Effect of Thickness on the Structure and Tribological Properties of MoSx Coating

MoSx coatings were prepared by bipolar-pulse DC unbalanced magnetron-sputtering system with the variation of coating thickness at different Ar pressures.The composition and surface morphology were determined by using energy dispersive X-ray and scanning electron microscopy;the structural characterization was analyzed by X-ray diffraction.The friction and wear properties were investigated by fretting tests in air with less than 10% and 50% relative humidity.At 0.40 Pa pressure,(002) basal plane orientation was formed throughout the coatings.At 0.88 Pa and 1.60 Pa pressures,(002) basal plane orientation was only noticed in the first stage of coating growth(around 0.20 μm in thickness), and then edge orientations with their basal planes perpendicular to the surface would be evolved in the coatings.Humidity has a minor influence on the coatings that have(002) basal plane orientation,whereas the tribological properties of MoSx coatings with edge orientations are greatly affected by humidity.The mechanisms of coating growth and friction and wear processes are discussed.     

Stress in Thin Films;Diffraction Elastic Constants and Grain Interaction

Untextured bulk polycrystals usually possess macroscopically isotropic elastic properties whereas for most thin films transvers isotropy is expected,owing to the limited dimenionlity .The usually applied models for the calculation of elstic constants of polycrystals from single crystal elastic contants(so-called grain interaction models)erroneously predict macroscopic isotropy for an(untextured) thin film.This paper presents a summary of recent work where it has been demonstrated for the first time by X-ray diffraction analysis of stresses in thin films that elastic grain interaction can lead to macroscopically anisotropic behaviour (shown by non-linear sin^2φ plots).A new grain interaction model,predictin the macroscopically anisotropic behaviour of thin films,is proposed.     

SAW滤波器简化衍射频响的计算方法

提出了由一个变迹ＩＤＴ叉指换能器和一个均匀ＩＤＴ组成的ＳＡＷ滤波器简化衍射频响的计算方法，即将均匀ＩＤＴ简化成单根指计算其衍射频响。该方法与未简化衍射频响的计算方法相比，计算量大为减小，前者约为后者的（Ｎ为均匀ＩＤＴ的指对数）。并给出了一个实例，用未简化与简化方法分别计算了其衍射频响，结果表明，两者符合得较好。     

用Bragg—Brentano聚焦几何测试摆动曲线应注意的两个问题

分析了在Ｂｒａｇｇ－Ｂｒｅｎｔａｎｏ聚焦几何下测试摆动曲线时，引起摆动曲线失真的两个因素，提出了用该系统测试摆动曲线应具备的两个必要条件：其一，发散狭缝ＤＳ一定要远小于样品真正摆动曲线半高宽ＦＷＨＭ；其二，最好用Ｋβ辐射以防Ｋα２的干扰。     

锆钡镧铝氟化物玻璃的分相研究

本文综述了氟化物玻璃中的分相研究。在前人研究基础上应用透射电镜，X射线能谱，电子能量损失谱及X射线衍射，差热分析等研究了锆钡镧铝氟化物玻璃中的液-液分相，发现此种现象普遍存在于该类玻璃之中。对玻璃成分与分相形貌及微观结构之间的关系、对析出晶相种类及分相与析晶的相互影响进行了研究。提出欲降低氟化物玻璃的光损耗，分相与析晶一样是不容忽视的因素。     

非线性半导体SiC微粉及其半导体漆（带）特性试验方法的研究

本文介绍了非线性半导体 SiC 微粉及其半导体漆(带)伏安特性的测量方法,以及用微机程序计算其非线性特征参数的方法,从而为研究新型防晕结构提供了科学有效的手段。     

多相物质粉末衍射的物相检索

讨论了多相物质粉末衍射的物相检索问题，介绍了XRDS的物相检索软件。这是一种智能型的物相检索程序，考虑了测试数据的不确定度，以及粉末样品和块状样品衍射图谱各自的特点，不仅注意到实际样品中微量物相存在的可能，也注意到块状样品结构有序性的可能。XRDS能够帮助材料工作者同时检出样品中所含的多种物相及其含量，操作简单、结果可靠。     

非水解溶胶-凝胶法低温合成硅酸锆

以工业纯ZrCl4、 Si(OC2H5)4为前驱体,通过非水解溶胶-凝胶法合成了硅酸锆.采用DTA-TG和XRD等测试手段研究了凝胶热处理过程中的物相变化.结果表明:当前驱体溶胶中未引入矿化剂时,硅酸锆的合成温度高达1450℃;相比之下,溶胶中引入矿化剂LiF后在600℃下便开始出现了ZrSiO4衍射峰,在700℃合成的硅酸锆不仅合成率高,而且晶体发育好,实现了低温合成硅酸锆的目标.     

龙永煤田煤的变质特征及其作用类型分析

从煤岩、煤化学分析着手，依据煤的挥发分、元素组成中的氢碳含量、镜质体反射率、显微硬度、煤的X射线衍射分析指标及电性质等来划分龙永煤田煤的变质程度为无烟煤；进一步分析其变质程度可知，实际已达无烟煤中高变质阶段；结合地质背景分析了其变质作用类型。