Quantitative preparation of long chain thioethers from an oxo-trans-2-enoic ester and a 9,12-dioxo-trans-10-enoic acid

Branched-chain thioethers have been prepared from methyl 4-oxo-trans-2-hexadecenoate and 9,12-dioxo-trans-10-octadecenoic acid. The reagents involved in these preparations were mercaptoacetic and mercaptopropionic acids. The yields of these thioethers are almost quantitative.     

An economical synthesis of the major sex attractant of the oak leaf roller—cis-10-tetradecenyl acetate

The major sex attractant of the oak leaf roller (Archips semiferanus Walker),cis-10-tetradecenyl acetate (I), was synthesized in 55–62% overall yield by a highly economical route from inexpensive azelaic acid (II).Authorized as Paper No. 4779 in the Journal Series of the Pennsylvania Agricultural Experiment Station.     

挖沙船的变频节能改造分析

挖沙船上主电机在采用变频调速以前,多用星三角起动或自耦减压起动方式。这种启动方式起动电流较大,导致所选用的柴油发电机的容量过大。采用变频调速以后,可以减小电动机的起动电流,降低柴油发电机的容量,减少前期投资,给企业带来可观的经济效益。     

Sex attractants for Geometrid and Noctuid moths

Male moths belonging to 17 species of Geometridae and nine species of Noctuidae were captured in traps baited with synthetic chemicals as part of a field screening program. The compounds tested were the C₁₈-C₂₂ homologs of: (1) (3Z,6Z,9Z)-triene hydrocarbons; (2) mixtures containing equal quantities of (3Z,6Z)-cis-9,10-expoxydienes, (3Z,92Z)-cis-6,7-epoxydienes, and (6Z,9Z)-cis-3,4-epoxydienes; (3) (3Z,6Z)-9S,10R-epoxydienes; (4) (3Z,6Z)-9R,10S-epoxydienes; and (5) (3Z,6Z,9Z,11E)-nonadecatetraene. Field captures and electroantennographic assays revealed a high degree of specificity in the responses of many species to the synthetic chemicals. In several species the ability of males to discriminate between the 9S,10R and 9R,10S enantiomers of the monoepoxydiene isomers was clearly shown. Synergists and inhibitors were discovered for several of the reported attractants, some of which were not previously known to have semiochemical activity. The geometrid moths captured includedEpirrhoe sperryi (Herbulot),Mesoleuca ruficillata (Guenée),Triphosa haesitata (Guenée),Metanema inatomaria (Guenée),Prochoerodes transversata (Drury),Cabera erythemaria (Guenée),Synaxis jubararia (Hulst),Dysstroma brunneata ethela (Hulst),Eulithes testata (Linnaeus),Sicya macularia (Harris),Xanthorhoe iduata (Guenée),X. abrasaria aquilonaria (Herrich-Schäffer),X. munitata (Hübner),Itame loricaria (Eversmann),Eupithecia annulata (Hulst),E. rovocastaliata (Packard) andE. satyrata dodata (Taylor). The noctuid moths captured includedBleptina caradrinalis (Guenée),Idia américalis (Guenée),I. aemula (Hübner),Rivula propinqualis (Guenée),Lomanaltes eductalis (Walker),Spargaloma sexpunctata (Grote),Caenurgina distincta (Neumuller),Euclidia cuspidea (Hübner), andZale duplicata (Bethune). Six of the nine noctuid species captured belong to three subfamilies for which sex attractants had not been reported previously. Details for the stereospecific synthesis of (3Z,6Z)-cis-9,10-epoxydienes are also reported.Issued as NRCC No. 24314.     

10kV配网自动化系统建设与规划

介绍10kV配网自动化系统建设与规划的主要内容,并提出注意事项。     

高温-超压-高CO2背景下致密砂岩储层成岩作用特征——以莺歌海盆地LD10区新近系梅山组-黄流组为例

利用薄片鉴定、扫描电镜、阴极发光及碳氧同位素分析等手段,对莺歌海盆地LD10区新近系梅山组-黄流组高温-超压-高CO₂背景下的储层成岩作用特征及其对孔隙的影响进行了系统研究。研究结果表明: ①莺歌海盆地LD10区新近系梅山组-黄流组储层发育重力流沉积,岩性以中-细粒长石岩屑石英砂岩为主,储层物性以特低-低孔、特低渗特征为主。②压实、胶结和溶蚀作用是研究区主要的成岩作用类型。超压对黏土矿物的转化及石英次生加大具有明显抑制作用,并在一定程度上保护了原生孔隙。富含CO₂的高温流体不仅造成了黏土矿物的异常转化,同时促进了溶蚀作用发生,增加了次生孔隙。③研究区黄二段储层的成岩演化序列为: 菱铁矿胶结→石英次生加大→绿泥石胶结→长石淋滤溶蚀→高岭石形成→早期方解石胶结→早期白云石胶结→长石溶蚀→方解石溶蚀→伊利石大量生成→晚期铁方解石、铁白云石形成。④总体上,压实作用使孔隙度减少了45.30%～62.93%,胶结作用使孔隙度减少了1.65%～35.01%,溶蚀作用使孔隙度增加了0.72%～8.00%。其中,黄流组中下部砂岩储层受到了超压保护和CO₂溶蚀作用的双重影响,物性较好,钻井过程中应考虑高CO₂风险。     

用PID控制弧焊逆变电源的试验研究

本文介绍了对逆变电源进行数字PID控制的原理和方法,分析了采样周期、PID参数及不同的焊接工况对控制特性的影响。试验表明,只要恰当地选择PID(或PI)参数,不仅能实现高精度的恒流控制,而且能使系统的动态性能显著提高。     

关于110 kV线路重合闸的探讨

重合闸在110 kV线路供电过程中起到了非常重要的作用,它关系着电力系统运行的安全性和可靠性。在重合闸投运前,需要模拟系统的运行情况,事前试验可能存在的重合闸形式,及时发现、排除其中存在的问题,确保重合闸能够正确动作。分析了110 kV线路重合闸的原理、功能,并以某案例分析为基础,简要探讨了对110 kV线路重合闸控制的相关认识。     

Perception of Hand Force in Power Grip for Females

Borg's rating of perceived exertion (RPE) and category ratio (CR‐10) scales are commonly used to quantify perceived muscular exertion for body segments. Twenty females participated in an experiment to study the power grip force at four perceived exertion levels using either dominant or nondominant hand under two posture conditions. It was found that the subjects tended to apply a higher power grip force (100% of perceived maximum voluntary contraction) than the levels they were requested to apply. The power grip forces between dominant and nondominant hands at low hand exertion levels were negligible. The grip forces between the two hands were significantly different when the exertion level was nearly maximal. Linear regression models were established for the subjects to link the relationship between the perceived hand exertion and measured grip force, hand used, and hand/arm posture. All the models were statistically significant (p < 0.0001) with R² values 0.97 or higher. These models provided better estimates in perceived hand exertion for dominant hand than for nondominant hand. A follow‐up experiment was conducted to measure the subjective rating of both the CR‐10 and RPE when a 98 N grip force was applied. It was found that the subjects reported higher exertion levels when they were using the CR‐10 scale than when they were using the RPE scale. © 2011 Wiley Periodicals, Inc.