剂对不锈钢的缓蚀效果，既不合理也很难测准。点蚀电位法是评价阻垢缓蚀剂对不锈钢缓蚀效果的有效方法，但要选择合适的空白水样。     

The Estimation of the Molecular Weight of Polytetrafluoroethylene Based on the Heat of Crystallisation. A Comment on Suwa's Equation

Summary: The influence of number‐average molecular weight ranging from 1.4 · 10⁴ to 1.2 · 10⁶ g/mol on the thermal behaviour of polytetrafluoroethylene (PTFE) has been studied. Samples have been prepared by radiation‐induced degradation of commercial PTFE. The molecular weight has been calculated using end‐group concentration determined by infrared (IR) spectroscopy and ¹⁹F solid‐state nuclear magnetic resonance (NMR) spectroscopy. Melting and crystallisation heats were investigated by differential scanning calorimetry (DSC). The results have been discussed with respect to quantitative relationships between number‐average molecular weight and heat of crystallisation of PTFE described in the literature. The molecular weight calculated from Suwa's equation, which is often used in the literature, has been found to be too low.

Concentration of end‐groups and the molecular weight of PTFE versus the irradiation dose.     

高固体分丙烯酸树脂相对分子质量的研究

采用溶液聚合法合成高固体分丙烯酸树脂,用凝胶渗透色谱(GPC)法分析引发剂的种类和用量、反应温度及聚合工艺对丙烯酸树脂的相对分子质量及其分布的影响。结果表明,选用偶氮二异丁腈和过氧化苯甲酰两种引发剂进行复配可提高聚合物的相对分子质量;采用“饥饿态”聚合工艺进行聚合反应可有效控制聚合物的相对分子质量,且相对分子质量分布均匀,分散度小于2;当引发剂用量为2%,在110℃的反应条件下制得的丙烯酸树脂的综合性能优异,固含量超过70%,相对分子质量可达4万。     

基于Monte Carlo随机模拟的综合交通网络布局评价与决策方法

针对综合交通网络评价指标权重及属性值具有主观性和随机性的特点,提出了基于模拟运算的布局规划方案排序选优的群体随机决策方法.仿真生成满足集结的多个专家对指标重要性偏好排序统计分布的权重,同时考虑交通需求的不确定性对指标值的影响,结合客观熵权计算方案的综合评价值,由多次模拟得到的排序优势度确定方案的优劣差异.根据设计的仿真流程通过算例说明了方法应用的有效性,评价中考虑了主客观因素及随机性特征,可以为网络布局提供科学决策依据.     

Harnessing the Melting Peculiarities of Ultra‐High Molecular Weight Polyethylene Fibers for the Processing of Compacted Fiber Composites

Summary: Compacted fiber composites offer unique properties due to their lack of an extraneous matrix. The conditions of processing ultra‐high molecular weight polyethylene (UHMWPE) fibers were simulated in a heated pressure cell. In situ X‐ray diffraction measurements were used to follow the relevant transitions and the changes in the degree of crystallinity during melting and crystallization. The results strongly support the suggestion that the hexagonal crystal phase, in which the chain conformation is extremely mobile on the segmental level, constitutes the physical basis of compaction technologies for processing UHMWPE fibers into a single‐polymer composite. This report suggests that using a pseudo‐phase diagram outlining the occurrence of different phases during slow heating and the degree of crystallinity can provide valuable insight into the technological parameters relevant for optimal processing conditions.

Degree of crystallinity as a function of pressure and temperature in a region relevant to compaction processes.     

结合双粒子群和K-means的混合文本聚类算法

传统K-means算法对初始聚类中心选择较敏感, 结果有可能收敛于一般次优解, 为些提出一种结合双粒子群和K-means的混合文本聚类算法。设计了自调整惯性权值策略, 根据最优适应度值的变化率动态调整惯性权值。两子群分别采用基于不同惯性权值策略的粒子群算法进化, 子代间及子代与父代信息交流, 共享最优粒子, 替换最劣粒子, 完成进化, 该算法命名为双粒子群算法。将能平衡全局与局部搜索能力的双粒子群算法与高效的K-means算法结合, 每个粒子是一组聚类中心, 类内离散度之和的倒数是适应度函数, 用K-means算法优化新生粒子, 即为结合双粒子群和K-means的混合文本聚类算法。实验结果表明, 该算法相对于K-means、PSO等文本聚类算法具有更强鲁棒性, 聚类效果也有明显的改善。     

考虑出行方向的广州出租车时空可达性研究

出行方向是可达性研究中的一个关键要素, 因此, 提出一种考虑出行方向的出租车时空可达性分析方法。根据出租车经验路径分方向构建经验等级路网, 采用基于分层路网的Dijkstra算法计算得到各OD对之间的行程时间, 作为可达性评价指标, 并采用网格法和反距离加权插值法绘制得到广州市中心商业区等时线及其渲染图, 分方向、分时段对其时空可达性进行分析。结果证明了不同出行方向下, 特别是处于高峰时段, 可达性有较大的不同。     

基于空间加权互信息的非刚性医学图像配准

互信息作为相似性测度标准在医学图像配准领域应用广泛,尤其是在刚性配准研究中,能实现较高配准精度和非常稳健的配准效果。然而由于非线性形变的复杂性,在非刚性配准领域,对基于互信息的配准方法进行深入研究势在必行。提出的方案采用基于B样条的自由变换模型模拟医学图像中解剖结构的非线性形变,同时根据变换模型,考虑空间信息对配准效果的影响,以空间加权的方式对互信息方法进行改进。使用对大规模参数优化效果较好的LBFGS方法对配准参数进行优化,编程实现程序,并通过实验对效果进行验证和分析。实验结果显示,该方案配准精度明显优于传统的互信息方法。