纳米稀土复合固体超强酸催化合成乙酸苄酯

采用共沉淀法制备了纳米稀土复合固体超强酸SO4^2-／ZrO2-2％Nd2O3催化剂，电镜分析表明，催化剂颗粒直径在25nm左右，比表面积测定：71．03m^2／g。酸强度-12．70〈Ho〈-11．99。并对合成乙酸苄酯的最佳反应条件进行了研究。研究表明：当苯甲醇与乙酸的物质的量比为1：2，反应时间为5h，反应温度为120℃，催化剂用量为6％苯甲醇的质量时，酯化率可达92．04％。研究发现，该催化剂可重复使用并可活化再生。     

Study of different effect on foaming process of biodegradable bionolle in supercritical carbon dioxide

Microcellular foaming of biodegradable Bionolle in supercritical CO₂ has been produced. The effects of a series of variable factors, such as saturation temperature, saturation pressure, and depressurization time and step on the foam structures and density, were studied through measurement of density and SEM observation. The experimental results show that higher saturation temperatures lead to an increase in bulk densities; and different depressurization time and step result in different product cell morphology. In addition, at some saturation temperature, the orientation of the cells can be found in the product morphology. XRD experimental results show that the foaming treatment with SC CO₂ increased the crystallinity of Bionolle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2901–2906, 2006     

Possible Energy Network with polygeneration system and CCS for China

On basis of adopting polygeneration systems for power and alternative fuels,capturing CO2 with near zero energy penalties,and storing CO2 on sites,a new kind of Energy Network can integrate energy utilization,CO2 capture,transportation and storage synthetically.Techno-economic analysis of this solution focusing on Inner Mongolia and the Yangtze River Delta districts had been carried with comparison to the chain method for energy utilization and CO2 sequestration.This solution can save 21.5% of energy,and re...     

Monitoring slope deformation using a 3-D laser image scanning system:a case study

An ILRIS-36D 3-D laser image scanning system was used to monitor the Anjialing strip mine slope on Pingshuo in Shanxi province.The basic working principles,performance indexes,features and data collection and processing methods are illustrated.The point cloud results are analyzed in detail.The rescale range analysis method was used to analyze the deformation characteristics of the slope.The results show that the trend of slope displacement is stable and that the degree of landslide danger is low.This work indicates that 3-D laser image scanning can supply multi-parameter,high precision real time data over long distances.These data can be used to study the distortion of the slope quickly and accurately.     

基于模糊神经网络的大场景人群密度估计方法 *

提出了一种估计大场景下密集人群密度的方法。该方法根据人类视觉的模糊性原理,认为用模糊集来划分人群密度范围比用确定的方法更符合人眼视知觉的认知方式,利用统计的方法确定灰度共生矩阵各指标对于各个密度类别的隶属函数;设计基于误差反向传播训练算法（BP）的模糊神经网络,计算样本模式对于各个密度类别的隶属度,并根据人群密度变化的时域连续性原理对人群密度范围进行合理估计。实验表明该方法提高了估计精度。     

Investigation on the electrocatalytic characteristics of SnO_2 electrodes with nanocoating prepared by electrodeposition method

SnO2 electrodes have many advantages in the degradation of toxic or bio-refractory organic wastewater,and SnO2 is a kind of anode material which has the potential to be widely used.Electrocatalytic effi-ciency and service life of Ti\SnO2 electrodes are key factors that can influence its applications.In order to enhance the electrocatalytic characteristics of Ti\SnO2 electrodes,a type of electrocatalytic electrode with nanocoating was prepared by direct current(DC)electrodeposition method and thermal oxidati...     

CuO-NiO/Al_20_2催化剂上N-甲基哌嗪合成研究

以共沉淀法制备铜、铝系复合氧化物作为催化剂,二乙醇胺和甲胺为原料,合成了N-甲基哌嗪.利用高压反应釜对其进行活性评价,发现CuO-NiO/Al2O3活性最高.并对铜、铝、镍摩尔比、沉淀剂种类、沉淀方式,焙烧温度等条件进行了优化.结果表明:催化剂中理想的Cu、Al、Ni摩尔比为1:1:3.2,沉淀剂为氢氧化钠,沉淀方式为并流,焙烧温度为500℃.该条件下N-甲基哌嗪的选择性为27.7%,二乙醇胺的转化率达89.8%.另外通过对使用前后催化剂进行表征分析发现催化剂失活原因为表面高聚物的附着和对孔道的堵塞.     

Study of the physico–chemical characteristics and rheological behaviour of boehmite dispersions for dip-coating applications

Dispersions of a totally dispersible AlOOH powder have been studied. The effect of the initial composition has been studied to outline the reactions that determine the final rheological behaviour of the dispersions. The final viscosity and viscoelastic properties of the dispersions are determined by the sol–gel phenomena occurring during the ageing treatment. Gel formation is favoured by low water and high acid contents, while it is disfavoured by prolonged stirring. Gelling time from 48 h to 4 months has been observed depending on the initial composition.     

陶瓷原料中二氧化硅分析方法的对比与选择

本文综合各种文献 ,对陶瓷原料中SiO2 的各种分析方法的优缺点 ,使用条件 ,应用侧重点进行了比较与评述