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21.
《Intermetallics》2015
The non-equiatomic FeCoNiAlSi alloy is prepared by the Bridgman solidification (BS) technique at different withdrawal velocities (V = 30, 100, and 200 μm/s). Various characterization techniques have been used to study the microstructure and crystal orientation. The morphological evolutions accompanying the crystal growth of the alloy prepared at different withdrawal velocities are nearly the same, from equiaxed grains to columnar crystals. The transition of coercivity is closely related to the local microstructure, while the saturation magnetization changes little at different sites. The coercivity can be significantly reduced from the equiaxed grain area to the columnar crystal area when the applied magnetic field direction is parallel to the crystal growth direction, no matter what is the withdrawal velocity. In addition, the alloy possesses magnetic anisotropy when the applied magnetic field is in different directions. 相似文献
22.
Using a comprehensive set of drop weight impact test data (h50) newly compiled from literature for 308 materials, a recent approach to predict impact sensitivities of nitro compounds is generalized to most explosive substances of interest. Compared to previous ones, this procedure is more thoroughly validated and exhibits a good predictive value. Furthermore, it yields new insight into the physical mechanisms involved, explaining for instance the unexpected desensitization of some oxygen-deficient triazoles upon nitration. 相似文献
23.
《Calphad》2015
This paper presents an overview and examples of material design and development using (1) classical thermodynamics; (2) CALPHAD (calculation of phase diagrams) modeling; and (3) Integrated Computational Materials Engineering (ICME) approaches. Although the examples are given in lightweight aluminum and magnesium alloys for structural applications, the fundamental methodology and modeling principles are applicable to all materials and engineering applications. The examples in this paper have demonstrated the effectiveness and limitations of classical thermodynamics in solving specific problems (such as nucleation during solidification and solid-state precipitation in aluminum alloys). Computational thermodynamics and CALPHAD modeling, when combined with critical experimental validation, have been used to guide the selection and design of new magnesium alloys for elevated-temperature applications. The future of material design and development will be based on a holistic ICME approach. However, key challenges exist in many aspects of ICME framework, such as the lack of diffusion/mobility databases for many materials systems, limitation of current microstructural modeling capability and integration tools for simulation codes of different length scales. 相似文献
24.
Xueli Du Yuelong Wang Rongna Shi Zhiyong Mao Zhihao Yuan 《Journal of the European Ceramic Society》2018,38(10):3512-3517
The PbClxS1-x and Pb1-xBixS (x? =?0–0.05) bulks were fabricated with a facile method of hydrothermal synthesis and microwave sintering, and the effect of anionic and cationic donors on the thermoelectric performance of PbS was investigated. Although Cl? and Bi3+ both effectively improved the thermoelectric properties of n-type PbS, more excellent thermoelectric performance was obtained from Cl? doped samples because of higher electrical property and lower thermal conductivity at higher temperature (T? >?600?K). The thermoelectric figure of merit (ZT) reaches 1.04 for PbCl0.015S0.985 at 800?K and increases with temperature increasing without sign of saturation, which is probably the highest value ever reported for single-phase polycrystalline n-type PbS. The results also indicate that the hydrothermal synthesis and microwave sintering can realize anion doping as well as cation doping for n-type PbS at low cost, and PbS should be a robust alternative for PbTe thermoelectric materials. 相似文献
25.
为了提升大断面球墨铸铁综合力学性能,通过复合添加微量合金元素铜、锑、锡、钼对大断面球墨铸铁进行微合金化处理,借助金相显微镜(OM)、扫描电子显微镜(SEM)及力学性能测试等手段,研究了Cu Sb Sn Mo复合微合金化大断面球墨铸铁微观组织和力学性能。结果表明,试验球墨铸铁具有良好的综合力学性能。大断面球墨铸铁中添加铜、锑、锡、钼后优化了材料的组织结构,基体组织为珠光体+少量牛眼状铁素体;试样石墨组织细小、圆整,分布均匀。同时,合金元素的复合加入使得其抗拉强度达到800 MPa以上,硬度约为280HB,伸长率达到5%以上。拉伸断口分析表明,微合金化大断面球墨铸铁断裂模式以解理断裂为主,伴有少量的塑性变形。 相似文献
26.
