Synthesis and characterization of CePO4 nanorods via solvothermal process

One-dimensional cerium phosphate(CePO4) nanorods were successfully synthesized by a facile and simple solvothermal method at 150 ℃ for 12 h, using Ce(NO3)3·6H2O and NaH2PO4·2H2O as the starting materials. Phase and morphologie of the as-synthesized CePO4 products, characterized by XRD, FESEM, and TEM, were proved to be perfect and uniform hexagonal CePO4 nanorods with aspect ratio of more than 100. The photoluminescence(PL) spectrometer was used to investigate the optical properties of the assynthesized hexagonal CePO4 nanorods.     

Preparation and spectral analysis of gold nanoparticles using magnetron sputtering and thermal annealing

Gold(Au) nanoparticles were prepared on Au-fi lm-coated K9 glass and silicon substrates by direct current(DC) magnetron sputtering and thermal annealing treatment. The effects of substrate material, annealing temperature, and time on morphologies of Au nanoparticles were investigated, and the formation mechanism of Au nanoparticles was discussed. The experimental results indicate that silicon substrate is more suitable for the formation of Au nanoparticles. On a silicon substrate, Au nanoparticles formed with good spherical shapes at temperature over 700 ℃. It was also found by spectral analysis that the fi eld enhancement factor of the island-shaped Au particles was smaller than that of the granular Au particles; the better the spherical shape as well as the smaller the size and spacing of Au particles, the higher the light absorption rate; the absorption peak had a red shift with increasing particle size and spacing.     

Effect of Mg-film thickness on the formation of semiconductor Mg2Si films prepared by resistive thermal evaporation method

Mg fi lms of various thicknesses were deposited on Si(111) substrates at room temperature by resistive thermal evaporation method, and then the Mg/Si samples were annealed at 40 ℃ for 4 h. The effects of Mg fi lm thickness on the formation and structure of Mg2Si fi lms were investigated. The results showed that the crystallization quality of Mg2Si fi lms was strongly infl uenced by the thickness of Mg fi lm. The XRD peak intensity of Mg2Si(220) gradually increased initially and then decreased with increasing Mg fi lm thickness. The XRD peak intensity of Mg2Si(220) reached its maximum when the Mg fi lm of 380 nm was used. The thickness of the Mg2Si fi lm annealed at 400 ℃ for 4 h was approximately 3 times of the Mg fi lm.     

变热流工况土壤导热系数对热恢复特性的影响研究

土壤热恢复特性是土壤源热泵长期稳定高效运行的决定性因素之一.土壤导热系数是土壤热物性最重要的参数之一,对土壤的热恢复特性具有决定性意义.利用ANSYS有限元分析模型,模拟研究在变热流工况下,土壤的导热系数对土壤热恢复特性的影响.     

高速电主轴热态性能有限元分析

以数控高速加工中心电主轴为研究对象,采用Solidworks软件建立了电主轴的三维模型,应用有限元分析软件Abaqus对电主轴模型进行了热态分析,绘制了电主轴的稳态温度场分布图,并求出电主轴在不同转速下的温度值.为电主轴冷却系统的设计提供了依据.     

驻马店—遂平一带地热资源赋存规律研究

利用已有的地热地质成果,以驻马店—淮滨凹陷带(驻马店—遂平段)地热田为研究区,采用物探和地球化学调查等方法,研究区域地热资源赋存规律,为地热资源保护与综合开发利用提供依据.通过测定同位素氘、氚、14C、18O可知,地热田地热流体年龄为2.6万~3.0万a,地热田及区域地热流体补给来源于驻马店市西部山前地带;依据地热田地质条件,采用热储法和回收率法进行了地热资源储量和地热流体可采资源储量的计算与评价.结果可知:驻马店—遂平一带地热区热储量为2.14×1019J;地热流体可开采量为1.14×107m3/a;地热田地热流体属理疗热矿水,可用于理疗、洗浴.     

