Borides at interfacial zone of IC6 TLP bonded joints

1　INTRODUCTIONTransientliquidphase (TLP)bondingtechniquehasbeensuccessfullyusedinjoiningheatresistantal loys ,likeHastelloyX ,Inconel713C ,In10 0 ,Udimet5 0 0 ,70 0 ,MarM 2 0 0 ,0 0 7,2 4 7,30 2 ,Rene′80 ,TD NiCr ,MA75 4,6 0 0 0 ,PWA14 2 2 ,CSMX 2etc ,whicharesusceptibletohotcrackingor post weldheat treatmentcrackingproblemsduringfusionweld ing[14 ] .Inaddition ,therewerereportsofjoiningNiAlandTiAlintermetallicsbyTLPbondingmethod[510 ] .Forexample ,Galehadinvestigatedthemic…     

锡磷青铜合金水平连铸工艺参数的优化

铸造锡磷青铜合金组织中存在显微缩松、枝晶偏析和反偏析是冷加工报废的主要原因.通过连铸工艺参数的正交实验,建立了轧制成材率与主要工艺参数之间的神经网络描述,网络模型与遗传算法结合对工艺参数的组合进行了优化,改善了铸坯的组织,提高了轧制带材成材率.     

Influence of expandable graphite on fire resistance and water resistance of flame-retardant coatings

Expandable graphite (EG) coating and ammonium polyphosphate-pentaerythritol-melamine (APP-PER-MEL) coating were prepared. Thermal degradation and char formation of the coatings were investigated by differential thermal analysis (DTA), thermogravimetry (TG), X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results have shown that the anti-oxidation and fire-resistant properties of expandable graphite coating containing EG with size of 74 μm are better than those of APP-PER-MEL coating. The static immersion test was applied to study water resistance of the coatings, and the fire protection test and mechanical test were used to analyse heat insulation and mechanical properties of coatings before and after water immersion. The fire-resistant and mechanical properties of APP-PER-MEL coating were severely damaged by water immersion, whereas EG coating containing 8.5% EG with size of 74 μm could retain the good fire resistance even after 500 h water immersion.     

12Cr2Ni4MoVNb钢热处理工艺参数的研究

通过对12Cr2Ni4MoVNb钢锻件的热处理工艺试验研究,重点进行了晶粒长大倾向、奥氏体化温度、奥氏体化保温时间、回火温度及回火保温时间对性能的影响的试验工作,分析了各种热处理工艺参数对力学性能的影响,优化了热处理工艺参数并在生产中进行了验证。在限定回火温度并且不损失塑韧性的前提下可以使σ_b和σ_(0.2)满足订货条件要求:σ_b≥90OMPa、σ_(0.2)≥60OMPa。     

化学镀Ni┐P/Fe双层结构材料中氢的扩散

采用超高真空气相氢渗透技术在80～250℃温度范围内,测定了氢在化学镀非晶态Ni-P/Fe双层结构材料中的扩散系数,研究了化学镀Ni-P镀层及其在300℃下真空退火热处理1h后对氢在基材中扩散行为的影响。结果表明,在实验温度范围内,氢在化学镀Ni-P/Fe双层结构中的有效扩散系数D与温度T的关系遵循Arrhenius方程,300℃真空退火处理后,有效扩散系数基本不变。     

Application of an analytical phase transformation model

Employing isothermal and isochronal differential scanning calorimetry, an analytical phase transformation model was used to study the kinetics of crystallization of amorphous Mg82.3Cu17.7 and Pd40Cu30P20Ni10 alloys. The analytical model comprised different combinations of various nucleation and growth mechanisms for a single transformation. Applying different combinations of nucleation and growth mechanisms, the nucleation and growth modes and the corresponding kinetic and thermodynamic parameters, have been determined. The influence of isothermal pre-annealing on subsequent isochronal crystallization kinetics with the increase of pre-annealing can be analyzed. The results show that the changes of the growth exponent, n, and the effective overall activation energy Q, occurring as function of the degree of transformation, do not necessarily imply a change of nucleation and growth mechanisms, i.e. such changes can occur while the transformation is isokinetic.     

Fluorinated Polyphosphazenes: A Survey

A general survey of fluorinated phosphazene polymers starting from their synthesis in 1965 to recent times is presented. Various types of fluorinated phosphazenes are described depending on the way fluorine atoms are connected to the polyphosphazene skeleton. The characterization, properties and practical utilization of these compounds in different domains are critically discussed.     

Enhancement by SO2 of initial activity for selective catalytic reduction of NO with CH3OH over \gamma-alumina

The effect of SO₂ on catalytic activity for NO reduction to N₂ by methanol in excess oxygen over $\gamma$ -alumina has been investigated. SCR activity increased initially upon exposure of a fresh $\gamma$ -alumina catalyst to SO₂ which is attributed to formation of Brønsted acid sites. Longer exposure to SO₂ leads to a decline in catalytic activity to a lower steady-state NO_x reduction activity which is independent of the SO₂ content in the feed gas.     

Analysis of the Thermal Explosion in Systems Porous Reagent–Active Gas–Solid Product

The specific features of dynamics of the thermal explosion in systems porous reagent–active gas–solid product under conditions where the heattransfer and masstransfer regions are separated from the ambient medium are considered. In addition to the competition of heat release and heat removal, the process of initiation of exothermal chemical interaction in these systems under normal pressures depends significantly on conditions of filtration transport of the gaseous reagent. The induction and postinduction periods of the thermal explosion are studied. The theoretical analysis of thermalexplosion issues is supplemented by an experimental study of the process for the porous titanium–nitrogen–titanium nitride system.     

单参数Wilson方程预测C_9-DMP体系汽液平衡

根据实测γ~∞_1用单参数Wilson方程预测均三甲苯-DMP和偏三甲苯-DMP二元体系汽液平衡,并推算均三甲苯-偏三甲苯-DMP三元体系的汽液平衡,与实测数据比较,均获得良好结果。