《Calphad》2021
A general flux equation for multicomponent diffusion in oxide melts is presented. An explicit method was developed to calculate the gradients of single-ion activities from those of oxides with the constraints of local equilibrium and electroneutrality. This resolves ambiguity in quantifying the thermochemical driving force for ionic diffusion. A model equation for multicomponent ionic diffusion was derived within the framework of non-equilibrium thermodynamics by de Groot and Mazur. The proposed model takes empirically measurable quantities as input variables, so the diffusion calculations are consistent with thermochemical data, as furnished by the CALPHAD (CALculation of PHAse Diagrams) method, as well as ionic mobility measurements. Although the model is derived for oxides, it can be applied to diffusion in other concentrated liquid electrolytes, such as chloride and fluoride melts. Formulas for multicomponent ionic diffusion in various reference frames are presented with respect to mole fraction. 相似文献
27.
The titanium carbides are potential candidates to achieve both high hardness and refractory property. We carried out a structural search for titanium carbides at three pressures of 0 GPa, 30 GPa and 50 GPa. A phase diagram of the Ti-C system at 0 K was obtained by elucidating formation enthalpies as a function of compositions, and their mechanical and metallic properties of titanium carbides were investigated systematically. We also discussed the relation of titanium concentration to the both mechanical and metallic properties of titanium carbides. It has been found that the average valence electron density and tractility improved at higher concentrations of titanium, while the degree of covalent bonding directionality decreased. To this effect, the hardness of titanium carbide decreases as the content of titanium increases. Our results indicated that the titanium content significantly affected the metallic properties of the Ti-C system. 相似文献
28.
Kinetic,thermodynamic parameters and in vitro digestion of tannase from Aspergillus tamarii URM 7115
Amanda Reges de Sena Tonny Cley Campos Leite Talita Camila Evaristo da Silva Nascimento Anna Carolina da Silva Catiane S. Souza Antônio Fernando de Mello Vaz 《Chemical Engineering Communications》2018,205(10):1415-1431
Tannase is an enzyme used in various industries and produced by a large number of microorganisms. The aim of this study was to evaluate tannase production to determine the biochemical, kinetic, and thermodynamic properties and to simulate tannase in vitro digestion. The tannase-producing fungal strain was isolated from “jamun” leaves and identified as Aspergillus tamarii. Temperature at 26°C for 67?h was the best combination for maximum tannase activity (6.35-fold; initial activity in Plackett–Burman design—15.53?U/mL and average final activity in Doehlert design—98.68?U/mL). The crude extract of tannase was optimally active at 40°C, pH 5.5 and 6.5. Moreover, tannase was stimulated by Na+, Ca2+, Mg2+, and Mn2+. The half-life at 40°C lasted 247.55?min. The free energy of Gibbs, enthalpy, and entropy, at 40°C, was 81.47, 16.85, and ?0.21?kJ/mol?·?K, respectively. After total digestion, 123.95% of the original activity was retained. Results suggested that tannase from A. tamarii URM 7115 is an enzyme of interest for industrial applications, such as gallic acid production, additive for feed industry, and for beverage manufacturing, due to its catalytic and thermodynamic properties. 相似文献
29.
Improving the performance of heat transfer fluids is altogether significant. The best approach for improving the thermal conductivity is the addition of nanoparticles to the base fluid. In the present study, specific heat, dynamic viscosity, and thermal conductivity of water-based Indian coal fly ash stable nanofluid for 0.1% to 0.5% volume concentration in the temperature range of 30 to 60°C has been investigated. To evaluate an average particle diameter of 11.5 nm, the fly ash nanoparticles were characterized with scanning electron microscopy and dynamic light scattering. Using zeta potential, the stability of nanofluid in the presence of surfactant Triton X-100 was tested. Thermal conductivity and viscosity of fly ash nanofluid increased, while specific heat decreased as volume concentration increased. The effect of temperature on the fly ash nanofluid was directly proportional to its thermal conductivity and specific heat and inversely proportional to viscosity. 相似文献
30.