天然胶/杜仲胶共混硫化物结晶性对热致形变回复性能的影响

用XRD法分析天然胶/杜仲胶共混硫化胶的结晶性,研究其结晶性对天然胶/杜仲胶共混硫化胶的物理性能和热致形变性能的影响.实验结果表明:随着杜仲胶用量的增加,硫化胶在XRD图谱中的衍射峰强度增大,硫化胶的结晶性增大,硫化胶交联密度有明显减小.定伸应力和拉伸强度随杜仲胶用量的增加而增大,而拉断伸长率减小,热致回复温度降低,试样的最终形变率减小.     

以NaHCO3为矿化剂溶剂热合成Zn2SnO4纳米粉体

以NaHCO3为矿化剂采用溶剂热法合成了Zn2SnO4纳米粉体,通过X-射线衍射（XRD）、扫描电镜（SEM）和透射电镜（TEM）考察了矿化剂浓度、溶剂热反应温度和时间、表面活性剂等对样品组成、结构和形貌的影响,结果表明：矿化剂浓度较低时所得样品为SnO2,矿化剂浓度为1.0 mol/L、溶剂热反应温度和时间为200℃,24 h时,可得立方结构的分散均匀的Zn2SnO4纳米粉体,添加表面活性剂PVP后,样品粒度增大,立方块形貌更加明显.     

Thermo economic evaluation of oxy fuel combustion cycle in Kazeroon power plant considering enhanced oil recovery revenues简

Oxy fuel combustion and conventional cycle （currently working cycle） in Kazeroon plant are modeled using commercial thermodynamic modeling software. Economic evaluation of the two models regarding the resources of transport and injection of carbon dioxide into oil fields at Gachsaran for enhanced oil recovery in the various oil price indices is conducted and indices net present value （NPV） and internal rate of return on investment （IRR） are calculated. The results of the two models reveal that gross efficiency of the oxy fuel cycle is more than reference cycle （62% compared to 49.03%）, but the net efficiency is less （41.85% compared to 47.92%） because of the high-energy consumption of the components, particularly air separation unit （ASU） in the oxy fuel cycle. In this model, pure carbon dioxide with pressure of 20~ 105 Pa and purity of 96.84% was captured. NOx emissions also decrease by 4289.7 tons per year due to separation of nitrogen in ASU. In this model, none of the components of oxy fuel cycle is a major engineering challenge. With increasing oil price, economic justification of oxy fuel combustion model increases. With the price of oil at $ 80 per barrel in mind and $ 31 per ton fines for emissions of carbon dioxide in the atmosphere, IRR is the same for both models.     

×Synergistic action of non-solvent induced phase separation in preparation of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation

A systematic study of air gap distance effects on the structure and properties of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation （TIPS） has been carried out. The results show that the hollow fiber membrane prepared at air gap zero has no skin layer; the pore size near the outer surface is larger than that near the inner surface; and the special pore channel-like structure near the outer surface is formed, which is quite different with the typical sponge-like structure caused by TIPS and the finger-like structure caused by non-solvent induced phase separation （NIPS）, because of the synergistic action of non-solvent induced phase separation at air gap zero. The pore size gradually decreases from outer surface layer to the intermediate layer, but increases gradually from intermediate layer to the inner surface layer. With the increase of air gap distance, the pore size near the outer surface gets smaller and a dense skin layer is formed, and the pore size gradually increases from the outer surface layer to the inner surface layer. Water permeability of the hollow fiber membrane decreases with air gap distance, the water permeability decreases sharply from 45.50× 10^-7 to 4.52× 10^-7 m^3/（m^2-s.kPa） as air gap increases from 0 to 10 mm at take-up speed of 0.236 m/s, further decreases from 4.52×10^-7 to 1.00×10 ^-8m^3/（m^2.s·kPa） as the air gap increases from 10 to 40 mm. Both the breaking strength and the elongation increase with the increase of air gap distance. The breaking strength increases from 2.25 MPa to 4.19 MPa and the elongation increases from 33.9% to 132.6% as air gap increases from 0 mm to 40 mm at take-up speed 0.236 m/s.