Preparation and properties of silicone‐containing poly(methyl methacrylate) gels

Poly(methyl methacrylate) (PMMA) gels with varying amounts of silicone and solvent and constant amounts of crosslinker were prepared by solution free radical crosslinking copolymerization of methyl methacrylate (MMA), ethylene glycol dimethacrylate (EGDM), tetraethoxysilane (TEOS) and vinyltriethoxysilane (VTES) comonomer systems. They were then studied in benzene at a total monomer concentration of 3.5 mol L^?1 and 70 °C. The conversion of monomer, volume swelling ratio, weight fraction and gel point were measured as a function of the reaction time, silicone concentration and benzene content up to the onset of macrogelation. Structural characteristics of the gels were examined by using equilibrium swelling in benzene, gel fraction and Fourier‐transform infrared (FTIR) analysis. The morphology of the copolymers was also investigated by SEM. Based on the obtained results, it was concluded that the FTIR data did not have the capacity to show the presence of the VTES or TEOS moiety in these kinds of copolymers. On the other hand, the variation of weight fraction of gel, W_g, and its equilibrium volume swelling ratio in benzene, q_v, exhibited the same behaviour as that of MMA/EGDM copolymers. Also, the dilution of the monomer mixture resulted in an increase in the gel point and swelling degree and a decrease in the percent of conversion and gel fraction. Finally, TEOS is not an ideal silicone compound for reaction in the MMA/EGDM copolymerization system, whereas VTES is a suitable silicone comonomer for this system and it has been proved useful. Copyright © 2005 Society of Chemical Industry     

Development of a predictive model for polymer/solvent diffusion coefficient calculations

A new calculation procedure for free‐volume parameters is considered in this work by using viscosity prediction methods and the Levenberg‐Marquardt calculation scheme. All parameters used in the Vrentas–Duda free‐volume theory can be estimated from pure component properties. The prediction results are compared with experimental data for some polymer/solvent systems. The diffusion coefficient calculated by Vrentas–Duda theory can be used in the modeling of membrane separation processes. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

隆德县大水沟饮水工程建设与管理措施分析

隆德县在大水沟农村饮水工程建设管理中，科学规划，优化设计方案，完善政策措施，创新管理体制和运行机制，尤其是用水户全过程参与工程建设管理、实行“两部制”水价、实施工程定期检查养护制度、建立工程管理单位目标责任考核制度、执行水费统一管理和提留统筹费等一系列做法．确保了国家投资效益的充分发挥和工程的可持续利用．     

NANO-MULTILAYERS WITH HIGH PERPENDICULAR ANISOTROPY FOR MAGNETIC RECORDING

(FePt/Ag)n nano-multilayers were deposited on MgO (100) single crystal with laser ablation and then subjected to annealing. FePt L1o grains with (001) texture and thus a large perpendicular magnetic anisotropy constant Ku of the order of 106 J/m3 were formed. A thick Ag layer is found to be favorable for decreasing the dispersion of the easy axis for magnetization. The measurement of time decay of magnetization gave rise to a small activation volume of the order of 10-25m3, showing the promising of being the recording medium for future high density perpendicular recording.     

Development of the meshless finite volume particle method with exact and efficient calculation of interparticle area

The Finite Volume Particle Method (FVPM) is a meshless method based on a definition of interparticle area which is closely analogous to cell face area in the classical finite volume method. In previous work, the interparticle area has been computed by numerical integration, which is a source of error and is extremely expensive. We show that if the particle weight or kernel function is defined as a discontinuous top-hat function, the particle interaction vectors may be evaluated exactly and efficiently. The new formulation reduces overall computational time by a factor between 6.4 and 8.2. In numerical experiments on a viscous flow with an analytical solution, the method converges under all conditions. Significantly, in contrast with standard FVPM and SPH, error depends on particle size but not on particle overlap (as long as the computational domain is completely covered by particles). The new method is shown to be superior to standard FVPM for shock tube flow and inviscid steady transonic flow. In benchmarking on a viscous multiphase flow application, FVPM with exact interparticle area is shown to be competitive with a mesh-based volume-of-fluid solver in terms of computational time required to resolve the structure of an interface.     

Dynamics of fluid circulation in coupled free and heterogeneous porous domains

Fluid flow in coupled free and porous domain, particularly when the porous medium is heterogeneous, is encountered in many hydro-environmental conditions, e.g., leakage from underground pipe, combined groundwater lake-subsurface interactions. One of the most difficult problems in the study of coupled flow behaviour has been the development of a universally applicable modelling scheme for combining the flow regimes. This is because the free/porous interfacial properties (e.g., shear-stress; velocity slip) that govern the coupled flow behaviour are difficult to determine experimentally under hydro-environmental conditions. On the other hand, the implications of various forms of heterogeneity in the porous media properties can be very different on the fluid-flow behaviour. Difficulties may also arise in direct coupling of the model equations that govern the fluid flow in the individual regions (e.g., Navier-Stokes for free-flow region and the Darcy's equation for the porous flow region). Consequently, models of coupled free and porous flow for hydro-environmental conditions are not very well developed at the moment. While there are some indications that fluids in coupled free and porous domains may circulate (i.e., development of flow cells), there is a lack of appropriate 3D analysis on how heterogeneities in porous media may affect such flow patterns. In this paper, we aim to analyse how porous media heterogeneity affects the dynamics of flow circulation in the porous side of a coupled free and porous domain. For this purpose, we analyse flow patterns in several model domains made up of two porous layers with differing permeabilities. The governing model equations are discretised and solved using the standard finite volume method on a staggered cell-centred mesh. The temporal discretisation is done using the explicit method. An in-house graphical user interface (GUI) has been created specifically to aid in the visualisation of otherwise complex flow patterns. The GUI contains many post-processing options and provides a comprehensive tool for the analysis of hydrodynamics and contaminant motion (not discussed in this paper) in coupled free and porous flow domains. This GUI is described in this paper briefly. The effects of altering the aspect ratio (i.e., multi-scale) of the domain on the coupled flow pattern have also been discussed.     

橡胶对HIPS树脂落锤指标的影响

通过对高抗冲聚苯乙烯树脂出现产品落锤指标偏低问题的分析，从橡胶配量及其粒径大小上进行了改进，同时改进了工艺操作，采取了提高反应釜搅拌速度、降低乙苯浓度等措施。结果产品合格率达到９９％以上，优级品率达到９８％以上。     

Alekseevskii-Tate revisited:An extension to the modified hydrodynamic theory of long rod penetration

The modified hydrodynamic theory of long rod penetration into semi-infinite targets was established independently by Alek-seevskii and Tate over forty years ago and since then many investigators contributed much to the development of the high speed penetration mechanics.However,in all the models proposed so far,the target resistance Rt is not well defined and usually determined by adjusting it until the predicted depth of penetration comes to an agreement with experimental data.In this paper,assumptions are...     

有限体积法求解立体角离散误差

为解决采用有限体积法求解辐射传输方程时引起离散误差的问题,从有限体积法立体角内热流密度的求解过程出发,运用泰勒级数推导了近似误差的表达式,并分析影响离散误差的各种因素,包括离散射线数,辐射强度分布,假散射及网格比.根据分析结果,采用辐射强度的连续分布模型,模拟了各种因素对误差的影响.结果表明,辐射强度的分布函数对于有限体积法的离散误差有一定程度影响.当增加网格数及减小网格尺寸比时,可以有效地减小离散误差.假散射与离散误差间呈较强的非线性耦合关系.