The In-Sn-Ni alloys of various compositions were prepared and annealed at 160°C and 240°C. No ternary compounds were found;
however, most of the binary compounds had extensive ternary solubility. There was a continuous solid solution between the
Ni3Sn phase and Ni3In phase. The Sn-In/Ni couples, made of Sn-In alloys with various compositions, were reacted at 160°C and 240°C and formed
only one compound for all the Sn-In alloys/Ni couples reacted up to 8 h. At 240°C, Ni28In72 phase formed in the couples made with pure indium, In-10at.%Sn and In-11at.%Sn alloys, while Ni3Sn4 phase formed in the couples made of alloys with compositions varied from pure Sn to In-12at.%Sn. At 160°C, except in the
In/Ni couple, Ni3Sn4 formed by interfacial reaction. 相似文献
A Ni catalyst was added to a cis-selective Pd catalyst in an attempt to further improve the Pd catalyst's cis-selectivity and activity for canola oil hydrogenation. The system was tested under reaction conditions known to be suitable for cis-selective hydrogenation with the Pd catalyst (50 ppm Pd, 70 °C, and 5.2 MPa). Although inactive on its own under these conditions, the addition of 100 ppm Ni increased the hydrogenation activity (from 2.12 to 2.49 10−2 min−1). Further addition of Ni up to 1000 ppm resulted in no further improvements in activity. The trans isomer contents of the oils hydrogenated with Pd and the Pd/Ni systems were similar. The level of conjugated dienes decreased rapidly during hydrogenation with both Pd alone and with the Pd/Ni combination and no changes in conjugation were detected in the presence of the Ni catalyst alone. The increased activity of the Pd/Ni system over Pd alone was attributed to adsorption of catalyst poisons from the oil by Ni. 相似文献
1. 1. System design optimization and validation for single-speed heat pump by S.K. Fischer and C.K. Rice, Oak Ridge National Laboratories.
2. 2. Analysis of on/off cycling for an air-to-air heat pump operating in the heating mode by W.A. Miller, Oak Ridge National Laboratories.
3. 3. Field measured cycling, frosting and defrosting losses for a high efficiency air source heat pump by V.D. Baxter and J.C. Moyers, Oak Ridge National Laboratories.
4. 4. Design and available energy analysis of a heating-only residential heat pump for the Western Pacific Northwest by D.E. Elger, C.M. Reistad and S. Lang, Oregon State University.
5. 5. A study of heat pump service life by Nance C. Lovvorn, Alabama Power Company and Carl C. Hiller, Electric Power Research.
Résumé
1. 1. Optimisation de la conception des systèmes et application à la pompe à chaleur à une seule vitesse;
2. 2. analyse du cycle par tout ou rien d'une pompe à chaleur air-air fonctionnant en mode de chauffage;
3. 3. pertes en fonctionnement cyclique, par givrage et dégivrage mesurées sur place pour une pompe à chaleur de grand rendement dont la source est l'air;
4. 4. conception et analyse de l'énergie disponible d'une pompe à chaleur uniquement pour le chauffage de locaux résidentiels sur la côte du Pacifique nord-ouest occidental;
5. 5. étude de la durée de vie d'une pompe à chaleur.
Les noms et les addresses des auteurs se trouvent dans le sommaire anglais. 相似文献