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Although structural adhesives are becoming widespread in numerous applications, one important limitation at present is the long term behaviour of bonded assemblies under conditions of high humidity, especially at elevated temperatures. This study presents a comparison between bulk properties of a structural epoxy resin and its behaviour in a torsional joint consisting of a hollowed-out cylinder bonded to a plate—both substrates being in stainless steel. Exposure to ca. 100% relative humidity at 70°C leads to modification of the bulk properties of the polymer, notably reduction of its elastic modulus. Although this may explain some differences in behaviour of the torsional joint, premature failure is attributed to weaknesses in the interphase zone.
Auger Electron Spectroscopy (AES) has been employed to investigate both unbonded steel surfaces and fracture zones. Although prolonged exposure to water leads to a more extensive degree of (apparently) adhesive failure at the interface polymer/metal, AES has shown the presence of non-negligible quantities of carbon, attributed to residual polymer. Failure would seem to occur, at least partly, in a weak interphase of the polymer, near, but not at, the interface.
Various possible causes are evoked. For dry failure, residual polymer may be due to the topography of the metal surface and/or local modification of the adhesive during cure. In the case of aged joints, in addition there are potential effects due to swelling and differential stresses, secondary bond failure and molecular chain scission within the polymer, all provoked by the presence of water. 相似文献
Auger Electron Spectroscopy (AES) has been employed to investigate both unbonded steel surfaces and fracture zones. Although prolonged exposure to water leads to a more extensive degree of (apparently) adhesive failure at the interface polymer/metal, AES has shown the presence of non-negligible quantities of carbon, attributed to residual polymer. Failure would seem to occur, at least partly, in a weak interphase of the polymer, near, but not at, the interface.
Various possible causes are evoked. For dry failure, residual polymer may be due to the topography of the metal surface and/or local modification of the adhesive during cure. In the case of aged joints, in addition there are potential effects due to swelling and differential stresses, secondary bond failure and molecular chain scission within the polymer, all provoked by the presence of water. 相似文献
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Based on controls of structural style and the position in coalbed methane(CBM)development,we used a method of curvatures to study its relations with CBM development parameters.We calculated structural curvatures of contours of the No.3coal seam floor of the Shanxi Formation in the Zaoyuan block of the Qinshui Basin and analyzed its relations with development parameters of coalbed methane wells.The results show that structural curvature is negatively related to coal reservoir pressure,while positively related to permeability.With an increase in structural curvature,the average production of coalbed methane wells increases at first and then decreases,reaching the highest production at 0.02 m-1 of structural curvature.Therefore,structural curvature can be an important index for potential evaluation of coalbed methane development and provide a basis for siting coalbed methane wells. 相似文献
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In order to determine the area for oil and gas exploration in China's north Sichuan basin, we have divided the time during which the Longmenshan foreland basin was formed into five periods, based on the sedimentary response relationship of the fore-land basin to structural evolution: 1) a late Triassic Noric period; 2) an early-Middle Jurassic period; 3) a late Jurassic to early Cre-taceous period; 4) a late Cretaceous to Paleogene-Neogene period and 5) the Quaternary period. As well, we analyzed the sedimen-tary environment and lithologic features of every basin-forming period. The results show that there are several favorable source-reservoir-cap assemblages in our study area, making it a major region for future oil and gas exploration in China's northern Sichuan basin. 相似文献
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丹皮酚结构改造研究进展 总被引:3,自引:0,他引:3
丹皮酚是传统中药牡丹皮的有效成分,具有广泛的生物活性,如抗菌消炎、镇痛、抗肿瘤和预防心血管系统疾病等.近年来,随着对丹皮酚作用及机制研究的不断拓展和深入,对其结构修饰和改造也开展了大量的工作,合成出一系列的丹皮酚衍生物,对丹皮酚结构改造的研究现状进行了系统的综述. 相似文献
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田配琴 《湖南城建高等专科学校学报》2014,(2):10-14
长距离大断面顶管施工不可避免的引起土体扰动和土层损失,导致土体塌陷和地表拉裂等现象.以某长距离超大断面顶管工程为工程研究背景,对顶管施工引起土体变形的机理展开了分析,对顶进施工过程中土体产生塌陷、地表出现张拉裂缝的原因进行了阐释,探讨了地表变位对周边建筑(构筑)物的影响,以及分析了该工程中运用的进出洞、中继器、触变泥浆减阻、加强现场监测、以及其他应急措施这5种关键控制技术,得到了一些保证工程施工安全的有益的经验. 相似文献
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Continuity versus Discretization 总被引:1,自引:1,他引:0
The threefold interest in architecture, biology and mathematics motivated us to examine and justify new architectural forms.
We discuss some notions of rhythm: Euclidean, morphogenetic and morphologic. Contemporary relationships between structure
and form are based on the generation of shape by technological processes, thus the resulting objects are restricted to their
material expression. Here a phenomenological organisation of form and its continuity with the landscape arise out of the mathematical
and architectural creativity. The use of the computer is applied from outside to inside instead from inside to outside; this
means that we are dealing with the organisational processes via continuous methods instead of evolutionary processes given
by computer simulations, known as genetic algorithms, where the resulting configurations are reduced to a matter of routine. The role of design as an aesthetic component innovates
the theoretical framework of structural engineering to establish the architectural environments. 相似文献
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